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81.
In order to understand the relationship between crystal structure and thermoelectric properties, the neutron diffraction patterns of the thermoelectric materials with the nominal composition CexCo4Sb12 (x = 0.5, 1.0) were measured at room temperature, the data were fitted by the Rietveld profile refinement method using the Fullprof2k program. It is found that the sample Ce0.5Co4Sb12 is composed of two phases, its major phase is CoSb3 with skutterudite-structure and the Ce atom is not incorporated into the lattice, the impurity is monoclinic CoSb2. In the case of Ce1.0Co4Sb12, the major phase is filled skutterudite, about 10% of the 2a site is occupied by Ce atom, the second phase is monoclinic CoSb2. 相似文献
82.
本文介绍了一种以新型智能功率模块IPM,SPWM专用控制芯片80C196MC为基础构成的交流牵引变频调速控制系统,介绍了系统的控制原理及软硬件的设计方案。 相似文献
83.
Light emission from carbon-based materials (fine grain graphite, CFC and silicon doped CFC) was observed during ITER relevant thermal shock loads by means of in situ optical diagnostics. The light emission which corresponds to particle release clearly indicated different particle release processes in the three materials. The differences were also found in the initiation temperatures of particle release and the surface morphology of the loaded areas. These results are related to the thermal stress in bulk materials. In addition to particle release, vapor cloud formation caused by thermal shock loads were observed as CII lines and lines from the C2 Swan system. No Si lines but lines from SiC2 molecules (Merrill-Sanford bands) were observed in Si doped CFC. This indicates that atomic silicon is not released under ITER relevant thermal shock loads. 相似文献
84.
Particles of UO2+x (x≅0.16 ± 0.06) exposed to the atmosphere react by oxidation and formation of complexes (hydrates, hydroxides and carbonates). Surface reactions alter and erode the UO2 particles. This paper outlines results for measurements of oxidation rates on uranium oxide particles using in situ photoluminescence spectroscopy (PL), X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). Phosphorescence spectra observed during oxidation of UO2+x were attributed to U(VI) in uranyl-type coordination and in octahedral coordination. Uranyl-type spectra formed during wet oxidation of UO2+x, and U(VI) octahedral spectra formed during dry oxidation of UO2+x. The uranyl-type species, although more stable, is more kinetically labile for vacuum reduction than is the octahedral U(VI). Oxidation of U(IV) species are diffusion controlled. Vacuum reduction of uranyl U(VI) in UO3 follows a field-enhanced cationic diffusion rate law, while re-oxidation follows a diffusion rate law. Post-oxidation core and valence band XPS and SIMS measurements provided qualitative and quantitative measures of uranium oxidation states near uranium oxide surfaces. 相似文献
85.
退火对直流磁控溅射铬膜附着性的影响 总被引:1,自引:0,他引:1
为了利用铬膜改善锆的抗腐蚀性,研究了退火对Zr-2基体上制备的直流磁控溅射铬膜附着性的影响,使用扫描电镜(SEM)观察了界面形貌及锆,铬的界面的分布,用X-射线衍射仪(XRD)分析了膜层的组成,用划痕法测定了铬膜的附着,结果表明,锆/铬界面结合良好,边界可见;与现有文献比较,获得的铬膜附着性好――均超过20N;溅射后退火使Zr-Cr界面更像扩散界面,但X-射线衍射结果未发现有界面反应产物;退火提高铬膜与Zr-2基体的附着性约50%,扩散际着附着性增加的主要因素。 相似文献
86.
87.
88.
89.
双BGO晶体能谱测井 总被引:1,自引:0,他引:1
C/O测井可以利用BGO晶体探测效率高的特点,在其探测器部分放置两个探测器,称为双探测C/O测井仪,长短源距两个探头所测谱数据进行补偿,有效地去除了井眼条件的影响,提高了测量精度和油水差值,更加有产地分油水层,并有望能在低孔隙度的地层中使用C/O测井仪器。 相似文献
90.
Bernhard Klinger 《Computing》1997,59(3):223-236
We investigate quasi-Monte Carlo integration for functions on thes-dimensional unit cube having point singularities. Error bounds are proved and the theoretical results are verified by computations
using Halton, Sobol’ and Niederreiter sequences.
Supported by the Austrian Science Foundation (Project 10223-PHY). 相似文献