Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

薄膜波导光隔离器和光电子单片集成技术

叙述了Ｂｉ，Ａｌ：ＹＩＧ薄膜的液相外延生长，研究了这种薄膜材料的光吸收系数、法拉第旋转角、磁光优值及生长感生磁各向异性与Ｂｉ含量的关系。在此基础上，连续外延生长了作单模磁光波导的双层Ｂｉ，Ａｌ：ＹＩＣ薄膜。光纤偏振器的使用使薄膜波导光隔离器向实用化迈进了一步，恒磁薄膜作偏磁场为器件集成化作出了贡献。采用ＭＯＣＶＤ技术，在ＧＧＧ（钆镓石榴石）基片上同时外延生长Ⅲ－Ⅴ族半导体薄膜和钇铁石榴石（ＹＩＧ）薄膜，把光隔离器和磁光光源直接集成在一起，是一种非常有前景的光电子集成组件。     

4×622Mb／sWDM40km光通信系统实验

本文完成了我国第一个４×６２２Ｍｂ／ｓ波分复用（ＷＤＭ）光通信系统实验，使单根光纤线路通信容量达２．４Ｇｂ／ｓ。该系统以ＤＦＢ－ＬＤ为光源，工作波长在１．５５μｍ附近，ＬＤ的工作频率稳定度优于±１５０ＭＨｚ，信道间隔２ｎｍ左右，无中继传输距离为４３．６ｋｍ，采用Ｆ－Ｐ调谐光滤波器作为解复用器，接收机灵敏度达－３０ｄＢｍ。     

光纤的淬冷增强原理

本文从拉丝工艺技术的角度出发，讨论了高速、高温拉丝工艺方法对光纤的淬冷增强原理。     

自聚焦棒耦合性能的分析

本文采用光线光学的原理分析了自聚焦棒（ＧＲＩＮ）的光学性能，在折射率分布为抛物线近似的条件下，推导出较为简单的ＧＲＩＮ中的光线轨迹方程，并实验测量了ＧＲＩＮ的耦合效率，从而由理论和实验两方面讨论ＧＲＩＮ的聚焦特性。     

凸非球面补偿检验的工艺球面分析解

本文从三级像差理论出发,推导了几种工艺球面检验凸二次曲面的计算公式。根据这些公式计算结果,进行了光路追迹,给出了这些公式对凸二次曲面的补偿范围;并讨论了几种特殊情况下的平面解。     

A novel design in composities of various materials for solar selective coatings

This study describes the development of multilayer metal-dielectric graded index solar selective coatings in which the metallic volume fraction increases with depth, from top (air–film interface) to bottom (film–substrate interface). The work is based on computer simulation followed by validation through fabrication of the coatings and optical measurements. The influence of the choice of the number of layers present in a graded index composite selective absorber and results obtained for a new destructive interference bilayer (four-layer system) coating, designed using the computer model, were studied. The design and optimization of the composite coating was undertaken using a computer tool developed within this program of research employing Bruggeman and Maxwell–Garnett effective medium formalisms. The design tool enabled all key design parameters, with the exception of particle size and orientation, to be varied systematically to permit the sensitivity of the optical properties of the selective absorber coating to be studied.The model was validated with a supporting program of experimental research in which many different selective absorbers were prepared by co-sputtering of metal and dielectric materials.Although the best compositional gradation can be achieved by increasing the number of layers, the variation in optical performance beyond a certain number of layers is minimal. The destructive interference produced between adjacent layers contributes to the absorptance. The effect of the number of layers (single, four and 10) has been calculated for various materials such as nickel, vanadium, tungsten, cobalt and chromium based coatings. Solar absorptance of 0.98 and 0.96 was achieved by simulation and experimental findings with less than 0.07 thermal emittance at 300 K for 200 nm thick, 4-PGSAC (four-layer system) of V : Al₂O₃ composites. Other designs showed lower optical performance for all the material combinations regardless of their individual optical properties. Use of such thin film coating on the absorbers of solar thermal appliances can reduce thermal losses significantly, which could be of importance to the relevant industry.     

光纤数字环路载波系统的发展

ＯＤＬＣ是当今用户接入网的新型设备，它一方面可取代端局，解决通信线路紧张和远距离大容量放号问题，另一方面也可满足日益增多的增值业务的需求。本文ＯＤＬＣ技术的基本原理，结合目前国内外常见ＯＤＬＣ系统，总结和对比了其基本特点，优势，并指明ＯＤＬＣ的技术发展方向和中国应用的前景。     

基于片上DC-DC的CMOS光接收机前置放大器

利用CSMC 0.6μm CMOS工艺,设计了基于片上DC-DC转换器的光接收机前置放大器。电路采用可调跨阻放大器与片上DC-DC结构,有效地克服了单端跨阻放大器易受电源波动的干扰,并解决了高灵敏度与低失真相互矛盾的问题。模拟结果表明,输入动态范围为83 dB(峰-峰值=0.2μA~3 mA),等效输入电流噪声为1.2 pA/Hz(155 MHz),可稳定工作在155 Mb/s速率上;在5 V电源电压下,功耗为95 mW。     

基于晶体双折射的光学FIR滤波器设计

提出建立在晶体双折射基础上，由晶体延迟片堆组成的光学FIR（Finite Impulse Response)滤波器设计方法，用以实现任意形状光谱输出。从FIR信号理论出发，建立了光学FIR滤波器数学模型，并分析了它与FIR滤波器的映射关系。在给出“输出反向传递法”来完成其光学实现同时，还以G／M滤波器设计实例证明其优良的光谱特性及角度特性。