Simple and economic syntheses of some (Z)-7- and (Z)-9-alkenyl acetates,and of (E,Z)-7,9-dodecadien-1-yl acetate,the sex pheromone of the European grapevine moth,using aleuritic acid as a common starting material

Short syntheses of (Z)-7-dodecen-1-yl acetate, (Z)-7-tetradecen-1-yl acetate, (Z)-9-dodecen-1-yl acetate, and (Z)-9-tetradecen-1-yl acetate from 7-hydroxyheptanal and 9-oxononanoic acid precursors obtained by oxidative cleavage of easily available aleuritic acid are reported. The key step in these syntheses is a stereoselective Wittig reaction between aldehyde and alkyl-phosphonium salt. Wittig-Horner type reaction of 7-hydroxyheptanal and diethyl cyanomethylphosphonate gave the ,-unsaturated nitrile derivative which after protection of the hydroxyl group was reduced to the corresponding aldehyde. Wittig reaction of the latter, followed by acetylation, completed the synthesis of (E,Z)-7,9-dodecadien-1-yl acetate, the sex pheromone of the European grapevine mothLobesia botrana Schiff.     

基于STM32F103的随钻测量系统

本文在仔细分析了随钻测量系统的工作原理之后,给出了随钻姿态测量的具体方法. 并使用STM32F103RET7和LSM303完成核心电路的设计. 完成数据采集和处理的工作. 最后给出上位机Labview程序实现数据的实时显示. 实验表明本文设计的嵌入式随钻测量系具有集成度高,精度高等特点.     

采用读卡机芯片FM1715SL设计的RFID读卡机

根据车辆管理系统对身份识别需求,提出基于国产芯片的RFID读卡机方案。数据接口设计为ISO14443TypeB的设备,在满足安全保密前提下,很好地兼顾了使用方便和高效便捷,大规模的车载应用验证了该方案的可靠性。     

Win7控制面板三大功能应用技巧

每个市场客户的需求是不一样的,使用情况也有差异.Win7的推出也是褒贬不一.Win7系统是微软开发的操作系统,在桌面、主题、功能、安全上相对于上一代系统有着很大的改进.以功能的强大及全面、存储空间小、操作系统简单和新增功能的人性化而受到用户的喜爱,且智能性上来说,Win7比XP要好很多.但是通过调查研究地发现,很多的用户对于Win7系统的使用仅仅停留在了表面阶段,对于系统中很多新的、提高便捷性的功能了解不足.因此,笔者通过这篇文章来研究和探讨win7系统的控制面板中三大功能的应用技巧,让win7系统能更好的为用户服务.     

强化两相混合的超临界技术制备聚乳酸微粒

针对商品化聚乳酸微球粒径分布较宽难于适用气溶胶给药要求的不足,采用水力空化混合强化超临界流体辅助雾化技术(SAA-HCM)制备聚乳酸(PLA)超细微粒.该技术主要特点是通过在超临界流体和液相进料处引入水力空化混合器,强化两相间的混合.考察SAA-HCM过程混合器压力、温度、沉淀器温度、进料中CO2与液体溶液质量流量比和溶液质量浓度等操作参数对微粒形态和粒径分布的影响,成功制备出球形度较好,粒径分布较窄(1～3μm)的PLA微球.经X射线衍射(XRD)分析和差示扫描量热(DSC)分析显示,与原料PLA相比,微球晶型及热曲线变化不大,但结晶度下降.同时把操作参数与相行为进行关联,探讨了影响颗粒形貌的机理.对比超临界流体辅助雾化法(SAA)的实验结果表明:水力空化的引入能有效强化混合器内的两相传质,混合更好,能制备出适用于气溶胶给药要求的超细微粒.     

3—乙酰基—5—溴 酚酮的合成

2-乙酰基-7-甲氨基酮1与溴反应得2-乙酰基-7-甲氨基-4-溴酮2。2与氢氧化钠反应得3-乙酰基-5-溴酚酮3。化合物2和3是两种新化合物,其结构已经红外光谱、核磁共振谱及元素分析证实。     

SIMATIC PCS7在净水厂中的应用

介绍西门子PCS 7在大连松树山净水厂中的应用,重点阐述PCS7系统的网络配置、硬件配置、程序结构。     

4G通信技术的FPGA远程更新系统设计

为了解决在恶劣环境、偏远地区等特殊场合的FPGA远程更新问题,提出了一种基于4G无线通信技术的FPGA远程更新系统设计方法。应用4G无线通信模块实现了更新控制器的通信组网,远程控制器通过4G网络与更新控制器建立通信连接,下发控制命令实现FPGA的远程更新。通过实际测试验证了新方法的可行性、正确性,有效弥补了传统更新方法布线复杂、效率低、距离短等不足,提高了设备维护效率、降低了维护成本,对工程应用具有重大意义。     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.     

Intermetallic phase formation in directionally solidified Al−Si−Fe alloy

The present study has been undertaken to better understand the solidification behavior of Al−Si−Fe alloys containing 7wt.% Si and 0.9wt.% Fe, with particular regard to the formation of phase during controlled solidification and influence of growth rates on intermetallic phase selection. The alloys studied were Al-7Si-0.9Fe alloys, which were produced by a modified Bridgman solidification arrangement. These alloys were solidified unidirectionally with different growth rates (1–30mm/min). The solidified microstructure of these alloys consists of the growth of primary aluminum and multiple second phase reactions.