Effect of TiO2 thin film thickness and specific surface area by low-pressure metal–organic chemical vapor deposition on photocatalytic activities

TiO₂ photocatalyst films having an anatase crystal structure with different thickness were prepared by the low-pressure metal–organic chemical vapor deposition (LPMOCVD) to examine the effect of growth conditions on photocatalytic activity. Film thickness was linearly proportional to the deposition time. Structure of the film was strongly dependent on the deposition time. In early stage of deposition, fine particles deposit on the substrate. As increasing the deposition time, crystal orientation is gradually selected following the Kolmogorov model and c-axis oriented columnar crystals become dominant. The photocatalytic activity strongly depends on the film deposition time (or film thickness) in nonlinear way. The optimum thickness of TiO₂ catalyst film grown by LPMOCVD may locate between 3 and 5 μm.     

涂料原料和涂层厚度对反射隔热保温性能影响研究

通过研究涂料配方中所用乳液、颜料、常规填料和隔热填料在红外灯下的反射、隔热和保温性能，发现高折射率的二氧化钛和含有微孔的硅藻土具有最佳的反射和隔热保温效果，轻质碳酸钙和重质碳酸钙具有一定的隔热保温作用，而理论上具有隔热保温效果的填料海泡石等并没有预期的效果。涂层厚度对隔热保温效果具有一定影响，但是没有颜料和填料的影响大。隔热涂料使用的填料应含有硅藻土、二氧化钛以及一些常规的填料。     

基于远程监控图像的绝缘子覆冰检测算法

提出一种基于远程监控图像的绝缘子覆冰情况检测算法。本文算法充分利用边缘检测方法和其他图像处理方法,对覆冰绝缘子侧面冰棱的边缘情况进行精确的检测。本文算法还引入了摄像头的标定参数,使其能更加准确地估计覆冰绝缘子侧面的冰棱长度。当摄像头因为外力或其他因素而产生角度偏移时,本文算法能及时地对摄像头标定参数做出修正,并利用新的标定参数重新估计绝缘子的覆冰情况。实验结果表明,本文算法对绝缘子侧面冰棱边缘检测效果显著,满足实时监控和预警报警的要求。     

薄壁注塑成型技术

由于3C产品向“轻、薄、短、小”方向发展得越来越快，所以薄壁注塑成型技术也受到人们高度重视。介绍了薄壁注塑成型技术产生的背景及其优点，分析了薄壁注塑成型的定义，综述了薄壁注塑成型中的注塑机、模具设计、制品设计和材料选用，探讨了薄壁注塑成型中所面临的主要问题。     

Theoretical studies of displacement deposition of nickel into porous silicon with ultrahigh aspect ratio

A model is developed to address the uniformity of displacement deposition of nickel inside porous silicon with an ultrahigh aspect ratio as high as 200. The nickel distribution is treated as a current distribution issue as in electrodeposition. It is shown that the deposition distribution along the pore depth exhibits a strong dependence on a polarization parameter ξ. High values of ξ correspond to mass transport limitations and lead to non-uniform distributions, whereas small ξ values, representing interfacial reaction control, produce uniform distributions. Non-uniform deposition primarily occurs at an initial stage in which the reaction is dominated by mass transfer. As the deposition process continues, the deposition rate drops to a low value, and the deposition uniformity shifts from Ni²⁺ mass transport limitations to its interfacial reaction control, leading to uniform Ni²⁺ concentration and deposition rate distributions. It is predicted that the non-uniformity at the initial stage could be remedied by increasing the bulk concentration of the nickel ions and decreasing the plating bath pH. In addition, the uniformity of the deposition distribution can be significantly improved by introducing inhibiting additive coumarin to the plating solution.     

换热器管板厚度的快速计算

在化工生产中，换热器设备是应用最广泛的一种设备，且占主导地位。而在换热器设计过程中，管板厚度设计计算比较复杂。本文的特点是在满足GB151—1999《管壳式换热器》标准要求的前提下，介绍一种快速简便估算管板厚度的计算公式，从而达到快速确定管板厚度的目的。     

An Experimental Study of Fatigue Strength for Adhesively Bonded Tubular Single Lap Joints

In this paper, manufacturing technology of the tubular single lap adhesive joint was studied to obtain reliable and optimal joint quality. In addition, a surface preparation method and a bonding process for the joint were devised. The effect of the adhesive thickness and the adherend roughness on the fatigue strength of the joint was experimentally investigated. From experiments, it has been found that the fatigue strength of the joint increased as the adhesive thickness decreased and the optimal arithmetic surface roughness of the adherends was about 2 μm.     

螺旋侧板厚度对浮式风力机Spar平台涡激载荷的影响

Spar平台因其特殊的深吃水立柱式结构,在来流影响下极易发生涡激运动。为探究不同厚度螺旋侧板对浮式风力机Spar平台涡激载荷的影响,基于CFD方法,针对不同厚度螺旋侧板,对平台进行了数值模拟并详细分析平台的升阻力系数、压力场及涡量场等流场参数。结果表明:螺旋侧板可有效抑制涡激载荷,且随厚度增加,升力系数幅值先增加后减小,阻力系数逐步减小;在研究范围内,螺旋侧板厚度为0.10 D时,升力系数幅值最小,阻力系数与原型平台在同一范围内,对涡激载荷的抑制效果最好。     

降膜波动特性的研究

本文提出了一种测定膜厚的新方法－双电导探针法，测定了高湍流降膜的厚度沿降膜管管程的变化情况，探讨了径向平均膜厚及膜厚的概率密度分布沿管程的变化规律，证明降膜的波动特性同时受到液相雷诺数和管程的影响。并对平均膜厚和液相雷诺数作了经验关联，得出NT＝（δ^ )^2/3 [8.92(ReL/4)^5/2 6.0×10^-6(ReL/4)^9/2]^2/15。     

工业管道测厚技术在化工厂的应用

本文较为详细地介绍了工业管道的规范化管理及其在化工厂的应用。指出管道定期定点测厚和计算机管理是工业管道规范化管理的重要内容。通过实施这一管理措施可以提高企业的经济效益和社会效益。