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排序方式: 共有684条查询结果,搜索用时 234 毫秒
131.
132.
Nawadon Petchwattana Phisut Naknaen Jakkid Sanetuntikul Borwon Narupai 《塑料、橡胶和复合材料》2018,47(4):147-155
In this paper, dimethylbenzylidene sorbitol (DMBS) was applied to poly(lactic acid) (PLA) as a nucleating and clarifying agents. Eight level concentrations, from 0.25 to 10?wt-%, were added and measured some changes in the thermal, mechanical, physical and morphological properties. Experimental results revealed that the nucleated PLA crystallised earlier together with the reductions of the crystallisation temperature (Tc) at all DMBS concentrations, while the glass transition temperature (Tg) reduced by around 10°C. The degree of crystallinity (Xc) increased from 1.48 to 16.6% corresponding to the decreased crystallisation time (tc) from more than 40 to less than 5?min at 100°C. The nucleated PLA maintained its clarity at all DMBS concentrations, with reductions of the haze value from around 36–29%. The tensile modulus and tensile strength increased slightly with the content of DMBS up to 1.5?wt-%. Beyond this content, they dropped slightly. 相似文献
133.
Shadpour Mallakpour Marziyeh Khani Fereshteh Mallakpour Mohammadhossein Fathi 《Polymer-Plastics Technology and Engineering》2018,57(1):28-37
In this work, the surface of synthetic nanosized Mg-substituted fluorapatite particles was modified with biodegradable diacid N-trimellitylimido-L-leucine as a coupling agent in methanol. Furthermore, different contents of N-trimellitylimido-L-leucine-modified Mg-substituted fluorapatite were doped into polyvinylpyrrolidone/L-leucine-modified montmorillonite material to prepare novel ternary polyvinylpyrrolidone/modified montmorillonite/N-trimellitylimido-L-leucine-Mg-substituted fluorapatite nanocomposites by an efficient sonication process. Nanocomposite containing 5?wt% modified montmorillonite and 3, 5, and 7?wt% N-trimellitylimido-L-leucine-modified Mg-substituted fluorapatite contents were prepared and labeled as polyvinylpyrrolidone/modified montmorillonite/N-trimellitylimido-L-leucine-Mg-substituted fluorapatite 3, polyvinylpyrrolidone/modified montmorillonite/N-trimellitylimido-L-leucine-Mg-substituted fluorapatite 5, and polyvinylpyrrolidone/modified montmorillonite/N-trimellitylimido-L-leucine-Mg-substituted fluorapatite 7, respectively. The structure and morphology of the aforesaid products were characterized by different analytical apparatuses. 相似文献
134.
Sarat K. Swain Sunita Barik Gopal C. Pradhan Lingaraj Behera 《Polymer-Plastics Technology and Engineering》2018,57(15):1585-1591
Mg-Al layered double hydroxide decorated starch bionanocomposites (starch/layered double hydroxide) are prepared by solution intercalation method. The bionanocomposites are systematically characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy techniques. The thermal stability of starch is enhanced due to dispersion of layered double hydroxide within the starch matrix. The chemical resistance property of starch is improved substantially with slight sacrifice in biodegradation behavior by the delamination of layered double hydroxide in starch matrix. Herein, layered double hydroxide acts as potential laminated filler for change in structural, thermal, and chemical resistance properties of starch with little sacrifice in biodegradable behavior. 相似文献
135.
The stable dispersion of nano-additives is highly desirable for the effective lubrication performance of nanolubricants. The compatibility of base oil with selected nano-additives is required for uniform and stable dispersion. This research evaluated the dispersion stability and tribological characteristics of nano-TiO2/SiO2 (average particle size 50 nm) as an additive in a biobased lubricant. The wear protection and friction reducing characteristics of the formulations were evaluated by four-ball extreme pressure tests and piston ring–cylinder liner sliding tests. Surface analysis tools, including scanning electron microscopy, energy-dispersive X-ray spectroscopy, and atomic force microscopy, were used to characterize the worn surfaces. Results showed that the nanolubricants demonstrated appreciable dispersion capability in the absence of a surfactant and an improvement in load-carrying capacity, antiwear behavior, and friction reduction capability. 相似文献
136.
Ultra-high-speed bicomponent spinning of poly(butylene terephthalate) (PBT) as sheath and biodegradable poly(butylene adipate-co-terephthalate) (PBAT) as core was accomplished with the take-up velocity up to 10 km/min. The structure development of the individual component and the properties of PBT/PBAT fibers were investigated through the measurements on differential scanning calorimetry, wide-angle X-ray diffraction, birefringence and tensile test. Due to the mutual interaction between two polymer-melts along the spinline, the processability of both components in PBT/PBAT bicomponent spinning was improved compared with those of corresponding single component spinnings. Furthermore, in PBT/PBAT fibers, the structure development of PBT component was found to be greatly enhanced, which led to the improvement in its thermal and mechanical properties; whereas the structure development of PBAT component was significantly suppressed, in which nearly non-oriented structure was observed in both crystalline and amorphous phases. 相似文献
137.
138.
139.
Kyu Ho Song Chang-Ha Lee Jong Sung Lim Youn-Woo Lee 《Korean Journal of Chemical Engineering》2002,19(1):139-145
Submicron particles of L-polylactic acid (L-PLA) without residual solvent were prepared by a continuous supercritical antisolvent
(SAS) recrystallization process. Methylene chloride (CH2C12) was used as a carrier solvent of L-PLA. Experiments were performed with changing process parameters such as pressure and
temperature at constant concentration. Also, L-PLA initial concentrations in methylene chloride were varied from 0.3 to 4
wt%. The flow rates of CO2 and solution, which were introduced into the precipitator, and nozzle diameter were kept unchanged in all of the experiments.
It was found that the SAS process gives fine tuning of particle size and particle size distribution (PSD) by simple manipulations
of the process parameters. In all cases of SAS recrystallization experiments, the formed spherical fine particles with a smooth
surface were non-agglomerated and free flowing. Mean particle size of the L-PLA microparticles formed was varied from 0.1
to 1 μm by means of adjusting the system pressure and/or temperature. 相似文献
140.
As tissue engineering and drug delivery applications increase in both number and complexity, the demand for new synthetic biocompatible polymers with precisely tailored properties grows accordingly. Block copolymers are a particularly promising biomaterial as the physical and physiological properties of these polymers can be closely controlled through manipulation of the type and organization of the blocks in the polymer's backbone. In this work, poly(ethylene glycol) (PEG) and poly(lactic acid) (PLA) were incorporated into PEG-PLA-PEG block macromonomers with (meth)acrylate functionality to form photopolymerizable, highly cross-linked polymers for potential use in a variety of biomedical applications. Simply by directing the PLA:PEG ratio in these macromonomers, the hydrophobicity, physical behavior, degradation, and biocompatibility of the resulting polymer were controlled. Specifically, it was found that by increasing the PLA:PEG ratio, the degree of water uptake and the mechanical strength of the material is significantly decreased, while the glass transition temperature and degradation of the PEG-PLA polymers are delayed. Additionally, the biocompatibility of the PEG-PLA polymers is significantly influenced by the chemical composition of the material as increased PLA generally yields greater cell compatibility. By demonstrating the versatility of the photopolymerizable PEG-PLA polymers, the results of this study indicate that these materials have the potential to serve as a synthetic biomaterial platform, in which the properties of the polymer can be tailored to a variety of tissue engineering or drug delivery applications. 相似文献