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排序方式: 共有4037条查询结果,搜索用时 15 毫秒
61.
This paper deals with the activity of the KCu and KCo catalysts supported on beta-zeolite for the simultaneous NOx/soot removal from a simulated diesel exhaust, containing C3H6 as model hydrocarbon. In order to reveal the effect of potassium, the corresponding monometallic catalysts (Co/beta and Cu/beta) were analyzed and different potassium loadings were used. In addition, for comparative purpose, the performance of a platinum based catalyst (Pt/beta) was studied. All noble-free catalysts show, at 450 °C, a high activity for the simultaneous NOx/soot removal. Among them, K1Cu/beta presents the best global performance at 350 and 450 °C achieving a high soot consumption rate (comparable to platinum catalysts) and the highest NOx reduction. In contrast to platinum catalysts, K1Cu/beta has the advantage that the main reaction products are N2 and CO2. 相似文献
62.
The loss in activity of Pt-promoted and unpromoted 25 wt% Co–Al2O3 catalysts has been compared under identical conditions except for adjustment of the space velocity to give the same initial CO-conversion. Both catalysts underwent a 200 h period of rapid, initial decline in CO conversion and then a slower, linear decline during the next 1000 h. Pt-promotion did not alter the cobalt dispersion (or average particle size) from that of the unpromoted catalyst but did increase the amount of cobalt that was reduced. When compared not by time-on-stream, but by the moles of Co converted per unit weight of catalyst, both the Pt-promoted and unpromoted catalysts decline in activity at the same rate. 相似文献
63.
64.
Tatjana Rades Chanho Pak Michèle Polisset-Thfoin Ryong Ryoo Jacques Fraissard 《Catalysis Letters》1994,29(1-2):91-103
NaY-supported bimetallic Pt-Pd catalysts have been studied by TEM, TPR and EXAFS. Small, randomly mixed particles are formed in the zeolite cages. When the Pt content is increased, a Pt core structure appears and the dispersion increases. Particle diameters are about 1–2 nm for bimetallic samples. 相似文献
65.
66.
This research aims to enhance the activity of Pt catalysts, thus to lower the loading of Pt metal in fuel cell. Highly dispersed platinum supported on single-walled carbon nanotubes (SWNTs) as catalyst was prepared by ion exchange method. The homemade Pt/SWNTs underwent a repetition of ion exchange and reduction process in order to achieve an increase of the metal loading. For comparison, the similar loading of Pt catalyst supported on carbon nanotubes was prepared by borohydride reduction method. The catalysts were characterized by using energy dispersive analysis of X-ray (EDAX), transmission electron micrograph (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectrum (XPS). Compared with the Pt/SWNTs catalyst prepared by borohydride method, higher Pt utilization was achieved on the SWNTs by ion exchange method. Furthermore, in comparison to the E-TEK 20 wt.% Pt/C catalyst with the support of carbon black, the results from electrochemical measurement indicated that the Pt/SWNTs prepared by ion exchange method displayed a higher catalytic activity for methanol oxidation and higher Pt utilization, while no significant increasing in the catalytic activity of the Pt/SWNTs catalyst obtained by borohydride method. 相似文献
67.
The chemical equilibrium for the coupling of ethylbenzene dehydrogenation with nitrobenzene hydrogenation, to produce styrene and aniline simultaneously, has been calculated on the basis of the Soave–Redlich–Kwong equation of state. The dehydrogenation of ethylbenzene in the presence of nitrobenzene over the catalysts -Al2O3, ZSM-5, activated carbon and platinum supported on activated carbon has been carried out at 400 °C. The effects of Pt loading and the pretreatment of the catalysts have been investigated. It has been revealed that the conversion of ethylbenzene can be greatly improved by the reaction coupling due to the elimination of the hydrogen produced in the reaction by the hydrogenation of nitrobenzene. Platinum supported on the activated carbon has been suggested as a suitable catalyst. The best results with ethylbenzene conversion of 33.8% and styrene selectivity of 99.2% were obtained over Pt(0.02 wt%)/AC at 400 °C. Moreover, such process is also energetically favored since the necessary process heat to drive the ethylbenzene dehydrogenation can be provided by the coupling with the exothermic nitrobenzene hydrogenation reaction. 相似文献
68.
The enantioselective hydrogenation of ethyl pyruvate to (S)-ethyl lactate over cinchonine- and -isocinchonine-modified Pt/Al2O3 catalysts was studied as a function of modifier concentration and reaction temperature. The maximum enantioselectivities obtained under the applied mild conditions were 89% ee using cinchonine (0.014 mmoldm–3, 1 bar H2, 23°C, 6% AcOH in toluene), and 76% ee in the case of -isocinchonine (0.14 mmoldm–3, 1 bar H2, –10°C, 6% AcOH in toluene). Since -isocinchonine of rigid structure exists only in anti-open conformation these data provide additional experimental evidence to support the former suggestion concerning the dominating role of anti-open conformation in these cinchona-modified enantioselective hydrogenations. 相似文献
69.
Shrikrishina D. Sartale Huang-Wei Shiu Wen-Hua Wen Meng-Fan Luo Y. C. Lin Yao-Jane Hsu 《Catalysis Letters》2007,119(1-2):95-100
Using a scanning-tunneling microscope, reflection high-energy electron diffraction and photoelectron spectra with synchrotron
radiation, we investigated the temperature dependence of the dehydrogenation of cyclohexene (C6H10) adsorbed on Pt nanoclusters supported on an ultra-thin film of Al2O3/NiAl(100). The Pt clusters, grown by vapor deposition, are structurally ordered and exhibit a mean diameter 2.2 nm and height
0.4 nm. The progress of dehydrogenation was monitored through the temporal variation of C 1s photoelectron spectra; analysis
of these features revealed that the dehydrogenation of cyclohexene with increasing sample temperature occurs as a sequential
process beginning around 150 K, a temperature significantly less than that for Pt single-crystal surfaces. The dehydrogenation
behavior, particularly the decomposition into elemental carbon, is found to vary with Pt coverage. 相似文献
70.
CeO2–ZrO2–La2O3 (CZL) mixed oxides were prepared by citric acid sol–gel method. The as-received gel was calcined at 500, 700, 900 and 1050 °C to obtain the so-called C5, C7, C9 and CK, respectively. The C5, C7 and C9 powders were impregnated with H2PtCl6 and then calcined at 500 °C to prepare P5C5, P5C7 and P5C9, respectively. The impregnated CK powders were calcined at 500, 700 and 900 °C to prepare P5CK, P7CK and P9CK, respectively. The XRD and XPS analyses show that the surface distribution of Pt is evidently influenced by the structural and textural properties of the support. The CO adsorption followed by FTIR reveals that the dispersion and the chemisorption sites of Pt are reduced as the calcination temperature of CZL support increases. The chemisorption ability of the CK samples is even completely deactivated. The encapsulation mechanism, which has been applied to explain the so-called strong metal–support interaction (SMSI) after reductive treatment, is introduced here to demonstrate the abnormal observations though the samples were prepared in oxidative atmosphere. The HRTEM results also confirm this explanation. The effects of oxygen vacancies, the chemisorption sites on the Pt surface and Pt/Ce interfacial sites on the three-way catalytic activities are discussed. 相似文献