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91.
We introduce a method for the computation of singular integrals arising in the discretization of integral equations. The basic method is based on the concept of admissible subdomains, known, e.g., from panel clustering techniques and -matrices: We split the domain of integration into a hierarchy of subdomains and perform standard quadrature on those subdomains that are amenable to it. By using additional properties of the integrand, we can significantly reduce the algorithmic complexity of our approach. The method works also well for hypersingular integrals. 相似文献
92.
制备了纳米级复合固体超强酸SO4^2-/ZrO2-Al2O3-SiO2催化剂,研究了其对乙酸和正戊醇酯化反应的催化作用,确定了反应的最佳条件:复合氧化物中n(Zr):n(AD:n(Si)=1:4:1,浸渍液(NH4)2SO4浓度为2mol/L,600℃焙烧3h,n(酸):n(醇)=1:1.4,催化剂用量为反应物料总质量的4.4%,在130℃下反应6h,乙酸戊酯的收率为89.13%。并通过XRD、IR、流动Hammer指示剂法以及TEM法对催化剂进行了表征,该催化剂的酸强度为-12.70〈Ho≤-11.99。 相似文献
93.
大型34CrMo1合金钢螺旋桨轴锻件的研制 总被引:1,自引:1,他引:0
大型34CrMo1合金钢螺旋桨轴锻件对超声检测、力学性能、非金属夹杂物、晶粒度等技术要求非常严格。通过强化各生产环节的过程质量控制,严密组织生产,最终成功研制了轴锻件。 相似文献
94.
Dr. Julien Orts Dr. Marielle Aulikki Wälti Dr. Dhiman Ghosh Dr. Silvia Campioni Dr. Sven J. Saupe Prof. Roland Riek 《Chembiochem : a European journal of chemical biology》2019,20(9):1161-1166
Amyloid fibrils are pathological hallmarks of various human diseases, including Parkinson's, Alzheimer's, amyotrophic lateral sclerosis (ALS or motor neurone disease), and prion diseases. Treatment of the amyloid diseases are hindered, among other factors, by timely detection and therefore, early detection of the amyloid fibrils would be beneficial for treatment against these disorders. Here, a small molecular fluorescent probe is reported that selectively recognize the fibrillar form of amyloid beta(1–42), α-synuclein, and HET-s(218–289) protein over their monomeric conformation. The rational design of the reporters relies on the well-known cross-β-sheet repetition motif, the key structural feature of amyloids. 相似文献
95.
《International Journal of Hydrogen Energy》2022,47(19):10777-10787
In this work, a practical numerical model with few parameters was proposed for the prediction of environmental hydrogen embrittlement. The proposed method adopts hydrogen enhanced plasticity-based mechanism in a fracture strain model to describe hydrogen embrittlement. Fracture toughness degradation of three commercial steels SA372J70, AISI4130 and X80 in high pressure hydrogen environment were investigated. Firstly, governing equations for hydrogen distribution and material damage evolution was established. Hydrogen enhanced localized flow softening effect was coupled within fracture strain dependency on stress triaxiality. Then, the numerical implementation and identification process of model parameters was described. Model parameters of the investigated steels were determined based on experiment results from literatures. Finally, with the calibrated model, fracture toughness reduction of the steels was predicted in a wide range of hydrogen pressure. The prediction results were compared with experimental results. Reasonable accuracy was reached. The proposed method is an attempt to reach balance between physical accurate prediction and engineering practicality. It is promising to provide a simplified numerical tool for the design and fit for service evaluation of hydrogen storage vessels. 相似文献
96.
《International Journal of Hydrogen Energy》2022,47(38):17056-17068
The study of steels which guarantee safety and reliability throughout their service life in hydrogen-rich environments has increased considerably in recent years. Their mechanical behavior in terms of hydrogen embrittlement is of utmost importance. This work aims to assess the effects of hydrogen on the tensile properties of quenched and tempered 42CrMo4 steels. Tensile tests were performed on smooth and notched specimens under different conditions: pre-charged in high pressure hydrogen gas, electrochemically pre-charged, and in-situ hydrogen charged in an acid aqueous medium. The influence of the charging methodology on the corresponding embrittlement indexes was assessed. The role of other test variables, such as the applied current density, the electrolyte composition, and the displacement rate was also studied. An important reduction of the strength was detected when notched specimens were subjected to in-situ charging. When the same tests were performed on smooth tensile specimens, the deformation results were reduced. This behavior is related to significant changes in the operative failure micromechanisms, from ductile (microvoids coalescence) in absence of hydrogen or under low hydrogen contents, to brittle (decohesion of martensite lath interfaces) under the most stringent conditions. 相似文献
97.
Kana Asano-Matsuda Sajida Ibrahim Tomoko Takano Jun Matsuda 《International journal of molecular sciences》2021,22(7)
The first step of urine formation is the selective filtration of the plasma into the urinary space at the kidney structure called the glomerulus. The filtration barrier of the glomerulus allows blood cells and large proteins such as albumin to be retained while eliminating the waste products of the body. The filtration barrier consists of three layers: fenestrated endothelial cells, glomerular basement membrane, and podocytes. Podocytes are specialized epithelial cells featured by numerous, actin-based projections called foot processes. Proteins on the foot process membrane are connected to the well-organized intracellular actin network. The Rho family of small GTPases (Rho GTPases) act as intracellular molecular switches. They tightly regulate actin dynamics and subsequent diverse cellular functions such as adhesion, migration, and spreading. Previous studies using podocyte-specific transgenic or knockout animal models have established that Rho GTPases are crucial for the podocyte health and barrier function. However, little attention has been paid regarding subcellular locations where distinct Rho GTPases contribute to specific functions. In the current review, we discuss cellular events involving the prototypical Rho GTPases (RhoA, Rac1, and Cdc42) in podocytes, with particular focus on the subcellular compartments where the signaling events occur. We also provide our synthesized views of the current understanding and propose future research directions. 相似文献
98.
摘要:为研究溶解氧质量浓度对10Ni5CrMo钢在阴极极化条件下氢脆敏感性影响规律,对10Ni5CrMo钢进行了阴极极化下的电化学交流阻抗谱测试﹑并采用慢应变速率拉伸实验和断口分析方法研究了海水中溶解氧质量浓度变化和不同阴极极化下10Ni5CrMo钢的氢脆敏感性。结果表明:溶解氧质量浓度变化对10Ni5CrMo钢强度几乎没有影响;同一溶解氧质量浓度下,随极化电位负移,断裂时间、伸长率、断面收缩率明显降低,氢脆系数增加,氢脆敏感性显著提高,极化电位达到-1000mV时,氢脆系数已超过安全区允许的最高值25%,进入危险区;同一极化电位下,随着海水中溶解氧质量浓度减少,材料塑性变差,断裂时间、伸长率和断面收缩率不断降低,氢脆系数增加,氢脆敏感性提高。 相似文献
99.
通过对船用长轴类大锻件的热处理工艺研究得知,采用临界区高温侧正火热处理工艺可以有效消除35CrMo钢组织遗传现象,细化晶粒。 相似文献
100.