塔巴庙区块气层录井参数分析研究

塔巴庙区块气藏属于低压、低渗气藏,储集层物性差异大、含气级别高,但含气非均质性强,录井解释评价困难。针对这一问题,开展了综合判断储集层物性和含气性方面的研究,分别探讨了钻时与全烃、钻井液性能与全烃、钻井液粘度与全烃、气测显示与测井参数和烃组分与气显示之间的关系,分析了其相关性及其在塔巴庙区块气层解释评价中的意义及作用。通过相关性研究,不但摸索出定性解释评价气层的方法,同时为今后深入研究录井相关参数关系,探索其内在规律,为实现准确解释评价储集层奠定了基础。     

Stress analysis of pin-loaded woven-glass fiber reinforced epoxy laminate conveying chain components

The aim of this study is to examine the effects of various loading conditions on the stress of a pin-loaded woven-glass fiber reinforced epoxy laminate conveying chain component. A numerical and experimental study was carried out to determine the stress distribution of composite conveying chain components used to convey loads. For the experimental study, an apparatus was developed to simulate chain components in real motion. Two different working conditions of the chain component were investigated. The first condition represents the movement of the chain components without loading. In the second condition, the chain component touches and moves the load. The commercial finite element package ANSYS was used to perform the numerical analysis using a three dimensional eight-noded layered structural solid elements. Chain tensile forces were loaded through pins and chosen as 250, 500, 750, 1000 and 1250 N for the two conditions of chain components. Experimental and numerical studies were compared and discussed for two conditions and five different tensile forces. A good agreement between experimental results and numerical predictions is obtained.     

Development of calibration models for quality control in the production of ethylene/propylene copolymers by FTIR spectroscopy,multivariate statistical tools,and artificial neural networks

Principal component regression (PCR), partial least squares (PLS), StepWise ordinary least squares regression (OLS), and back‐propagation artificial neural network (BP‐ANN) are applied here for the determination of the propylene concentration of a set of 83 production samples of ethylene–propylene copolymers from their infrared spectra. The set of available samples was split into (a) a training set, for models calculation; (b) a test set, for selecting the correct number of latent variables in PCR and PLS and the end point of the training phase of BP‐ANN; (c) a production set, for evaluating the predictive ability of the models. The predictive ability of the models is thus evaluated by genuine predictions. The model obtained by StepWise OLS turned out to be the best one, both in fitting and prediction. The study of the breakdown number of samples to be included in the training set showed that at least 52 experiments are necessary to build a reliable and predictive calibration model. It can be concluded that FTIR spectroscopy and OLS can be properly employed for monitoring the synthesis or the final product of ethylene–propylene copolymers, by predicting the concentration of propylene directly along the process line. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Influence of third monomer on the crystal phase transition behavior of ethylene-tetrafluoroethylene copolymer

Crystal phase transition between the low- and high-temperature phases has been investigated for ethylene (E)-tetrafluoroethylene (TFE) alternating copolymer (ETFE) containing the third monomeric species by the temperature dependent measurements of wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) and differential scanning calorimetry. Nonafluoro-1-hexene (NFH) and hexafluoropropylene (HFP) were chosen as the third monomers, where they are different in the side-branch length, -(CF₂)₃CF₃ and -CF₃, respectively. In the case of E/TFE/NFH copolymer (ET-C4F9), the crystal phase transition temperature of the original ETFE two-components copolymer was not very much affected by the existence of NFH in the range of NFH content from 0.7 to 3 mol%. Contrarily, the crystal phase transition temperature of E/TFE/HFP copolymer (ET-CF3) was found to decrease drastically with increasing HFP content. The melting temperature and the higher-order structure were also affected sensitively depending on the HFP content. This difference in phase transition behavior between ET-C4F9 and ET-CF3 copolymers is reasonably interpreted as follows: the short side groups (-CF₃) of HFP monomeric unit are included in the crystal lattice of E/TFE chains and the unit cell is expanded gradually with an increment of the HFP content, resulting in the decrease in phase transition point because of easier thermal motion of the chains. On the other hand, the long side groups [-(CF₂)₃CF₃] of NFH monomeric units are excluded out of the crystal lattice and located on the lamellar surfaces or in the amorphous region and do not affect very much the phase transition temperature even when the NFH content is increased. In association with such a change in crystal structure, the long period of stacked lamellar structure was found to decrease remarkably in the case of NFH, whereas it does not change very much for HFP, consistent with the interpretation of the above-mentioned WAXD data.     

聚酯装置熔体过滤器的国产化改造

熔体过滤器为聚酯装置关键设备,其国产化问题一直未能解决。该文通过对天津分公司200kt/a聚酯装置熔体过滤器改造方案的介绍,探讨了其国产化条件,分析了国产熔体过滤器的结构特点,并与进口过滤器进行了对比,提出了一些看法。     

结构安全性综合评估方法的研究

已有结构的安全性的评估是关系到社会经济、安全的重大问题。本文作者从临界结构入手，以构件失效影响面积为参考，得到了计算构件重要性系数的简便方法，结合构件的可靠度提出了定性与定量结合的结构安全性综合评估方法。从工程实例来看，本文提出的方法简单实用，与现行的鉴定标准符合得比较好。     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

新型引线热浸镀锡合金的研究

分析比较了进口锡与国产锡的成分和性能。设计出了新型的引线热浸镀锡合金，它具有较低的工作温度、优良的抗氧化性、流动性和可焊性。     

ALGORITHMIC SYNTHESIS OF GENERAL NON-SHARP SIMPLE DISTILLATION COLUMN SEQUENCES

An algorithmic approach was used to select recoveries for non-sharp sequence designs. Simple distillation columns were employed. The non-key component distribution was modeled using the Fenske equation. The combination of producing impure products and allowing non-key component distribution, results in a large search space. With this large search space size and software limitations, five problems were solved (see summary table in the Design Examples sub-section). The optimal non-key component distribution was found to be significant but not necessarily maximal. Parallel processing was selected as optimal in contrast to the more traditional sequential processing.