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61.
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63.
The thermoelectric power of the vanadates of potassium, cesium and lithium and their solid solutions was measured in the temperature
range covering their transition points. The thermoelectric power measurement was carried out by the two-electrode technique
for pellets of polycrystalline ceramic samples. The thermoelectric power increased with temperature initially, then decreased
attaining a zero value at the transition temperature. As the concentration of KVO3 increased the thermoelectric power decreased for the solid solutions (K
x
− Cs1−x
)VO3, whereas the thermoelectric power increased with increase in concentration of KVO3 for the solid solutions (K
x
− Li1−x
)VO3. Vanadates of potassium, cesium, and lithium and their solid solutions showedP type semiconductor behaviour in ferroelectric state andn type semiconductor behaviour in paraelectric region. 相似文献
64.
Jingheng Deng Jingyuan Jiang Yuanyuan Zhang Xiaoping Lin Changming Du Ya Xiong 《Applied catalysis. B, Environmental》2008,84(3-4):468-473
The iron vanadate, FeVO4, was prepared and characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM). It was found that FeVO4 could effectively catalyze H2O2 to generate active hydroxyl radical OH, which was confirmed with electron spin resonance (ESR) spin-trapping technique. Therefore, it was employed as a heterogeneous Fenton-like catalyst in the present contribution, and its catalytic activity was mainly evaluated in terms of the degradation efficiency of Orange II. Compared with the conventional heterogeneous Fenton-like catalysts, α-Fe2O3, Fe3O4 and γ-FeOOH, FeVO4 possessed a much higher catalytic activity. The high catalytic activity possibly involved in a special two-way Fenton-like mechanism, that is, the activation of H2O2 by both Fe(III) and V(V) in FeVO4. Moreover, FeVO4 possessed a wide applicable pH range and its catalytic activity was slightly affected by the solution pH values in the range of 3–8. 相似文献
65.
采用共沉淀法合成Mg/Al摩尔比为2:1的层状双金属氢氧化物Mg/Al-LDH,并在500℃下煅烧6 h得到煅烧双金属氢氧化物Mg/Al-CLDH。研究Mg/Al-CLDH对钒酸根的吸附性能,探讨镁铝摩尔比、吸附剂用量、溶液初始浓度、时间和温度等因素对吸附效果的影响,并对其吸附过程的动力学和热力学过程进行研究。研究表明:Mg/Al-CLDH 对钒酸根的吸附效果很好。该吸附过程符合准一级动力学方程,平衡吸附等温线很好地符合Langmuir方程,并且Langmuir方程拟合常数高达0.999。通过热力学计算发现ΔGΘ为负值,ΔHΘ为正值,表明此吸附本质上是吸热自发过程。吸附机理研究表明此吸附主要是表面吸附。 相似文献
66.
《分离科学与技术》2012,47(17):2943-2958
ABSTRACTIron vanadate (FeVO4) nanoparticles were synthesized by hydrothermal method and used as heterogeneous Fenton-like catalyst in ultrasound (US)-assisted degradation of Acid Blue 113. By using a quadratic response surface model, more than 99% color removal and 80% TOC reduction were obtained using low amounts of catalyst and H2O2 at short reaction time and circumneutral pH condition. The synthesized nanocatalyst also exhibited a good reusability under US irradiation. The results indicate that the proposed sono-Fenton-like process is efficient for the treatment of recalcitrant compounds in industrial effluents. 相似文献
67.
68.
Shilei Xie Teng Zhai Yongjie Zhu Wei Li Rongliang Qiu Yexiang Tong Xihong Lu 《International Journal of Hydrogen Energy》2014
Photoelectrochemical water splitting has attracted increasing attention recently in the perspective of clean and sustainable energy economy. Herein, we reported the synthesis of NiO functionalized Mo doped BiVO4 (denoted as NiO/Mo:BiVO4) nanobelts and their enhanced photoelectrochemical activity for efficient water oxidation. The prepared NiO/Mo:BiVO4 p–n junction structure showed much higher water splitting activity than the pristine BiVO4 and Mo:BiVO4. Such obvious enhancement are due to the increased donor density by doping with Mo and fast separation of the photoexcited electron–hole pairs by the novel p–n junction composite structure. Under light irradiation, photoexcited holes in the conduction band (CB) of Mo:BiVO4 will conveniently transfer to the p-type NiO with the effect of the inner electric field. Meanwhile, the holes would oxidize the water into oxygen and the electrons transfer to the counter electrode (Pt electrode) to produce hydrogen. This novel p–n junction structure could open up new opportunities to develop high-performance photoanode for water splitting. 相似文献
69.
Sang-Hyun Song Sung-Eun Yoon Jaewon Choi Byung-Kook Kim Jong-Sung Park 《International Journal of Hydrogen Energy》2014
The composite electrodes for protonic ceramic fuel cells (PCFC) were fabricated by infiltration of (La0.8Sr0.2)FeO3−δ (LSF) cathode and (La0.7Sr0.3)V0.90O3−δ (LSV) anode into a porous protonic ceramic, Ba(Ce0.51Zr0.30Y0.15Zn0.04)O3−δ (BCZY-Zn), respectively. Further, Pd-ceria catalysts were added into the composite anode. In the same method, the oxygen ion conducting fuel cells with the yttria-stabilized zirconia as an electrolyte (YSZ cell) were also fabricated. At 973 K, the non-ohmic area specific resistance (ASR) of PCFC (0.09 Ω cm2) was much smaller than that of the YSZ cell (0.28 Ω cm2) although the protonic conductivity of BCZY-Zn was slightly smaller than the oxygen ion conductivity of YSZ. According to the analysis of the symmetric cells with BCZY-Zn as an electrolyte, the LSV-composite anode showed better performance than the LSF-composite cathode at low temperatures. 相似文献
70.
The process of acid leaching of calcification roasted vanadium slag was studied. The effects of process parameters variation on phase of the vanadium leaching residue, leaching rate of vanadium and the reason of vanadium loss were analyzed. The results showed that the main phase of vanadium leaching residue was insoluble in acid of dense solid solution R2O3 and Fe2TiO5, which was also mixed with silicate pyroxene phase and small amount of vanadate phase. The vanadium leaching rate first increased and then decreased with raising the roasting temperature, roasting time and the CaO/V2O5 mass ratio. Silicate species and its effect on vanadate, spinel oxidation incomplete, vanadium and vanadium bronze solid solution in of R2O3, and the difference of best leaching acidity of Ca3V2O8, Ca2V2O7 and CaV2O6 were the causes of vanadium loss. 相似文献