Phase behavior,density, and crystallization of polyethylene in n‐pentane and in n‐pentane/CO2 at high pressures

The phase behavior and volumetric properties of polyethylene (PE) in solutions of n‐pentane and n‐pentane/CO₂ were studied in a temperature (T) range of 370–440 K at pressures up to 60 MPa. Measurements were conducted with a variable‐volume view‐cell system equipped with optical sensors to monitor the changes in the transmitted light intensity as the P or the T of the system was changed. Lower‐critical‐solution‐temperature‐type behavior was observed for all of the liquid–liquid (L–L) phase boundaries, which shifted to higher pressures in solutions containing CO₂. The solid–fluid (S–F) phase boundaries were investigated over a P range of 8–54 MPa and took place in a narrow T range, from 374 to 378 K in this P interval. The S–F phase boundary showed a unique feature in that the demixing temperatures showed both increasing and decreasing trends with P depending on the P range. This was observed in both the PE/n‐pentane and PE/n‐pentane/CO₂ mixtures. The density of these solutions were measured as a function of P at selected temperatures or as a function of T at selected pressures that corresponded to the paths followed in approaching the phase boundaries (S–F or L–L) starting from a homogeneous one‐phase condition. The data showed a smooth variation of the overall mixture density along these paths. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2201–2209, 2003     

V波段小型化低相噪频率综合器

本文研究了一种V波段超小型低相噪频率综合器,研制了L段捷变频频综、Ku波段取样锁相源、上变频组件、倍频器等四个小型化组件.为了得到较低的相位噪声和捷变频速度,本捷变频频综采用上变频-倍频方案,其中DRO PLS保证低相位噪声性能,L波段捷变频频综保证捷变频功能.该频综尺寸为100×80×30mm³,相位噪声低于-86dBc/Hz(1kHz),捷变频时间小于40μs,杂波抑制优于-60dBc.     

反铁磁晶体的红外频率特性

研究了红外频段非线性s偏振表面波在反铁磁晶体和电介质交界面上的频率特性，求出了非线性色散方程，揭示了非线性s偏振表面波存在一个临界频率，低于这个频率，非线性s偏振表面波的频率范围，发现功率不再是决定导波频率范围的唯一因素，两种材料的介电常数比在这里起了至关重要的作用。     

中扬子及邻区层序地层与原型盆地演化

中扬子及邻区原型盆地可划分为 9个大层序,其中,1～6大层序由中、古生代海相地层组成;第 7大层序为早、中侏罗纪的陆相沉积;第 8大层序为晚侏罗世的前渊沉积;第 9层序为晚白垩世至第三纪的伸展盆地。震旦纪,中部地区为台地相环境,向南为浅海陆棚环境,向北以陆表海为主;寒武纪至早奥陶世为典型的大陆边缘盆地;中、晚奥陶世至志留纪为裂谷盆地发展阶段;泥盆纪至石炭纪该区发生广泛海侵,与华南海域和太平洋海域多处相连;二叠纪至早、中三叠世为原型盆地的重要转型时期,随着分隔秦岭微板块与扬子板块的勉略古洋盆向东打开,扬子北缘由前期的区域性隆起转变为向北加深的大陆边缘盆地;晚三叠世经历了两次幕式旋回,巴东组沉积时期盆地沉降缓慢,九里岗组沉积时期则较快;早、中侏罗世原型盆地早幕 (早侏罗世)沉积缓慢,晚幕 (中侏罗世)快速沉降,以水下沉积作用为主;晚侏罗世可划分为两大构造演化阶段,早期构造活动相对平静,晚期强烈;晚白垩世至老第三纪,盆地范围缩小,以湖泊、河流体系为主。由此,中扬子及邻区在地质历史时期经历了 4种不同性质的原型盆地,具有幕式充填特征。     

两相异步电动机变频调速装置

主要讨论对称两相变频器主电路的结构以及介绍一种简单实用的磁链轨迹控制技术．     

液闪效率示踪法校正效果的评价

本文评价了Aloka商品液闪仪效率示踪法dpm校正的效果。轻,中度猝灭校正效果理想,具有简便、实用和适用性广泛的特点。严重化学和颜色猝灭样品的校正结果分别随猝灭增加而向增大和减小的方向偏离,形成喇叭状曲线,文中对这一现象给出初步解释。     

油气微运移的烃类相态

微运移机制是目前油气化探等非地震直接找油的理论基础,只有研究清楚油气微运移的相态,才可能进一步研究微运移的机制;含油气水相是油气发生微运移最普遍和优先起作用的相态;在特定的地质条件下,不排除油气以其它相态发生渗漏的可能。     

Interfacial reactions in In-Sn/Ni couples and phase equilibria of the In-Sn-Ni system

The In-Sn-Ni alloys of various compositions were prepared and annealed at 160°C and 240°C. No ternary compounds were found; however, most of the binary compounds had extensive ternary solubility. There was a continuous solid solution between the Ni₃Sn phase and Ni₃In phase. The Sn-In/Ni couples, made of Sn-In alloys with various compositions, were reacted at 160°C and 240°C and formed only one compound for all the Sn-In alloys/Ni couples reacted up to 8 h. At 240°C, Ni₂₈In₇₂ phase formed in the couples made with pure indium, In-10at.%Sn and In-11at.%Sn alloys, while Ni₃Sn₄ phase formed in the couples made of alloys with compositions varied from pure Sn to In-12at.%Sn. At 160°C, except in the In/Ni couple, Ni₃Sn₄ formed by interfacial reaction.     

Application of annexation principle of thermodynamic property of In-Pb-Sb and In-Bi-Pb melts

Based on the principle of annexation and phase diagrams, the structural units of In-Pb-Sb and In-Bi-Pb melts were determined, and their calculating models of mass action concentrations were formulated. Calculated results agree well with practical values, which in turn show that the models deduced can reflect the structural realities of corresponding melts and the principle of annexation is applicable not only to some binary metallic melts, but also to ternary metallic melts.     

位山引黄灌区泥沙淤积原因及处理对策

位山灌区是黄河下游大型引黄灌区 ,渠系泥沙淤积严重 ,泥沙处理困难。通过采用远距离输沙、集中处理沉沙区泥沙、分散沉沙和节水减淤等技术措施 ,减少了渠系的泥沙淤积。对清淤产生的泥沙 ,采取综合开发利用的技术和管理措施 ,取得了比较可靠的效果。