染料释放化合物及一当量成色剂浅谈

简述了染料释放化合物的发展过程 ,并由此引出一当量成色剂的概念 ,叙述了一当量成色剂应用和发展 ,对一当量成色剂应用前景做了预测。     

Conversion measurement in polyethylene/peroxide coupling system under steady shear flow

The coupling reaction of melt linear low density polyethylene (LLDPE) initiated by dicumyl peroxide (DCP) in steady shear flow field was investigated. The conversion of DCP was measured by electron spin resonance (ESR) and chemical titration. An absolute method was proposed to calculate the actual conversion of DCP from rheological data. The coupling efficiency of DCP was obtained from those analyses, which was shown to increase at first, reach a maximum and then decrease in the end stage. A linear relationship between the coupling efficiency of DCP and the concentration of macroradicals was also found in the experiments.     

通信用片式介质陶瓷双工器的设计与制作

介绍了通信用介质陶瓷双工器的设计方法和制作过程。该双工器是由接收滤波器和发射滤波器组成的。每种滤波器是由一块高介电常数、高Q值和接近零温度系数的介质陶瓷块制成的。这个陶瓷块上包含两个四分之一波长同轴谐振腔、输入及输出电极和耦合装置,并且输入及输出电极在陶瓷块的同一侧面上,因此滤波器具有体积小巧,结构稳定和安装方便的特点。采用介电常数为90的陶瓷材料制作了中心频率分别为903MHz和927MHz的接收和发射滤波器,经网络分析仪测试,各项技术指标满足设计要求。     

Oxidative coupling of methane over Na+-ZrO2-C1-/Al2O3 catalysts

Oxidative coupling of methane (OCM) was carried out over Na⁺-ZrO₂-Cl /A1[₂O₃ catalysts in a temperature range from 1023 to 1123 K. The catalysts were prepared by impregnating the α- or γ-Al₂O₃ supports with sodium carbonate and/or zirconyl chloride. The OCM activity was examined using the catalysts prepared by three different preparation procedures. The best catalyst was the one prepared by subsequent impregnation of sodium carbonate-preimpregnated γ-Al₂O₃ with a mixed solution of sodium carbonate and zirconyl chloride. It was found that preimpregnated sodium played an important role in reducing the combustion activity of the γ-Al₂O₃. The catalyst with an optimal composition showed the highest C₂ selectivity and yield of 40.8% and 15.1%, respectively. From the X-ray diffraction analysis it was found that tetragonal ZrO₂ was formed and that NaCl existed in the catalysts with relatively high sodium contents.     

双曲拱桥的车桥耦合振动试验研究

行驶汽车的轴重和速度超出设计范围给双曲拱桥的动力性能造成了很大的影响,然而这方面的研究却很少.结合1座旧双曲拱桥,进行了实地车桥耦合振动试验,得出了车速与动力系数、冲击系数之间的关系,以及车辆荷载作用下桥梁振动的规律;同时对旧桥进行了参数分析,并据此进行了裸拱状态的理论耦合振动分析,得出了一些结论,可为以后双曲拱桥的评估及加固设计提供参考.     

二维直线电机平台的双神经网络前馈解耦控制

针对二维直线电机系统中的直线电机本身存在的非线性以及XY两轴之间互相影响产生的耦合对控制精度的影响,提出了一种基于前馈结构的双神经网络解耦控制方法.根据二维直线电机两轴间的耦合结构和前馈控制结构,对应搭建了双神经网络模型,设计一种双神经网络的解耦控制策略,以消除二维直线电机两轴间的非线性强耦合对系统控制精度的影响.仿真结果表明:提出的双神经网络前馈解耦控制方法的有效性,并在起始阶段的跟踪方面表现出良好的性能.     

基于应力-渗流-损伤耦合模型的重力坝三维水力劈裂数值模拟

裂缝的高压水力劈裂是混凝土高坝安全评估的重要部分。目前,重力坝水力劈裂的数值模拟绝大多数是二维的,对于坝体上游面经常出现的竖直裂缝的三维水力劈裂的数值研究几乎为零。本文提出一种应力-渗流-损伤耦合模型,用于混凝土重力坝三维水力劈裂的模拟。采用该耦合模型,模拟了一个内置裂缝的圆柱体试件的水力劈裂,数值结果与试验结果吻合很好,验证了所提耦合模型的合理性。在此基础上,采用该耦合模型,进行了国内某混凝土重力坝三维水力劈裂的模拟,数值模拟得到的损伤区域与设计院根据安全监测实测结果得到的范围基本吻合。研究结果表明:本文耦合模型可以方便、有效地进行重力坝三维水力劈裂的模拟,评估表面裂缝的危险程度。     

基于显著性分析的气缸盖结构优化设计

为了改变缸盖的结构,提高气缸盖运行工况下的温度分布及结构可靠性,进行了以鼻梁区宽度等六组参数为设计变量、以其许用范围约束条件、以等效热应力最低为优化目标的汽缸盖结构优化。基于正交实验法,构建了6因素5水平的正交实验表,并建立相应的三维模型,仿真得到了温度场及热应力。通过均值化法去量纲,分析得到了各因素的显著性水平,基于各因素的显著性水平选取了最优方案,并进行对比。结果表明,优化尺寸优选后方案的最大热应力比原始结构降低了13.48%,为缸盖的结构设计提供了一定的参考。     

Modelling of the thermomechanical coupling during hot forming of viscoplastic materials

In the present paper, a strategy for solving transient thermoviscoplastic problems is described. The general thermal and mechanical coupling phenomena are discussed by assuming material properties to be temperature-dependent and accounting for the mechanical terms in the non-stationary heat conduction equation. Time integration is carried out with an implicit scheme. An interesting version of the three-field approach is presented to obtain an accurate solution for the stress field. Finally, a global product coupling algorithm, in which the unknown nodal velocities and temperatures are solved with a two-step solution procedure is suggested. The proposed fractional step method partitions the initial coupled problem into an isothermal viscoplastic problem followed by a purely heat conduction problem at fixed configuration. Applications in metal forming analyses involving full thermomechanical coupling conclude the paper.     

海洋废弃平台桩基拆除绳锯机驱动系统控制研究

伴随着海洋油气田多年的开采,越来越多的废弃平台需要分解处理,切割是非常重要的一道工序。平台水下桩基切割可以采用绳锯机来完成,考虑到桩基的直径较大,研发的绳锯机切割框架包含4个绳轮,其中驱动轮为相邻两个。为了安全高效切割,必须使两个驱动轮保持同步。建立驱动轮同步工作的动力学模型,提出同步耦合控制方法。结合绳锯机的实际结构,对控制方法进行仿真分析和实验研究。结果表明:该控制方法能够满足绳锯机的水下切割要求,为绳锯机的高效稳定工作打下了一定理论基础。