EIS evaluation of the filiform corrosion of aluminium coated by a cataphoretic paint

Filiform corrosion is mainly considered as a cosmetic attack and is undesirable in most applications. The initiation and propagation of the filaments are related to different parameters such as the presence of defects, the permeability of the coating to water and oxygen, the adherence of the paint system and the presence of salts.

The aim of this work is to study the behaviour of painted aluminium samples towards filiform corrosion or delamination. The 6082 Aluminium alloy was selected and the samples were covered with a cataphoretic epoxy primer without lead (PPG Industries France). Prior to the application of the electrocoat, the samples were pre-treated by a commercial Zr/Ti or chromate conversion treatment or simply etched with a commercial acid etching product.

Filiform corrosion was studied by the normalized test (ISO/DIS 4623): painted and scratched samples were inoculated in HCl and exposed in a constant humidity chamber at 40 °C and 82% RH for 3 weeks. After exposure the samples were subjected to a visual and optical microscopic examination.

Electrochemical impedance spectroscopy was used to study the sensitivity to filiform corrosion. The operating mode of this test is similar to the normalized one. The samples were scratched before inoculation for 1 h in HCl and then exposed to the humidity chamber for a maximum of 4 days. The samples were tested by EIS in an acidified 0.1 M Na₂SO₄ electrolyte solution. The resulting impedance spectra were analyzed with an appropriate equivalent electrical circuit which allows the evaluation of the exposed metallic surface area, directly related to the extent of filiform corrosion or delamination. Different parameters were varied: the exposure time in the humidity chamber; the immersion time in the electrolyte sulphate solution as well as its pH and the coating thickness.     

西霞院水利枢纽工程泄洪闸振冲碎石桩基础处理

通过西霞院水利枢纽工程泄洪闸振冲碎石桩基础处理施工方法论述,给出了加砂层振冲碎石桩施工造孔水压、水量、成孔速度、填料级配、填料方法以及振密电流值、留振时间等施工控制参数。     

Grain Growth Behavior of 5Cr21Mn9Ni4N Steel Micro-Alloyed by Rare Earth

Grain growth behavior of 5Cr21Mn9Ni4NRE steel was experimentally studied at various solid solution treatment temperatures and holding for different times. The experimental results show that the 5Cr21Mn9Ni4NRE steel has the feature of sharp austenite grain coarsening after solid solution treatment at the temperature above 1150 ℃. RE added in the steel has the benefit to restrain grain growth and increase grain growth activation energy.     

Amorphous diffusion bonding of steel pipe and its impact toughness

An iron-based amorphous foil (FeNiCrSiB) was used as an interlayer for the amorphous diffusion bonding of low carbon steel pipes under argon flux. The microstructure and mechanical properties of the joint were analyzed using an electron probe micro-analyzer (EPMA), tensile test, bending test and impact test. The results show that the joint microstructure resembles that of the base metal and no precipitates form at the joint. Melting point depressants (B, Si) diffuse far away from the joint and the base metal element is homogenous across the joint. The joint impact toughness is greater than the base metal toughness and the mechanical properties of the joint are similar around the pipe.     

Study of liquid injection impact on the performance of new refrigerant mixtures

In this paper, the test results of liquid injection impact on the performance of new alternative refrigerant mixtures such as: R-410A, R-507, R-407C and R-404A are discussed, analysed and presented. The test results were obtained using an air-source heat pump set-up with enhanced surface tubing under various liquid injection ratios. Performance tests were conducted according to the ARI/ASHRAE standards. The performance data demonstrated that as liquid injection ratio increases, compressor head pressure and discharge temperature decrease. This has a positive effect in protecting the compressor. The effect of liquid injection on mixture behaviour varies from one mixture to another depending upon the mixture's composition. Furthermore, liquid injection appears to have a significant influence on R-410A behaviour compared to the other mixtures in question. Copyright © 2002 John Wiley & Sons, Ltd.     

超声波流量计计量系统性能的主要影响因素

随着我国天然气工业的发展，已有大量超声波流量计用于高压、大流量的天然气计量。尽管我国已于2001年颁布并实施了气体超声波流量计使用方面的国家标准GB/T18604-2001，但是随着超声波流量计越来越广泛的使用，国内外对超声波流量计计量性能的影响因素已有了进一步的研究；而且，目前我国超声波流量计在天然气计量中的应用效果也还需要进一步改善。因此，根据目前国、内外最新研究成果，对噪声、脏污、压力及温度测量对超声波流量计计量系统性能的主要影响因素以及控制对策进行了分析探讨，以期改变虽经实验室检定合格、但用于现场却不能达到预期计量性能效果的情况，使超声波流量计在现场能够得到更好的应用。     

摩擦焊在钢制实心抽油杆修复中的应用

通过对焊接工艺及焊后热处理工艺优化，采用摩擦焊接技术对报废抽油杆中仍有使用寿命的杆头与杆体进行了拼接，获得了性能达标的抽油杆。从而提高了旧杆的修复率．降低了采油成本。该技术可在抽油杆修复及相关行业进行推广应用。     

探讨电石法PVC烟气治理方法

分析了电石法PVC生产链中电石炉烟气及电厂烟气二氧化硫的排放情况,指出利用电石炉烟气中的CO合成氨、再将合成氨用于燃煤电厂烟气的"氨法"脱硫是具有较大应用潜力的循环经济产业链。     

未增塑聚氯乙烯(PVC-U)异型材配方基础

PVC-U异型材配方十分复杂,常用原料通常在10种以上。根据大连实德集团实际生产情况,这10多种原料通常以7大组分的方式进行配料和生产。文中就该配方中7大组分的分类、特点及应用情况分别进行了详细介绍。     

Dynamic response and behavior of reinforced concrete slabs under impact loading

Reinforced concrete slabs are among the most common structural elements. In spite of the large number of slabs designed and built, the effect of their details on their behavior under impact loads are not always appreciated or properly taken into account. This experimental study was aimed at understanding the dynamic behavior of structural concrete slabs under impact loading to improve the state of the art of protective design. This study investigated the effects of different types of slab reinforcements and the applied impact loads on the dynamic response and behavior of reinforced concrete slabs.