Composite group vector space method for estimating melting and boiling point of pure organic compound

Composition Group Vector Space (CGVS) method for estimating melting and boiling point T _m , T _b of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T _m , T _b have been established and the numerical values of relative parameters have been presented. The average percentage deviations of T _m , T _b estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.     

Chemical vapor deposition of aluminum for ulsi applications

Aluminum has been used widely as a conducting material in the fabrication of integrated circuits, and chemical vapor deposition process for Al has been actively investigated for the application in ultra large scale integration. In this review, various precursors, mainly alkyl aluminum and alane compounds, and reaction mechanisms of these precursors in Al CVI) are described. Epitaxial growth and selectivity of the deposition are also discussed. In addition to thermal reactions, plasma and photochemical reactions are also briefly described.     

Electroluminescence from phenylenevinylene-based polymer blends

The electroluminescent behaviour of films of poly(phenylphenylenevinylene) (PPPV), of PPPV blended with polystyrene (PS) and of PS doped with oligo(phenylenevinylene) sandwiched between indium–tin oxide (ITO) and Al contacts has been investigated. Polymer blending increases the relative quantum efficiency by up to two orders of magnitude. Studying the cell performance under application of rectangular voltage pulses as a function of temperature indicates that (i) hole injection at the ITO contact occurs by tunnelling, (ii) tunnel injection of electrons at the cathode is promoted by a space charge field across an interfacial Al₂O₃ layers and (iii) leakage of holes through the cathodic barrier is the main loss mechanism for holes.     

Electrochemical properties of ultra-long,aligned, carbon nanotube array electrode in organic electrolyte

The electrochemical properties of an electrochemical double-layer capacitor electrode based on an ultra-long (500 μm), aligned, carbon nanotube array (ACNTA) in Et₄NPF₆/propylene carbonate electrolyte are examined. The specific capacitance of the ACNTA electrode in an organic electrolyte is 24.5 F g⁻¹, which is larger than that obtained in an aqueous electrolyte. The results of ac impedance measurements show that the ACNTA electrode gives a high power density and an excellent rate capability in an organic electrolyte. It is shown that the ACNTA electrode has a lower equivalent series resistance and a better rate capability than activated carbon electrode. This is due to the fact that ACNTA possesses a larger pore size and a more a regular pore structure. Both these features are conformed by scanning electron microscopic and nitrogen gas adsorption studies.     

Evaluation of different coating systems by electrochemical methods

Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests.     

两种具有电双稳态的全有机络合物

首次发现两种在室温下即具有电双稳态的全有机（有机-有机）络合物，分别称为MCA＋TCNQ和BBDN＋TCNQ。它们可在真空中制备成薄膜，在数伏电压的作用下，从高电阻至低电阻的跃迁时间小于100ns，因此可作为一次写入的存储器材料。根据我国目前最小刻线宽度的水平，可望在1．6cm2的SiO2平面上做出64Mb的存储器。     

Electrochemical injection of organic corrosion inhibitors into carbonated cementitious materials: Part 1. Effects on pore solution chemistry

This series of investigations was intended to clarify phenomena associated with electrochemical injection of the organic base corrosion inhibitors, ethanolamine and guanidine, into carbonated concrete. In Part 1, experiments were conducted with laminated specimens of carbonated cement paste, that were specially designed to facilitate analysis with adequate spatial resolution to assess changes in their pore solution phase chemistry after they had been subjected to constant current electrolysis between embedded cathodes and external anodes. The anolyte solutions provided sources of ethanolamine or guanidine in contact with the exterior specimen surfaces. Effects of variations in the applied current density and duration of electrolysis on the concentration profiles of the two inhibitors and the other main constituents of the pore solution phase were determined. The results have been used to underpin the development of a mathematical model, which is described in Part 2.     

取代水杨醛Schiff碱金属配合物催化氧化脱硫性能

以水杨醛类Schiff碱为配体,与Co(NO_3)_2、Cu(NO_3)_2反应合成6种Salen(M)型配合物Ⅰ～Ⅵ。以1-己硫醇、二丁基硫醚和2-甲基噻吩为模型化合物配制模拟油体系,考察了配合物Ⅰ～Ⅵ的催化氧化脱硫性能,并分析了配合物结构与氧化脱硫性能的关系。结果表明,6种配合物在75 min时的总脱硫效果为Ⅵ>Ⅴ>Ⅳ>Ⅰ>Ⅲ>Ⅱ,Ⅵ的总脱硫率为31.9%。对1-己硫醇及二丁基硫醚脱除效果最佳的是Ⅴ,脱除率分别为74.2%和65.1%;对2-甲基噻吩脱除效果最好的是Ⅰ,脱除率为26.8%。构效关系研究表明,中心金属离子与O_2的配位能力越强,配体的共轭体系越大、电子云密度越高,配合物的脱硫性能越好;通过IR和离子色谱对单一硫化物模拟油体系氧化前后的产物进行分析发现,硫化物氧化后皆生成相应的砜类或亚砜类,且1-己硫醇和二丁基硫醚被进一步氧化生成SO_3~(2–)或SO_4~(2–)。     

Effects Of Ozone On The Production Of Biodegradable Dissolved Organic Carbon (BDOC) During Water Treatment

This article deals with the oxidation effect of ozone on the increasing fraction of biodegradable organic matter with the “ozotest” method, a laboratory technique which simulates the effect of ozonation and allows a complete oxidation assessment. Ozone treatment was performed on river water samples and sand filter effluent samples. Ozone consumption, reduction of UV absorbance and BDOC formation were monitored with applied ozone doses from 0 to 10 mg/L and with contact times from 0 to 60 min. The BDOC formation was optimum at an applied ozone dose of 0.25-0.5 mg O₃ per mg DOC (contact time = 5 min) corresponding to apparition of traces of residual ozone and maximum UV reduction. Maximum ozone consumption, UV reduction and BDOC formation occurred simultaneously during the first two minutes of treatment. Concerning BDOC formation, applied ozone dose showed a greater effectiveness than contact time. For the same quantity of consumed ozone, a short contact time associated with a high ozone dose was preferable to a long contact time and a low ozone dose.     

Preparation of DNA-encapsulated polyethersulfone hollow microspheres for organic compounds and heavy metal ions removal

DNA-encapsulated polyethersulfone (PES) hollow microspheres are fabricated by means of a liquid-liquid phase separation technique; the hollow microspheres are then used to remove environmental pollutant organic compounds and heavy metal ions. The amounts of DNA encapsulated in the microspheres are dependent on the PES concentration, the DNA concentration used to prepare the particles, and the diameter of the syringe needle. The hollow microspheres can be used to remove harmful organic compounds including ethidium bromide (EB), acridine orange (AO) and endocrine disruptors. With the increase of the DNA amount encapsulated into the hollow microspheres, the removal ratios of these compounds increased. Additionally, the DNA-encapsulated PES hollow microspheres can selectively accumulate and remove heavy metal ions such as Ag⁺, Cu²⁺ and Zn²⁺ These results suggested that the DNA-encapsulated PES hollow microspheres have a potential to be used in environmental applications.