纳米铜锰复合氧化物固相反应法的制备与表征

以乙酸铜、乙酸锰与草酸为原料,采用固相化学反应法制备了纳米铜锰复合氧化物前驱物,利用均匀设计考察了微波功率与加热时间、热分解温度及时间对产物粒径的影响。研究表明热分解温度对产品粒径的影响最大。最小粒径产物的制备条件是：微波功率540 W,微波加热时间15 min;热分解温度370℃,热分解时间2 h。XRD和TEM分析结果表明,此产品主要物相为Cu1.5Mn1.5O4,结构属立方晶系,空间群为Fd3m,平均粒径16.9-19.0 nm。应用TG-DTG和DSC技术研究了纳米铜锰复合氧化物的热分解过程以及热分解动力学,采用Ozawa积分法和Coats-Redfern积分法得前驱体的热分解机理函数均为G（α）=[-ln（1-α）]^2/3。     

Studies on miscibility in homopolymer/ random copolymer blends by equation of state theory

The miscibility of poly(methyl methacrylate) (PMMA) and styrene-acrylonitrile random copolymers (SAN) blends was investigated on the basis of the Flory—Orwoll—Vrij equation of state theory. To obtain the equation of state parameters (P*, V*_sp, T*: characteristic parameters), the pressure—volume—temperature (PVT) behaviour was measured for PMMA and a series of SANs with various acrylonitrile contents. The exchange energy parameter X_ij was also calculated by fitting the theory to some phase diagrams of PMMA/SAN blends. The Flory—Huggins interaction parameter χ was separated into two contributions based on the equation of state theory for mixtures: the exchange energy term χ_inter and the free volume term χ_free. Both the temperature and copolymer composition dependences of χ_inter and χ_free were estimated by calculations using the equation of state parameters. There exists a region in which χ_inter is negative, leading to a miscibility window in PMMA/SAN blends. However, the immiscibility at high temperatures in the blends cannot be explained only by χ_inter; it is caused by the free volume contribution, χ_free. The miscibility window behaviour in PMMA/SAN blends may be explained within the framework of the equation of state theory.     

基于VPN的远程粮情检测系统通讯软件研究

针对本地化粮情检测系统实现远程操作,研究Winsock与VPN技术在系统通讯软件中的应用。VPN技术可以大幅降低搭建专网所需的网络设备成本与管理难度,使用Winsock技术可以提供完整的TCP/IP底层协议从而减少程序开发时间。本文设计一种基于VPN的远程粮情检测系统的通讯软件,在多线程下有效利用套接字的拥塞模式并完成网络状态自检,通过设置VPN客户端提升网络传输速度,实现系统通讯软件安全、可靠、快速的运行。     

Bulk and Surface Properties of a VPO Catalyst Used in an Electrochemical Membrane Reactor: Conductivity-, XRD-, TPO- and XPS-study

In the first part of this work, the electrical conductivity of vanadium phosphorous oxide (VPO) catalyst was investigated by means of the 2-probe EIS method. The VPO showed an extremely low conductivity at low oxygen partial pressure, which is the prevailing condition in the anodic compartment in an electrochemical membrane reactor (EMR). In the second part of this study, fresh as well as VPO catalyst already used in an EMR were characterised with XRD, XPS and temperature programmed oxidation (TPO). The XRD measurements revealed an unchanged bulk phase structure after operation in the EMR. Significant differences in the average oxidation states of vanadium in the catalyst layer in the EMR were determined via XPS, where the catalyst surface facing the electrolyte membrane was more oxidised than the surface facing the anodic gas compartment. The lowered uptake and release of oxygen was observed in TPO experiments for the catalyst used in the EMR.     

影响固态发酵速率的因素及其动力学

论述了固态发酵过程中基质的形态特性、基质含水量、通气速率与气体组成、发酵温度诸因素对发酵速率的影响；探讨了固态发酵过程动力学模型及其特征。     

石蜡沉积对储层渗透率的影响研究

油气开采过程中的蜡质、沥青质等有机固相沉积。严重影响着油田的正常生产。固相沉积物不仅堵塞油井、输油管线,而且也给油藏多孔介质造成一系列的伤害。如堵塞油藏孔隙、降低孔隙度和渗透率,改变油藏岩石的润湿性,从而影响原油采收率的提高。本文采用热力学理论建立了液固两相相平衡方程,模拟计算石蜡沉积量对储层孔隙度和渗透率影响,进而求出对油井产能的影响。     

抚顺乙烯脱甲烷塔改造

通过乙烯装置脱甲烷塔系统改造后的运行状况的分析，对脱甲烷塔改造后的运行状态进行了总结，并为更进一步的优化工艺条件提出措施。     

用固体核磁技术分析PE 100管材料的抗熔垂性

用固体核磁技术分析了2种具有不同抗熔垂性能的聚乙烯管材料的凝聚态结构与流变性能。管材树脂的抗熔垂性能与其核磁迟豫特性紧密相关,好的抗熔垂性能对应更长的纵向迟豫时间。抗熔垂性能好的双峰管材料的重均分子量更高,高相对分子质量部分的含量更多。     

质量交换网络集成的状态空间法

State space approach is an effective method to mass-exchange network (MEN) synthesis. By decomposing the network into two interactive parts, a distribution network and a process operator, the synthesis problem can be formulated into a mixed integer nonlinear programming (MINLP) model. In this article, a generalized state space model based on typical MEN is established and verified in two cases. A new asymmetrical operator and cost index are also adopted to speed up the solution process. The results demonstrate the efficiency of the proposed approach.     

Compressibility of the polymer crystal

Results for the compressibilities of a wide range of polymer crystals along the fibre- and the transverse crystal axes are presented. Good agreement is found between the theoretical and the experimental results of different authors.