大规格圆钢质量分析和控制

针对湘钢棒材厂生产大规格圆钢出现的表面质量问题，重点介绍了在成品轧机后采用U形辊道和立活套替换棍道；冷床输入辊道采用镶WT合金套；增设高压水除鳞装置；中间轧件尺寸精度控制等措施，成功的解决了大规格圆钢表面擦伤、“麻面”、尺寸超差等表面质量问题，产品质量显著提高。     

套管钻井用套管外表面磨损后剩余强度分析

在分析讨论套管钻井管柱磨损形态的基础上,结合API5C5实物试验尺寸要求,通过有限元计算分析方法,对钻井套管完钻后含有外表面磨损缺陷的套管柱的极限剩余抗挤强度和极限剩余抗拉强度进行了研究,分别获得了均匀磨损和偏磨条件下,套管钻井套管柱外表面磨损缺陷的临界长度尺寸数值,以及不同破坏失效准则条件下的剩余抗挤强度和剩余抗拉强度的计算方程,为套管钻井中套管柱的设计、计算奠定了理论基础。     

锆酸铅薄膜的生长特性与表面化学态

以醋酸铅和异丙醇锆为原料，乙二醇甲醚为溶剂。通过溶胶-凝胶法和快速退火工艺在Pt(111)／Ti／SiO2／Si(100)基片成功地制备出不开裂的钙钛矿PbZrO3薄膜。用XRD和原子力显微镜测量了薄膜随退火温度变化的结构和表面形貌特征，用XPS测试了650℃退火PbZrO3薄膜的表面化学态。     

Copper(II) removal from aqueous solutions by fly ash

The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol^?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation.     

硅表面上的纳米量子点的自组织生长

纳米半导体量子点以其所具有的新颖光电性质与输运特性正在受到人们普遍重视。作为制备高质量纳米量子点的工艺技术 ,自组织生长方法倍受材料物理学家的青睐。而如何制备尺寸大小与密度分布可控的纳米量子点更为人们所注目。因为这是关系到纳米量子点最终能否器件实用化的关键。文中以此为主线 ,着重介绍了各种 Si表面 ,如常规表面、氧化表面、台阶表面以及吸附表面上 ,不同纳米量子点的自组织生长及其形成机理 ,并展望了其未来发展前景     

XPS studies of directly fluorinated HDPE: problems and solutions

X-ray photoelectron spectroscopy (XPS) applied to the study of fluorinated polymer surfaces presents several problems related both to peak assignment and to degradation. In this work, we analyse extensively the question of XPS peak assignments in this kind of surfaces. We conclude that in this kind of surfaces using binding energy differences between fluorine and carbon is better than using absolute binding energies. Also a useful relation between fluorine photoelectron energy vs. polymer composition expressed through the atomic ratio fluorine/carbon (F/C) was found. A protocol for data treatment is proposed and applied to a XPS study of the degradation induced by X-ray on high-density polyethylene surfaces modified by direct fluorination. Results obtained for the degradation, namely the atomic ratio F/C obtained by two different methods, combined with angle resolved X-ray photoelectron spectroscopy (ARXPS) were used to study the fluorine concentration profile in depth, producing self-consistent results.     

正交参数与平纹面

本文证明了一族闭曲线C(t),t∈I,称变闭曲线,在光滑性条件下,具有正交参数u,即当C(t)表为(?)=(?)(u,t)时,有(?)·(?)≡0.接着,文中提出了一种“降维法”,即用一族平行平面将空间曲面截成平面变曲线,并讨论其若干整体性质.     

多层频率选择表面的分析

本文利用矩量法和广义散射矩阵理论分析了多层频率选择表面的散射特性。通过引入广义波导概念,可以统一分析单元形状为任意的多层频率选择表面。作为示例,计算了几种不同结构频率选择表面的散射特性,结果与文献中给出的数据相符。     

Possibilities and extension of XRD material response analysis in failure research for the advanced evaluation of the damage level of Hertzian loaded components

Due to clearly distinguishable damage symptoms, it is differentiated between the surface and sub‐surface failure mode of rolling bearings. Material states red out by X‐ray diffraction (XRD) residual stress measurements point to a variety of loading conditions especially at raceway surfaces that are associated with several competing failure mechanisms. The corresponding lifetime reduction can range from the lower fatigue strength region to material ratcheting in extreme cases. Relevant position of the microstructural changes and nature of the failure mechanisms are characterized. The time alteration of the XRD material parameters measured at or near the surface and at the depth of the maximum equivalent stress correlates, in a different manner, with the statistical parameter of the 10 % bearing life. Both failure modes are illustrated by concrete examples. Contaminated lubricant and boundary lubrication, which represent practically important surface‐induced failures, are discussed in more detail. Gray staining, i.e. shallow pitting, often occurs without distinct indication of global material aging by means of XRD characteristics. Here, scanning electron microscopy observations and electron microprobe analyses point to corrosion fatigue as acting surface failure mechanism. The interaction between material and lubricant under complex loading regimes particularly of mixed friction and corrosion opens further failure research areas in the field of tribology.     

光通信用垂直腔面发射激光器的进展

垂直腔面发射激光器(VCSEL)以其优异的性能有望成为信息时代的新光源.文章介绍了用于光通信的VCSEL的开发现状.