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51.
The titanium carbides are potential candidates to achieve both high hardness and refractory property. We carried out a structural search for titanium carbides at three pressures of 0 GPa, 30 GPa and 50 GPa. A phase diagram of the Ti-C system at 0 K was obtained by elucidating formation enthalpies as a function of compositions, and their mechanical and metallic properties of titanium carbides were investigated systematically. We also discussed the relation of titanium concentration to the both mechanical and metallic properties of titanium carbides. It has been found that the average valence electron density and tractility improved at higher concentrations of titanium, while the degree of covalent bonding directionality decreased. To this effect, the hardness of titanium carbide decreases as the content of titanium increases. Our results indicated that the titanium content significantly affected the metallic properties of the Ti-C system. 相似文献
52.
A number of semiflexible homopolyazomethines and copolyazomethines based on hydroxy-functionalised mesogenic cores have been synthesised and characterised. The reported polymers include structural modifications such as an alteration of the coaxiality, shortening of the flexible spacers or copolymerisation to attain materials with reduced melting temperatures and suitable processability. These structural alterations have been introduced by condensing different ,ω-bis-[(4-formyl-3-hydroxyphenyl)oxy]alkanes with 2-methyl-1,4-phenylenediamine and/or 4-methyl-1,3-phenylenediamine. Fibres have been melt extruded from those nematic polyazomethines with the most favourable thermal properties. As-spun and tension-annealed fibres have been investigated by thermal analysis (TGA and DSC), X-ray diffraction and SEM microscopy in an attempt to infer a relationship between microstructure and tensile properties. From the results presented here, copolymerisation incorporating flexible spacers of different lengths seems to be the best strategy to balance ease of processing and tensile properties. Some of the fibres have improved mechanical properties compared with those previously reported for this class of semiflexible polyazomethine. A nematic polyazomethine with a decamethylenic spacer has also been modified with low percentages of several metal ions [Fe(III), Zn(II), V(IV) and Ni(II)] in order to establish a comparison with previously reported Cu(II)-modified fibres. 相似文献
53.
Kuniaki Honjo 《Carbon》2003,41(5):979-984
Fracture toughness (KIC) of representative high-strength type PAN (polyacrylonitrile)-based carbon fibers, Torayca™ T300 and T800H, with or without artificial surface defects, were estimated to be ca. 1 MPam1/2 from the tensile strength vs. fracture mirror size relation, assuming a constant crack-to-mirror size ratio. The corresponding critical energy release rate (Γ) was ca. 7.4 J m−2, which was close to the value derived from the reported surface energies for a graphite crystal. Similar KIC values were obtained for the old-type PAN-based carbon fibers from the reported data by the use of the present estimation procedure. 相似文献
54.
The present paper includes experimental and analytical data on the fracture properties of a nickel-iron superalloy, a ferromagnetic austenite, at 4 K in magnetic fields of 0 and 6 T. The tensile, notch tensile and small punch tests are employed. A finite element analysis is also performed to convert the experimentally measured load-displacement data into useful engineering information. To interpret the results we review the available theory of the influence of magnetic field on the stress intensity factor for a crack in ferromagnetic materials. 相似文献
55.
T. Choi J.‐H. Jang C.K. Ullal M.C. LeMieux V.V. Tsukruk E.L. Thomas 《Advanced functional materials》2006,16(10)
The probing of the micromechanical properties within a two‐dimensional polymer structure with sixfold symmetry fabricated via interference lithography reveals a nonuniform spatial distribution in the elastic modulus “imprinted” with an interference pattern in work reported by Tsukruk, Thomas, and co‐workers on p. 1324. The image prepared by M. Lemieux and T. Gorishnyy shows how the interference pattern is formed by three laser beams and is transferred to the solid polymer structure. The elastic and plastic properties within a two‐dimensional polymer (SU8) structure with sixfold symmetry fabricated via interference lithography are presented. There is a nonuniform spatial distribution in the elastic modulus, with a higher elastic modulus obtained for nodes (brightest regions in the laser interference pattern) and a lower elastic modulus for beams (darkest regions in the laser interference pattern) of the photopatterned films. We suggest that such a nonuniformity and unusual plastic behavior are related to the variable material properties “imprinted” by the interference pattern. 相似文献
56.
CMP系统技术与市场 总被引:3,自引:1,他引:2
葛劢冲 《电子工业专用设备》2003,32(1):17-24
概述了CMP系统技术的发展历史、发展趋势以及在IC生产中的重要性,介绍了国外CMP设备主要制造厂家的设备型号和性能及CMP设备市场分布和需求,阐述了CMP系统技术的基础研究、关键技术和国内研究概况。 相似文献
57.
58.
The aim of this work was to establish the important parameters that control the hot compaction behaviour of woven oriented polypropylene. Five commercial woven cloths, based on four different polypropylene polymers, were selected so that the perceived important variables could be studied. These include the mechanical properties of the original oriented tapes or fibres, the geometry of the oriented reinforcement (fibres or tapes), the mechanical properties of the base polymer (which are crucially dependant on the molecular weight and morphology), and the weave style. The five cloths were chosen so as to explore the boundaries of these various parameters, i.e. low and high molecular weight: circular or rectangular reinforcement (fibres or tapes): low or high tape initial orientation: coarse or fine weave.A vital aspect of this study was the realisation that hot compacted polypropylene could be envisaged as a composite, comprising an oriented ‘reinforcement’ bound together by a matrix phase, formed by melting and recrystallisation of the original oriented material. We have established the crucial importance of the properties of the melted and recrystallised matrix phase, especially the level of ductility, in controlling the properties of the hot compacted composite. 相似文献
59.
通过加入增强剂、增韧剂、抗氧剂等添国剂可改善聚丙烯力学性能。以SiO2为填料,丁苯橡胶(SBS)为增韧剂,探讨SiO2、丁苯橡胶含量对共混体系强度、韧性的影响,结果表明,在SBS含量大于5%、SiO2一小于10%的范围内,可使PP/SiO2/SBS复合的拉伸弹性模量和冲击强度明显提高,其力学性能均为均衡。 相似文献
60.
SiC/Al合金层状复合材料的机械性能及损伤行为 总被引:5,自引:0,他引:5
张永俐 《材料科学与工程学报》1994,(4)
在室温条件下测定了Al合金以连续层状形式存在于SiC陶瓷层间并渗透入SiC陶瓷层内、Al合金浓度呈层状变化高低相间,以及Al合金和SiC陶瓷均匀分布相互渗透三种SiC含量相同而结构形式不同的SiC/Al合金复合材料的机械性能;用SEM和光学显微镜观察分析了复合材料的断口形貌及裂纹扩展过程。结果表明,在SiC陶瓷层间以连续层状形式存在的Al合金在应力作用下发生较大程度的塑性变形,在裂纹尾部被拉伸和形成桥接,引起能量耗散,减缓裂纹扩展速度,防止裂纹张开,使复合材料的韧性得到明显改善;SiC/Al合金陶瓷─金属层状复合材料的损伤形式主要是SiC陶瓷层开裂、金属层桥接和裂纹偏转。 相似文献