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91.
当HDPE含量46%(质量分数,以下同)、其它添加剂(如抗氧剂、阻燃剂、交联剂和润滑剂等辅助填料)的含量11%,两种导电填料石墨(GP)和碳黑(CB)的总含量为43%时,研究结果表明石墨含量的变化对HDPE/CB-GP复合材料室温电阻率、阴C强度和后NTC强度有显著的影响.HDPE/CB-GP复合材料中GP的含量〈8.6%时,样品的室温电阻率〈30Ω·m,PTC强度〉7、后NTC强度〈1.3;电阻率.温度曲线经过17次冷热循环后重现性好,复合材料具有实际应用价值;GP在复合材料中为层片状结构。 相似文献
92.
刘道杰 《石油工业计算机应用》2007,15(4):32-34,37
模拟退火算法是一种利用统计力学观点求解优化问题全局最优解的方法,是目前解决优化问题的一种比较先进的方法。本文应用模拟退火算法对蒸汽吞吐注采参数进行优化设计,并确定出了6个吞吐周期的最优周期产油量和周期注蒸汽量,较实际周期产油量和实际周期注汽量均有明显增加。将各周期的优化累积产油量和优化累积注汽量画在累积产油量与累积注汽量的双对数坐标中,得出累积注汽量和累积采油量关系曲线(简称注采关系曲线)。将该注采关系曲线外推估算了该井未来周期的累积产油量和累积注汽量,从而达到对蒸汽吞吐井生产能力的预测。 相似文献
93.
Yunpeng Wang Zhaoyun Wang Changyi Zhao Hongjun Wang Jinzhong Liu Jialan Lu Dehan Liu 《Journal of Petroleum Geology》2007,30(4):339-356
In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C1‐5) and methane (C1) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C1‐5 (Ea = 59‐72kcal, A = 1.0×1014 s?1) and C1 (Ea = 61‐78kcal, A = 6.06×1014 s?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×1014 s?1 for C1‐5; and Ea = 48‐72kcal, A=3.9×1013 s?1 for C1, respectively). Using these kinetic parameters, both the yields and timings of C1‐5 and C1 hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression. 相似文献
94.
In an effort to investigate the mechanism of catalysis of titanium tetrabutoxide on the polycondensation of poly(butylene terephthalate), alcoholysis and hydrolysis reactions were studied with the aid of model molecules. The retarding effect of water has also been taken into account. Appropriate kinetic equations are derived and discussed and the results compared with experimental data obtained at different molar ratios of reactants. 相似文献
95.
Hari B. Goyal M. O. Garg K. R. Rao R. D. Srivastava 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(2):49-56
The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid. 相似文献
96.
97.
98.
活性炭中甲烷水合物的生成动力学 总被引:6,自引:1,他引:5
在温度275.75-279.95K和压力5.6-9.6MPa的静置条件下,测定了14组甲烷水合物在活性炭中的生成动力学数据(压力-时间关系),分析了甲烷水合物在活性炭中生成的物理过程,结合边界层理论和结晶学原理,提出了单液膜传质控制机理的生成动力学模型,并求得了解析解,使用Levenberg-Marquardt方法拟合模型参数,模型预测值与实验值符合良好。 相似文献
99.
A model has been developed to study the effects of chemical kinetics on the residue curve maps (RCM) for reactive distillation systems with liquid phase splitting. In the model, chemical reaction can occur in both or only one of the two liquid phases. The heating policy V/V0=H/H0 is applied so that the kinetic effect can be described by a single parameter, the Damköhler number Da. The effects of reaction kinetics on pseudohomogeneous and heterogeneous mixtures have been compared. The properties of their RCMs are the same outside, but are fully different inside the liquid-liquid (L-L) region if they have different chemical equilibrium curves. Inside the L-L region, the chemical equilibrium curve coincides to a unique reactive liquid-liquid tie line in case that the pseudohomogeneous chemical equilibrium curve intersects with the L-L envelope. When the reaction occurs in only one of the two liquid phases, the residue curves inside the L-L region are strongly affected by the L-L envelope, especially at high Da. In the present paper, first an illustrative arbitrary reaction system, and then the reaction of cyclohexene with water to cyclohexanol are analysed with respect to their RCMs. 相似文献
100.
本文概要介绍了CAD 8903机芯采用国产集成电路CD7680,CD74211,DG4053实现音频、视频切换功能的电路,并对CD7680中音频信号处理电路的特殊用法进行了说明。 相似文献