枪黑色Sn-Ni合金在NaOH溶液中的析氢电催化性能

为了降低电解制氢的电耗,提高经济效益.作者对枪黑色Sn-Ni合金在NaOH溶液中的析氢电流化性能进行了研究.试验测出的电化学参数表明,在NaOH溶液中电解制氢时,枪黑色Sn-Ni合金的析氢电催化性能比45钢和高硫镍的强很多,而且具有很高的电化学稳定性.用它取代目前工业上使用的45钢和高硫镍作为电解制氢的阴极,可显著降低制氢的生产成本.     

等离子喷焊铜基自熔性合金的研制

为了克服铜铁异种材料喷焊过程中易产生焊缝裂纹和基体裂纹的倾向,研制开发了一种Cu-Ni-Sn自熔性合金粉末材料.通过对Cu-Ni-Sn粉末材料的化学成分的设计,喷焊层的组织显微结构及抗腐蚀性能的综合分析,认为该材料等离子喷焊工艺性能良好,焊层耐腐蚀效果十分明显.在生产实际中应用等离子喷焊制备Cu-Ni-Sn焊层,能明显提高粉末材料的熔敷率和性能,并且改善劳动工作环境.该合金性能优于传统材料,值得推广.     

Microstructure developed in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum

Microstructural changes in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum have been studied by means of scanning and transmission electron microscopy (SEM and TEM). The wear rates of Ti-6Al-4V alloy in vacuum were measured under different sliding velocities and loads. The experimental results showed that a severely deformed layer with a grain size of 50–100 nm and thickness about 70 μm was formed underneath the worn surface. Under the slower sliding velocities, the substructure of the layer had a high dislocation density, while under higher sliding velocities, twins were found to exist in the substructure. A process by which the deformed layer formed has been proposed and the deformation of materials at the contacting spots of the Ti-6Al-4V sample is discussed.     

Synthesis of TiO2 nanopellet by TiCl4 as a precursor for degradation of RhodamineB

In the present investigation in order to promote TiO₂ pellet structure and its photocatalytic activity, two new precursors were synthesized in the powder and sol forms, using sol–gel method with precipitation of TiCl₄. Since TiO₂ pellets are normally synthesized by the commercial TiO₂ powder (DegussaP25), in this investigation and in the first step a new synthesized TiO₂ powder was produced and compared with DegussaP25. Subsequently, two types of pellet were made by the new synthesized powder and titania sol. The characterization of the synthesized TiO₂ powder and pellet were performed by XRD, FT-IR, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The result showed that by the new procedure utilized here, without using any additive not only the surface area of the produced TiO₂ powder has been increased, but also the crystalline phase is completely in the anatase form. It was also found that the synthesized pellets by the sol precursor had better morphological structure than the synthesized pellets by theTiO₂ powder (either DegussaP25 or new synthesized powder). Ultimately, in order to evaluate photocatalytic activity of TiO₂ powders and pellet, degradation of RhodamineB was tested.     

Mg-Ca-Mn、Mg-Ca-Sr三元生物镁合金制备与研究

为了改善Mg-Ca二元生物镁合金的力学性能和体外降解性能,分别制备了Mg-Ca-Mn和Mg-Ca-Sr三元合金,比较了3种合金的显微组织、力学性能及在Hanks溶液中的降解性能.实验结果表明,Mg-Ca-Sr合金的力学性能和体外降解性能较好,抗拉强度为230MPa,析氢腐蚀速率为0.042 mL/(d·cm2).     

两种不同焊丝对7A05铝合金焊接性的影响

选择两种焊丝,对Al Zn Mg系合金7A05 T6进行焊接性研究。焊接裂纹试验结果表明,采用两种焊丝焊接7A05合金时,接头均具有较好的抗热裂纹敏感性。两种焊丝焊接接头的拉伸强度均为母材强度的75%以上,经过时效处理的焊接接头力学性能有了明显的提高。分析认为微观组织中沉淀物质点越小,均匀分散到晶界上越多,接头的拉伸强度越高。     

Annealing process of fine grained co-stabilised (Y,Mg)-PSZ/MgAl2O4 ceramics

Abstract

Co-stabilised (Y,Mg) partially stabilised zirconia (PSZ) ceramics with MgAl₂O₄ spinel additions were produced, with industrial zirconia as the main starting material. Powders were prepared using a mechanical milling–mixing process. The effect of the annealing process on the mechanical properties, phase compositions, and microstructure of fine grained PSZ ceramics was investigated.     

Al—Zn—Mg—Cu合金的超塑性变形力学行为

介绍了一种新的超塑性处理工艺,采用简单的预处理工艺结合升温拉伸,可以使合金获得优异的超塑性,轧制形变组织在拉伸过程中发生动态再结晶,形成细晶组织并赋予合金优异的超塑性。     

半不连续切屑流动速度的系统分析及切屑变形的度量

本文借助影片运动分析仪,对用高速摄影记录的钛合金切屑沿前刀面的流动规律进行了研究,并用系统分析法进行了描述,推导出能反映半不连续切屑不均匀变形过程的动态衡量参数,同时也导出了度量此种切屑塑性变形的准静态参数——等效切削比。     

钛元素对铝钛合金中铝含量测定的干扰

在纯铝标样中加入相应的钛元素为标准,采用ＥＤＴＡ滴定法,测试钛元素对铝钛合金中铝含量测定的干扰。实验证明,钛对铝的测定干扰十分严重。文章给出了正确测定铝含量的方法。