基板温度对电热爆炸喷涂制备粘结层性能的影响

基板温度分别为室温、100和200 ℃时,采用电热爆炸喷涂技术在IC10合金表面制备NiCoCrAlY合金粘结层.利用扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD),对热循环前后的粘结层的组织形貌、化学成分及相进行分析.结果表明,基板温度对电热爆炸喷涂技术所制备NiCoCrAlY合金粘结层有明显的影响,随着基板温度的升高,所制备的粘结层与基体界面结合良好,表面粗糙度减小.在1050 ℃热循环后粘结层表面生成了Al2O3氧化层,起到了保护基体的作用.     

Characterization of micro-crack propagation through analysis of edge effect in acoustic microimaging of microelectronic packages

The miniaturization and three dimensional die stacking in advanced microelectronic packages poses a big challenge to their non-destructive evaluation by acoustic microimaging. In particular, their complicated structures and multiple interfaces make the interpretation of acoustic data even more difficult. A common phenomenon observed in acoustic microimaging of microelectronic packages is the edge effect phenomena, which obscures the detection of defects such as cracks and voids.In this paper, two dimensional finite element modelling is firstly carried out to numerically simulate acoustic microimaging of modern microelectronic packages. A flip-chip with a 140 µm solder bump and a 230 MHz virtual transducer with a spot size of 16 µm are modelled. Crack propagation in the solder bump is further modelled, and B-scan images for different sizes of micro-cracks are obtained. C-line plots are then derived from the simulated B-scan images to quantitatively analyze the edge effect. Gradual progression of the crack is found to have a predictable influence on the edge effect profile. By exploiting this feature, a crack propagation characterization method is developed. Finally, an experiment based on the accelerated thermal cycling test is designed to verify the proposed method.     

Application of periodic operation to maleic anhydride production

Two-step and multi-step feed composition cycling of the partial oxidation of butadiene to maleic anhydride have been studied. Multi-step cycles were created by N₂ flushes between steps containing just one reactant. Both production and selectivity to maleic anhydride are decreased over a cycle in this type of periodic operation. Selectivity to furan is increased, however. N₂ flushing concentrates production of maleic anhydride in the butadiene step, which may have process advantages.     

Dung pads increase pasture production,soil nutrients and microbial biomass carbon in grazed dairy systems

In grazing systems dung is an important source of nutrients which can increase soil fertility and contribute to nutrient cycling through increased pasture production. Changes in soil chemical and biological properties and pasture production were measured below and around dung pads created in the field. Almost 65% of the total dung P remained after 45 days and about two-thirds of the pad fresh weight had disappeared in that time, indicating that physical degradation is the mechanism of incorporation of dung P. All the pads bar one were completely degraded by 112 days. At this time, soil pH and EC increased under dung pads as did Olsen extractable inorganic phosphorus (Pi) and total phosphorus (Pt), with these changes observed at 0–5 and 5–10 cm depths. Bicarbonate extractable soil organic phosphorus (Po) was not affected by dung and the observed differences in soil Po:Pi ratios were largely influenced by the substantial addition of inorganic P from dung. Dung increased the P buffering capacity of the 0–5 cm soil samples collected at the end of the experiment, potentially contributing to the increased extractable soil P measured under the pads. Dung also changed soil properties in 0–10 cm samples with increases in soil pH, EC, Colwell P and Colwell K recorded even long after the dung had completely disappeared. Microbial biomass carbon increased under dung pads in the 0–10 cm soil samples in the first 45 days after pads were applied. Total herbage production and ryegrass biomass increased significantly under and around the pads by 112 days after dung was applied. The botanical composition changed significantly with increased ryegrass contents observed, but only under the dung pads. This experiment demonstrated that increases in pasture around dung pads in the field are not solely due to animal rejection.     

压制参数对TATB基PBX膨胀特性的影响

对采用不同工艺参数(压力、药温)压制成型的TATB基PBX药柱进行了热循环试验。研究了压制参数对TATB基PBX药柱膨胀特性的影响,并对其影响机理进行了分析。结果表明,在药温恒定(110℃)条件下,增加压制压力,药柱轴向高度的不可逆膨胀增大,而药柱体积的不可逆膨胀却减小;压力恒定(170M Pa)时,降低药温,药柱轴向高度和整体体积的不可逆膨胀都有所减小。分析认为这是由于不同压制参数导致成型过程晶体取向度不同和晶体破碎程度不同所引起的。     

Thermal barrier coating bonded by (Al2O3–Y2O3)/(Y2O3-stabilized ZrO2) laminated composite coating prepared by two-step cyclic spray pyrolysis

Thermal barrier coating bonded by (Al₂O₃–Y₂O₃)/(Y₂O₃-stabilized ZrO₂) (YSZ) laminated coating has been developed on Ni-based superalloy by two-step cyclic pyrolysis. It is demonstrated, from cyclic oxidation tests at 1100 °C, that YSZ top coat and alloy substrate can be bonded together effectively by the (Al₂O₃–Y₂O₃)/YSZ laminated coating, showing good resistance to oxidation, cracking, spallation and buckling. These beneficial effects can be attributed to the sealing effect of the designed multi-sealed compact bond coat with α-Al₂O₃ layers, the decrease of thermal stresses, the increase of fracture toughness in such bond coat and no interdiffusion between the substrate and bond coat.     

Influence of preparation temperature on the oxidation resistance and mechanical properties of C/SiC coated C/C composites

A C/SiC oxidation resistance coating was prepared on carbon/carbon (C/C) composites by slurry and pack cementation. The microstructure, oxidation resistance and mechanical properties of C/SiC coating prepared from 1773 to 2573 K were investigated. With the increase of the preparation temperature, the oxidation resistance of C/SiC coating increases, however, the flexure strength decreases gradually. The preparation of C/SiC coating on C/C composites results in the fracture behavior of C/C composites changing from pseudo-plastic to brittle failure model. The decrease of flexure strength is mainly attributed to the decrease of C/C matrix’ flexure strength at high temperature.     

粉末粒度对AB5型合金电化学性能的影响

研究了粉末粒度对AB5型储氢合金电化学性能的影响.结果表明当合金粉末粒度为22.49～163.8 μm时,随粉末粒度的减小,储氢合金电极的电化学容量降低;由于粉末粒度大的电极负极充放电循环寿命的衰减率小于粉末粒度小的衰减率,所以随粉末粒度的减小,储氢合金电极材料充放电循环寿命缩短.     

CA-SA分子合金的制备及储热性能研究

用差示扫描量热仪(DSC)分析研究了癸酸(CA)/硬脂酸(SA)二元混合物的热性能,结果表明,CA-SA合金没有一个确定的低共熔点,只有一个配比范围,并用IR和DSC对81%CA-SA二元混合物经180次加速冷热循环前后的分子结构和热性能进行对比研究,分析表明,此共熔物的分子结构没有发生变化,相变温度和相变焓变化较小,热性能稳定,适合作为相变储能材料。     

EB-PVD梯度热障涂层的制备及其热疲劳性能

采用ＥＢ－ＰＶＤ的方法,连续蒸发按一一分比混合的Ａｌ＋Ａ１２Ｏ３＋ＺｒＯ２混合源,在Ｎｉ基高温合金基体上制备了一种新型结构的热障涂层,ＳＥＭ和ＥＤＳ的观察、分析表明,这作层实现了由金属粘结层向陶资顶层的微观结构的梯度过渡和化学成分的连续变化。涂层的基本结构为ＮｉＣｏＣｒＡ１Ｙ／Ｎｉ３Ａｌ＋Ａ１２Ｏ３／Ａ１２Ｏ３ＺｒＯ２／ＺｒＯ２。这北度热障涂层在１０５０℃的抗高温氧化性能优于传统的二层结构的热障涂