InSb衬底表面的氧化层研究

能在高温下工作的InSb基InAlSb红外探测器是新一代红外探测器的发展方向。对衬底表面氧化层的研究是该研究方向的基础。利用椭偏仪(Spectroscopic Ellipsometry,SE)、X射线光电子能谱分析(X-ray photoelectron spectroscopy, XPS)对用现工艺生长的InSb衬底表面氧化层进行了分析。从常用的腐蚀液中挑选了较优的腐蚀液,调节配比,试验加入无机酸后的效果,获得了较优的表面氧化层处理液。对处理后的表面氧化层的稳定性进行了对比,分析了其主要成分的变化,最终获得了满足Epi-ready InSb晶片表面氧化层参数的衬底,为后面高温工作探测组件的研究打好了基础。     

考虑局部非热平衡的流体层流横掠多孔介质中恒热流平板的传热分析

对流体层流横掠多孔介质中恒热流加热的平板,应用Brinkman-Forchheime-extended Darcy流动模型和流体与多孔介质之间局部非热平衡理论建立守恒方程组,应用数量级分析和积分法,得出了速度边界层厚度、热边界层厚度、壁面黏性摩擦系数和对流传热系数、流体与多孔介质之间局部温差的计算公式。结果表明,速度边界层与光板时明显不同,其在平板前端迅速增长,之后越来越平坦,趋于一个恒定值;而热边界层则沿着流动方向不断增长,类似于光板时的情况;局部的表面对流传热系数在平板前端达最大值,之后逐渐减小,也类似于光板时的情况;多孔介质与流体间的局部温差在平板前端达最大值,之后呈现沿着流动方向逐渐减小的变化趋势。     

Structural Control of NiO–YSZ/LSCF–YSZ Dual‐Layer Hollow Fiber Membrane for Potential Syngas Production

The objective of this study was to fabricate dual‐layer hollow fiber as a microreactor for potential syngas production via phase inversion‐based co‐extrusion/cosintering process. As the main challenge of phase inversion is the difficulty to obtain defect‐free fiber, this work focuses on the effect of the fabrication parameters, that is, nonsolvent content, sintering temperature and outer‐layer extrusion rate, on the macrostructure of the produced hollow fiber. SEM images confirm that the addition of nonsolvent has successfully minimized the finger‐like formation. At high sintering temperature, more dense hollow fiber was formed while outer‐layer extrusion rate affects the outer layer thickness.     

差动传感测量釉层热应力

本文介绍一种以差动传感原理测量冷却过程中釉层热应力的方法及装置，并对该装置的测量误差进行了分析。     

高岭石-氨基硅烷插层复合物的制备与表征

以高岭石-甲醇(K-M)复合物为前驱体,利用置换法于常温下制备了3种高岭石-氨基硅烷插层复合物。用X射线衍射、Fourier变换红外光谱仪、透射电子显微镜、热分析仪等对复合物进行了表征。结果表明:3种高岭石-氨基硅烷插层复合物的层间距均扩大至2nm以上,插层率都大于95%。3种氨基硅烷分子均和K-M前驱体的甲氧基共同存在于高岭石层间,均呈两层倾斜排列,倾斜程度不同。氨基硅烷的插入破坏了高岭石层间的氢键,加剧了高岭石自身结构中硅氧四面体片层与铝氧八面体片层之间的错位,使得复合物片层出现不同程度的卷曲变形。3种高岭石-氨基硅烷插层复合物的热分解过程均分三步进行:表面水的蒸发及层间甲氧基的脱嵌分解、插层剂氨基硅烷分子的脱嵌、高岭石脱羟基。     

聚合物电解质膜燃料电池气体扩散层上新型双层微孔层的制备和性能

聚合物电解质膜燃料电池（PEMFC）的微孔层对电池性能有重要影响。首次使用多壁碳纳米管（MWCNTs）在碳纸上先制备1层微孔层,再用碳黑（CB）在其上制备第2层微孔层,形成双层微孔层。从不同尺度上观察了微孔层（MPL）的形貌和结构,测量了气体扩散层（GDL）垂直向电阻,并测试了电池性能。结果表明,双层微孔层的平整程度与单独使用碳黑制备的微孔层相似,比单独使用MWCNTs制备的微孔层更加平整;双层微孔层的GDL垂直向的电阻比单层微孔层的GDL更小;使用双层微孔层制备的膜电极比相同碳载量下的单层微孔层制备的膜电极性能更好。     

薄板弯曲时树脂基碳纤维智能层的力阻响应

将智能层附于足够大的矩形薄板表面,通过不同的弯曲试验构造出多种表面应变状态,基于三种工况下的试验结果,建立智能层电阻变化与平面二维应变状态之间的映射关系,该关系表明纵向应变对智能层的电阻变化的影响占主导地位。在此基础上对其它工况下智能层的电阻变化率进行了预测,其结果与实验结果具有较好的一致性。     

From Laboratory Experiments to Design of a Conveyor-Belt Dryer via Mathematical Modeling

Abstract

A conveyor-belt dryer for picrite has been modeled mathematically in this work. The necessary parameters for the system of equations were obtained from regression analysis of thin-layer drying data. The convective drying experiments were carried out at temperatures of 40, 60, 80, and 100°C and air velocities of 0.5 and 1.5 m/sec. To analyze the drying behavior, the drying curves were fitted to different semi-theoretical drying kinetics models such as those of Lewis, Page, Henderson and Pabis, Wang and Singh, and the decay models. The decay function (for second order reactions) gives better results and describes the thin layer drying curves quite well. The effective diffusivity was also determined from the integrated Fick's second law equation and correlated with temperature using an Arrhenius-type model. External heat and mass transfer coefficients were refitted to the empirical correlation using dimensionless numbers (J _h , J _D  = m · Re ⁿ ) and their new coefficients were optimized as a function of temperature. The internal mass transfer coefficient was also correlated as a function of moisture content, air temperature, and velocity.     

ESTIMATION OF THE EFFECT OF PRODUCT SHRINKAGE ON THE DRYING TIMES,HEAT INPUT AND CONDENSER LOAD OF THE PRIMARY AND SECONDARY DRYING STAGES OF THE LYOPHILIZATION PROCESS IN VIALS

ABSTRACT

The effects of cake shrinkage on the drying times and energy requirements of the primary and secondary drying stages of the freeze drying process involving the drying of a material in a vial, are estimated through the construction and solution of an extended unsteady state and spatially multidimensional model that accounts for the changes introduced by cake shrinkage on the internal and external mass and heat transfer mechanisms of the freeze drying     

微型离心泵泵叶三层式滑块机构三板模具设计

针对微型离心泵泵叶塑件成型模具设计困难的问题,设计了一种改进型三板点浇口模以用于该泵叶塑件的成型。塑件的浇注成型应用3个点浇口来进行平衡注塑,以控制塑件成型变形。模腔布局为1模1腔。针对塑件叶槽区域脱模困难问题,设计了一种3层3次复合抽芯脱模用于难脱模叶槽部位特征的脱模,机构中,将叶槽部位特征的成型块分割成2层成型件后,机构的第一次抽芯动作由弹簧驱动上层滑块实施上层成型块的抽芯;机构的第二次抽芯由斜导柱驱动实施下层成型块的抽芯;最后,由弯销驱动基座滑块带动2个侧抽芯滑块向外抽芯,以让出塑件完全顶出脱模的运动空间。第二次抽芯、第三次抽芯的驱动动力分别由模架模板的第三次开模、第四次开模打开来进行驱动。塑件的最终脱模由油缸驱动顶针板及顶杆顶出而实现塑件的完全脱模。基于塑件、流道脱模及抽芯机构的动作需要,将典型三板点浇口模架改进为四板4次开模点浇口,从而能使塑件、流道废料及驱动滑块机构分次按序来实施抽芯脱模。模具脱模机构动作设置合理,机构结构设计巧妙,模具整体工作可靠,有较好的设计参考价值。