全文获取类型
收费全文 | 12881篇 |
免费 | 2110篇 |
国内免费 | 1215篇 |
专业分类
电工技术 | 1508篇 |
综合类 | 1200篇 |
化学工业 | 2254篇 |
金属工艺 | 459篇 |
机械仪表 | 1057篇 |
建筑科学 | 226篇 |
矿业工程 | 200篇 |
能源动力 | 768篇 |
轻工业 | 160篇 |
水利工程 | 195篇 |
石油天然气 | 465篇 |
武器工业 | 355篇 |
无线电 | 1515篇 |
一般工业技术 | 1649篇 |
冶金工业 | 325篇 |
原子能技术 | 99篇 |
自动化技术 | 3771篇 |
出版年
2024年 | 116篇 |
2023年 | 313篇 |
2022年 | 512篇 |
2021年 | 526篇 |
2020年 | 645篇 |
2019年 | 526篇 |
2018年 | 495篇 |
2017年 | 628篇 |
2016年 | 663篇 |
2015年 | 674篇 |
2014年 | 845篇 |
2013年 | 915篇 |
2012年 | 1000篇 |
2011年 | 1084篇 |
2010年 | 766篇 |
2009年 | 827篇 |
2008年 | 683篇 |
2007年 | 820篇 |
2006年 | 682篇 |
2005年 | 527篇 |
2004年 | 411篇 |
2003年 | 411篇 |
2002年 | 340篇 |
2001年 | 266篇 |
2000年 | 261篇 |
1999年 | 186篇 |
1998年 | 182篇 |
1997年 | 153篇 |
1996年 | 131篇 |
1995年 | 104篇 |
1994年 | 114篇 |
1993年 | 57篇 |
1992年 | 77篇 |
1991年 | 49篇 |
1990年 | 43篇 |
1989年 | 32篇 |
1988年 | 23篇 |
1987年 | 24篇 |
1986年 | 17篇 |
1985年 | 13篇 |
1984年 | 20篇 |
1983年 | 14篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
针对多数流形学习算法是基于单一流形的假设,当高维数据集中存在多个流形,流形学习算法可视化效果差问题,借鉴流形曲面在二维平面空间展开的思想提出基于局部保持的的子流形可视化方法。利用奇异值分解和k均值聚类方法将流形数据划分为多块子流形,计算第一流形切块中心与其余切块中心的拓扑结构关系,在目标低维空间保持上述中心间拓扑结构下逐一对流形切块投影展开,最后在人脸数据集上进行实验。实验结果表明:该方法较好保持了子流形内的数据间的拓扑结构。 相似文献
52.
纳米铜锰复合氧化物固相反应法的制备与表征 总被引:1,自引:0,他引:1
以乙酸铜、乙酸锰与草酸为原料,采用固相化学反应法制备了纳米铜锰复合氧化物前驱物,利用均匀设计考察了微波功率与加热时间、热分解温度及时间对产物粒径的影响。研究表明热分解温度对产品粒径的影响最大。最小粒径产物的制备条件是:微波功率540 W,微波加热时间15 min;热分解温度370℃,热分解时间2 h。XRD和TEM分析结果表明,此产品主要物相为Cu1.5Mn1.5O4,结构属立方晶系,空间群为Fd3m,平均粒径16.9-19.0 nm。应用TG-DTG和DSC技术研究了纳米铜锰复合氧化物的热分解过程以及热分解动力学,采用Ozawa积分法和Coats-Redfern积分法得前驱体的热分解机理函数均为G(α)=[-ln(1-α)]^2/3。 相似文献
53.
为解决EMD-IT去噪算法中阈值难以确定的问题,提出一种基于高斯白噪声能量分布的阈值估计方法。将含噪信号进行经验模态分解并估计各固有模态函数(IMF)中噪声的能量;根据模态单元阈值的含义,在各IMF中利用去除掉的模态单元包含的总能量等于噪声能量这一准则估计阈值。合成数据和实际心电信号的去噪仿真实验验证了该方法的有效性,其是自适应的且避免了阈值选择的主观性。 相似文献
54.
To investigate species-specific decomposition rates of litter from native (Quercus faginea) and introduced (Eucalyptus globulus) tree species in Portugal, we monitored changes in the phenolic signature of leaf litter during decomposition as mediated by an aquatic, Proasellus coxalis (Isopoda: Asellota), and two terrestrial, Porcellio dispar and Eluma caelatum (Isopoda: Oniscidea), detritivores. Although the litter of Eucalyptus and Quercus did not differ in overall protein precipitation capacity, we detected differences in terms of contents of particular phenolic compounds and phenol oxidation products. Accordingly, we observed food-specific consumption rates in Proasellus, but not in the terrestrial isopods. Proasellus digested Eucalyptus at significantly higher rates than Quercus, whereas the opposite was the case for Eluma, and Porcellio digested both litter types equally well. Despite slight differences in detail, effects of Proasellus on changes in the signature of litter phenolics were similar for both litter types, whereas terrestrial isopods—Porcellio and Eluma, although they differed from each other—digestively degraded phenolic compounds in Eucalyptus and Quercus litter, respectively, in different ways. Overall, however, degradation of litter phenolics was similarly effective on both litter types. From these data, we conclude that decomposition of Eucalyptus litter does not proceed more slowly than of litter from native Portuguese trees. 相似文献
55.
The effect of pH on the decomposition of peracetic acid in an aqueous solution was studied. It was found that three potential reactions, namely i) the spontaneous decomposition, ii) the hydrolysis and iii) the transition metal catalysed decomposition, are responsible for the consumption of peracetic acid. The spontaneous decomposition reaches its maximum at pH 8.2, while both the hydrolysis and metal ion catalysed decomposition increase as the pH increases. At pH 10.5 and higher, the hydrolysis becomes dominant when the metal ion catalysed decomposition is minimized by the addition of DTMPA. The kinetics of the peracetic acid hydrolysis was developed, which can very well predict the development of peracetic acid and hydrogen peroxide during the decomposition reaction. 相似文献
56.
微波作用下天然气水合物分解的研究及应用 总被引:16,自引:1,他引:16
介绍了微波和天然气水合物的作用的国内外实验研究进展,说明了微波对天然气水合物的分解有很大的促进作用,分析了用微波加热开采天然气水合物资源、解除天然气输送、开采过程中天然气形成水合物而造成的堵塞等应用的可行性,最后展望了微波在天然气工业中的广泛应用前景。 相似文献
57.
Bo Hyun Ryu Sang Yup Lee Dong Hyun Lee Gui Young Han Tae-Jin Lee Ki June Yoon 《Catalysis Today》2007,123(1-4):303-309
Carbon black has recently been reported to act as an effective catalyst for methane decomposition and to exhibit stable catalytic behavior despite carbon deposition, and thus it can be used for CO2-free production of hydrogen from natural gas. In this work, various carbon blacks with different primary particle size were investigated with respect to methane decomposition under atmospheric pressure from 1123 to 1223 K. Catalytic characteristics, such as activity, activation energy and reaction order, were investigated and compared. It was observed that with decreasing primary particle size (or increasing specific surface area), the specific activity increased and the activation energy decreased. The reaction orders for various pelletized, rubber-reinforcing carbon blacks were 0.6–0.7, about the same regardless of the primary particle size, while they were near 1 for fluffy carbon blacks. Fluffy carbon black showed higher activity and activation energy than the pelletized carbon black of the same primary particle size. Changes of the surface morphology during carbon deposition were observed by TEM. Variations of the number of active sites were discussed in regard of the primary particle size, carbon deposition and binder. The presence of different types of active sites was also suggested. 相似文献
58.
Direct nitric oxide decomposition over perovskites is fairly slow and complex, its mechanism changing dramatically with temperature. Previous kinetic study for three representative compositions (La0.87Sr0.13Mn0.2Ni0.8O3−δ, La0.66Sr0.34Ni0.3Co0.7O3−δ and La0.8Sr0.2Cu0.15Fe0.85O3−δ) has shown that depending on the temperature range, the inhibition effect of oxygen either increases or decreases with temperature. This paper deals with the effect of CO2, H2O and CH4 on the nitric oxide decomposition over the same perovskites studied at a steady-state in a plug-flow reactor with 1 g catalyst and total flowrates of 50 or 100 ml/min of 2 or 5% NO. The effect of carbon dioxide (0.5–10%) was evaluated between 873 and 923 K, whereas that of H2O vapor (1.6 or 2.5%) from 723 to 923 K. Both CO2 and H2O inhibit the NO decomposition, but inhibition by CO2 is considerably stronger. For all three catalysts, these effects increase with temperature. Kinetic parameters for the inhibiting effects of CO2 and H2O over the three perovskites were determined. Addition of methane to the feed (NO/CH4=4) increases conversion of NO to N2 about two to four times, depending on the initial NO concentration and on temperature. This, however, is still much too low for practical applications. Furthermore, the rates of methane oxidation by nitric oxide over perovskites are substantially slower than those of methane oxidation by oxygen. Thus, perovskites do not seem to be suitable for catalytic selective NO reduction with methane. 相似文献
59.
Shampa Kandoi Jeff Greeley Marco A. Sanchez-Castillo Steven T. Evans Amit A. Gokhale James A. Dumesic Manos Mavrikakis 《Topics in Catalysis》2006,37(1):17-28
A microkinetic model for methanol decomposition on platinum is presented. The model incorporates competitive decomposition
pathways, beginning with both O–H and C–H bond scission in methanol, and uses results from density functional theory (DFT)
calculations [Greeley and Mavrikakis, J. Am. Chem. Soc. 124 (2002) 7193, Greeley and Mavrikakis, J. Am. Chem. Soc. 126 (2004)
3910]. Results from reaction kinetics experiments show that the rate of H2 production increases with increasing temperature and methanol concentration in the feed and is only nominally affected by
the presence of CO or H2 with methanol. The model, based on the values of binding energies, pre-exponential factors and activation energy barriers
derived from first principles calculations, accurately predicts experimental reaction rates and orders. The model also gives
insight into the most favorable reaction pathway, the rate-limiting step, the apparent activation energy, coverages, and the
effects of pressure. It is found that the pathway beginning with the C–H bond scission (CH3OH→H2COH→HCOH→CO) is dominant compared with the path beginning with O–H bond scission. The cleavage of the first C–H bond in methanol
is the rate-controlling step. The surface is highly poisoned by CO, whereas COH appears to be a spectator species. 相似文献
60.
Photocatalytic activities for water decomposition were examined for photocatalysts using hexa- and octa-titanates and TiO2(B) with different tunnel space in the structure. Using RuO2 as promoter, M2Ti6O13 (M = Li, Na, K, Rb) showed the stoichiometric production of Hz and O2 except for Li, whereas H2Ti8O17 and TiO2(B) had very low activity producing only hydrogen as a product. The effects of promoters on Na2Ti6O13 showed that the activity increased in the order of RuO2 > RuO2 + IrO2 > IrO2 > RuO2 + Pt > MnO2. These effects along with other related ones are discussed: it emerges that the presence of the tunnels is important for the achievement of high photocatalytic activity. 相似文献