一种环保化学储能电池——钒氧化还原液流电池

可再生能源需要性能优良的储能电池与之配套，因此，研究和开发价廉、高效率的储能系统是十分必要的。本文通过介绍钒氧化还原液流电池的原理和特点，指出钒电池是一种潜力巨大的新型环保储能电池。同时介绍钒电池制备和应用时的三大技术关键及一定的解决方法。     

Investigations of ferritic/martensitic super heat resistant 11‐12 %Cr steels for 650 °C power plants

The investigations of advanced ferritic/martensitic 11–12 %Cr steels for 650 °C power plant components focus on the improvement of high‐temperature creep properties with respect to chemical composition. The claim of the DFG research work was the development of new heat‐resistant 12 %Cr ferritic‐martensitic steels with sufficient creep and oxidation resistance for a 650 °C application by using basic principles and concepts of physical metallurgy on the basis of the state of art and to overcome the usual trial and error industrial alloy development. Efforts are focussed on a 100,000h creep strength of 100MPa at 650 °C in combination with a sufficient corrosion resistance by a Cr content of 12 % with contents 4‐5 %W, 3.4‐5,5 %Co, V, B and 1 %Cu as well as the choice of Ta or Ti instead of Nb. The results demonstrate that the aim is not to realize with the used alloying concept. In the long term range all 12 %Cr melts have a lower creep rupture strength than the advanced 9 %Cr piping steel P92. A high creep strength could be reached with a 0.06 % Ta alloyed 11 %Cr melt, which is in addition alloyed with a higher C and B content and as well as with lower W and Co portions. The results indicate in accordance with the finding of other steel researcher that a lower Cr content allows more effectiveness for the alloying partners respectively for the generation of more stable precipitates.     

钒氮钢中铁素体等温形核规律的试验研究

采用Geeble 3500热模拟试验机，对比研究了钒氮钢、钒钢的等温相变特征。结果表明，在相变过程中，钒氮钢中铁素体形核总量和晶内铁素体形核数量都明显高于钒钢，分析认为，这与钒氮钢中V（C，N）的析出造成了铁素体形核位置的改变，同时也增加了形核位置密度有关，尝试用一种新的形核方式对此进行了描述。     

Effects of various environments on fatigue crack growth in Laser formed and IM Ti–6Al–4V alloys

The fatigue crack growth behaviors of Laser formed and ingot metallurgy (IM) Ti–6Al–4V alloys were studied in three environments: vacuum, air and 3.5% NaCl solution. Taking the Unified Fatigue Damage Approach, the fatigue crack growth data were analyzed with two intrinsic parameters, stress intensity amplitude ΔK and maximum stress intensity K_max, and their limiting values ΔK^* and . Fatigue crack growth rates da/dN were found increase with stress ratio R, highest in 3.5% NaCl solution, somewhat less in air and lowest in vacuum, and higher in IM alloy than in Laser formed one. In 3.5% NaCl solution, stress corrosion cracking (SCC) was superimposed on fatigue at R=0.9 for where K_max>K_ISCC, the threshold stress intensity for SCC. This and environment-assisted fatigue crack growth were evidenced by the deviation in fatigue crack growth trajectory (ΔK^* vs. curve) from the pure fatigue line where . Furthermore, the fractographic features, identified along the trajectory path, reflected the fatigue crack growth behaviors of both alloys in a given environment.     

The recovery and recrystallization of cold rolled V-W-Ti alloys

Several V-W-Ti alloys with about 50% reduction in thickness by cold rolling were isochronally annealed at temperatures from 100 to 1100 °C. Hardness was measured after the annealing. By comparison with V4Cr4Ti and V4Ti alloys, the V6WTi alloy was found to begin recovery at a temperature about 100 °C higher, while the full recrystallization temperature was around 900 °C for all of the alloys. Hardness decreased successively above 500 °C in V8W, as is the case in pure V. Impurity induced hardening was observed around 300 °C only in the alloys without Ti. Precipitation and the interaction between interstitial impurities and dislocations were supposed to be the main contributors to the different recovery and recrystallization behaviors of the alloys.     

Nanocomposite Films of V_2O_5-MoO_3 Xerogel with Poly Ethylene Oxide Intercalation

1　IntroductionItiswell establishedthatsomeinorganiclayeredcompoundssuchasMoO3 ,V2 O5canbeintercalatedbyavarietyofalkaliions (Li+ ,Na+ ,etc .) ,atomsandlargermoleculestoformintercalationhost guestcompounds ,whichareexpectedtobeusedaspotentialcathodicmate rialsinsecondaryLibatteriesandelectrochromicdevice s[1] .Thepolymer layeredoxidenanocompositeshaveat tractedmuchattentionduetotheirspecialstructureaswellassuperiorelectrical,electrochemicalandopticalproperties .Recently ,nanocompositesof (P…     

第二十届国际原电池和蓄电池会议评述

世界小型蓄电池市场现状及发展趋势分析表明,金属氢化物镍蓄电池开始下降,镉镍蓄电池保持稳定,而锂离子蓄电池仍然处于快速增长态势。预计2003年锂离子蓄电池产量将达到12.55亿只,比2002年增长45%,销售额将达36.14亿美元,比2002年增长29%,价格比2002年下降16%;同时,新型电池技术发展也依然强劲,其中呈现了三个热点技术领域,即锂离子蓄电池及相关材料,42V和混合电动车蓄电池,燃料电池。对上述热点领域的技术发展现状及趋势作了评述。     

V带疲劳寿命P—S—N曲线研究

本文在讨论Ｖ带寿命概率分布的基础上，着重研究其寿命－载荷关系和分散性变化规律，并给出了解放牌汽车气泵Ｖ带的Ｐ－Ｓ－Ｎ曲线．最后，对实验数据进行了分析总结     

橡塑磁条在永磁音像微特电机中的应用

本文简述了橡塑磁条的制造工艺及在永磁音像电机规模生产中的应用，与铁氧体烧结磁环进行比较，阐述了橡塑磁条在音像微特电机中使用的优势。     

快速凝固热强Al-4Ti-2V-3La合金的显微结构和力学性能的研究

采用金相（ＯＭ）、透射电镜（ＴＥＭ）、扫描电镜（ＳＥＭ）等先进技术研究了快速凝固Ａｌ－４Ｔｉ－２Ｖ－３Ｌａ合金，确定了基体中弥散分布的细小强化相为单一的Ａｌ２０（Ｔｉ，Ｖ）２Ｌａ相，结构为金刚石立方结构，晶格常数ａ＝１．４７ｎｍ。该性能接近当前较成熟的热强铝合金，说明快凝Ａｌ－Ｔｉ－Ｌａ基合金作为热强铝合金具有潜在的实力。