花篮螺丝断裂危险点的实验分析

对火力发电厂管道支吊架系统中的花篮螺丝进行了力学性能测试和分析。在测试中发现 ,通过线弹性有限元计算所得的最大应力处 (拉筋与头部拐角处内侧 ) ,并不是“最危险”的断裂地方 ,最后断裂发生在拉筋中部内侧。之后进行的弹塑性有限元计算也与这个结论相吻合。计算还表明 ,原设计强度富裕较大 ,可以减去部分重量。实验结果证明了理论分析的正确性。     

4自由度并联机器人刚度分析

少自由度并联机构应用于机床上时要求具有很高的刚度,而少自由度并联机器人的刚度和机器人雅可比矩阵有很密切的关系。采用螺旋理论方法求出了4-RUC 4自由度并联机构的雅可比矩阵,推导出4自由度并联机器人的刚度计算公式和条件指数计算公式,分析了少自由度并联机器人在某一位置时(z=0)最大和最小刚度所在的方向,给出了这种4自由度并联机器人的最大和最小刚度曲线,通过曲线可以评价出此并联机构在各个方向上刚度大小,为这种机器人的应用和开发提供了有力的依据。     

Experimental investigation on the influence of different grades of wood chips on screw feeding performance

Although basic investigations on wood chip material properties haven been carried out, only few studies deal with transport of wood chips, despite the fact that significant problems are commonly observed when feeding biomass in industrial applications. Within the work presented, basic bulk material properties were measured and experiments carried out with a system consisting of a hopper, agitator and a screw conveyor. The aim of this study was to investigate how three different wood chip grades and two blends of wood chips influence typical design parameters, such as mass flow and driving torque, of a biomass feeding system. The measured basic bulk properties are in good overall agreement with the literature. However, discrepancies were discovered between two standardized methods for determination of the bulk density. The results for the driving torque, mass flow and mass-related energy consumption showed that different grades of wood chips can alter these values considerably. Between two wood chip grades, a twice as high torque was recorded, while a third grade could not be fed due to jamming. One of the major findings of this study is that mixing a rather small amount of a high-fine content grade with the non-feedable grade of wood chips resulted in a blend which inhibited jamming during the screw feeding process.     

Examining the misalignment of a linear guideway pair on a feed drive system under different ball screw preload levels with a cost-effective MEMS vibration sensing system

This paper presents an innovative and cost-effective scheme for examining on line the degree of misalignment of a pair of linear guideway rails in a feed drive system. Prototype MEMS-based vibration detection modules were constructed and installed on the ball screw nut and linear guideway block. The ball screw preload was adjusted with four settings by changing ball sizes in this feed drive system. For each preload setting, a linear guideway rail was adjusted using feeler gauges to produce 11 misalignment statuses. The y-axis deviation caused by misalignment along the feed direction (x-axis) was measured with a dial gauge. For each preload and misalignment setting, the vibration signal was ascertained from the installed detection modules while the work table was driven by the controller. By analyzing the vibration signals from the detection module on the linear guideway block, we found that the characteristic frequency in a specific spectrum band could be used as a misalignment index. The characteristic frequencies exhibited a descending trend when the deviation was less than 40 μm and an increasing trend when the deviation was 40–120 μm. These findings demonstrate the feasibility of using cost-effective sensing units to examine the parallelism or distinguish the deviation between the linear guideway rails without disassembling the work table. This could be valuable for machine intelligence applications in the automation industry.     

高炉煤粉球磨机大修

介绍了球磨机大修施工过程、经验和安装工艺技术要求，工程确保了施工安全，有效地恢复了球磨机的精度要求和功能。     

Effect of Ni and SAPO-34 co-additive on enhancing hydrogen storage performance of MgH2

The hydrogen storage performances of MgH₂ improved by the addition of Ni and SAPO-34 were studied in detail. The mixture of MgH₂ with Ni and SAPO-34 was a physical reaction as shown by the X-ray diffraction (XRD) results. The SAPO-34 and Ni were uniformly distributed on the surface of MgH₂. The thermodynamic and kinetic properties of 90MgH₂/5Ni/5SAPO-34 were investigated by differential scanning calorimetry (DSC) and pressure-composition-isothermal (PCI) methods. The results showed that the dehydrogenation activation energy of 90MgH₂/5Ni/5SAPO-34 decreased by 64.3 kJ/mol compared with that of MgH₂. In addition, the relationship between the value of dehydrogenation heat and hydrogen content was also investigated by in-situ calorimetry. The enthalpy value of each sample in the dehydrogenation processes were calculated by in-situ calorimetry measurement. The dehydrogenation enthalpies of as-milled MgH₂ and 90MgH₂/5Ni/5SAPO-34 were 63.2 kJ/mol H₂ and 53.6 kJ/mol H₂, respectively. Thus, the co-doping of Ni and SAPO-34 contributed significantly to decrease the thermodynamic stability and improve the hydrogen sorption kinetic properties of MgH₂.     

Homogeneous dispersion of boron nitride nanoplatelets in powder feedstocks for plasma spraying

Hexagonal Boron nitride nanoplatelet (BNNP) with the combination of excellent mechanical properties, high-temperature thermal stability, and self-lubrication is a promising strengthening agent in plasma-sprayed composite coatings. However, it is a significant challenge to produce plasma sprayable feedstocks with homogeneously dispersed BNNPs owing to the intrinsic agglomeration of BNNPs. In this research, three powder preparation processes (electrostatic interaction, ball milling, and shear mixing) were employed to disperse BNNPs in Ni-Cr-Cr₂O₃ (NCCO) powders. The shear mixing process presents a competitive advantage in powder preparation, providing stable shear force and achieving exfoliated BNNPs homogeneous distribution in the composite powders. The spray drying technique was finally utilized to obtain spherical agglomerated BNNP-NCCO feedstocks with characteristics of relatively smooth surface and uniform size distribution. Hence, shear mixing and spray drying processes are expected to produce large-scale spherical composite powders with a homogeneous distribution of 2D layered nanomaterials for industrial application.     

Synthesis of SnO2@MnO2@graphite nanosheet with high reversibility and stable structure as a high-performance anode material for lithium-ion batteries

In this study, SnO₂@MnO₂@graphite (SMG) anode material is prepared via a facile ball-milling approach combined with hydrothermal treatment. SnO₂ and MnO₂ nanoparticles are evenly dispersed on numerous sheet-like graphite. MnO₂ can not only play a catalytic role for facilitating the conversion reaction of Sn/Li₂O to SnO₂, but also as a barrier to impede the coarsening of Sn in the composite. Meanwhile, graphite nanosheets could serve as an ideal volume expansion buffer and good electron conductor. Consequently, the SMG anode delivers superior reversible capacity of 1048.5 mAhg⁻¹, ideal rate capability of 522.2 mAhg⁻¹ at 5.0 A g^-1 and stable long-life cyclic performance of 814.8 mAhg⁻¹ at 1.0 A g^-1 after 1000 cycles. This result indicates that the incorporation of MnO₂, graphite nanosheet and SnO₂ have a great potential in enhancing the performance of SnO₂-based anode for battery applications.     

Mechanochemical processing and microstructural characterization of pure Fe2B nanocrystals

The results of current investigation demonstrate that mechanochemical processing can be used to synthesize high purity Fe₂B nanocrystals by selecting well-optimized milling conditions, reaction paths and proper starting materials. Microstructure, phase analyses, specific surface area, and magnetic properties of the synthesized nanocrystals were examined by using X-ray diffraction/spectroscopy, electron microscopy, nitrogen adsorption–desorption methods following Brunauer-Emmett-Teller equation and vibrating sample magnetometer techniques, respectively. Removal of MgO impurity phase by leaching the resulting powder in the acetic acid solution yielded single phase Fe₂B nanocrystals with the crystallite size and specific surface area of 12.5 nm and 29 m²/g, respectively. Magnetization results clearly indicated the ferromagnetic behavior of Fe₂B nanocrystals with saturation magnetization observed around 96.26 emu·g^?1. Electron microscope images revealed coaxial/spherical powder shape and morphology of the single-phase Fe₂B nanocrystals.     

Mechano-chemical synthesis of manganese borohydride (Mn(BH4)2) and inverse cubic spinel (Li2MnCl4) in the (nLiBH4 + MnCl2) (n = 1, 2, 3, 5, 9 and 23) mixtures and their dehydrogenation behavior

Manganese borohydride (Mn(BH₄)₂) was successfully synthesized by a mechano-chemical activation synthesis (MCAS) from lithium borohydride (LiBH₄) and manganese chloride (MnCl₂) by applying high energy ball milling for 30 min. For the first time a wide range of molar ratios n = 1, 2, 3, 5, 9 and 23 in the (nLiBH₄ + MnCl₂) mixture was investigated. During ball milling for 30 min the mixtures release only a very small quantity of H₂ that increases with the molar ratio n but does not exceed ∼0.2 wt.% for n = 23. However, longer milling duration leads to more H₂ released. For the equimolar ratio n = 1 the principal phases synthesized are Li₂MnCl₄, an inverse cubic spinel phase, and the Mn(BH₄)₂ borohydride. For n = 2 a LiCl salt is formed which coexists with Mn(BH₄)₂. With the n increasing from 3 to 23 LiBH₄ is not completely reacted and its increasing amount is retained in the microstructure coexisting with LiCl and Mn(BH₄)₂. Gas mass spectrometry during Temperature Programmed Desorption (TPD) up to 450 °C shows the release of hydrogen as a principal gas with a maximum intensity around 130–150 °C accompanied by a miniscule quantity of borane B₂H₆. The intensity of the B₂H₆ peak is 200–600 times smaller than the intensity of the corresponding H₂ peak. In situ heating experiments using a continuous monitoring during heating show no evidence of melting of Mn(BH₄)₂ up to about 270–280 °C. At 100 °C under 1 bar H₂ pressure the ball milled n = 2 and 3 mixtures are capable of desorbing quite rapidly ∼4 wt.% H₂ which is a very large amount of H₂ considering that the mixture also contains 2 mol of LiCl salt. The H₂ quantities experimentally desorbed at 100 and 200 °C do not exceed the maximum theoretical quantities of H₂ expected to be desorbed from Mn(BH₄)₂ for various molar ratios n. It clearly confirms that the contribution from B₂H₆ evolved is negligibly small (if any) when desorption occurs isothermally in the practical temperature range 100–200 °C. It is found that the ball milled mixture with the molar ratio n = 3 exhibits the highest rate constant k and the lowest apparent activation energy for dehydrogenation, E_A ∼ 102 kJ/mol. Decreasing or increasing the molar ratio n below or above 3 increases the apparent activation energy. Ball milled mixtures with the molar ratio n = 2 and 3 discharge slowly H₂ during storage at room temperature and 40 °C. The addition of 5 wt.% nano-Ni with a specific surface area of 60.5 m²/g substantially enhances the rate of discharge at 40 °C.