A theoretical approach to the kinetics of the thermal decomposition of molten thermoplastic polyurethane elastomers, under conditions of thermoplastic processing, is described. On the basis of these considerations, the thermal decomposition in different instruments (melt index analyser and measuring extruder) can be described quantitatively and the various results can be compared. As a result, identical conditions of decomposition of the melt can be defined accurately, thus opening up the possibility of combining experimental values from different instruments. The fundamental kinetic equation obtained for the kinetics of the thermal decomposition of thermoplastic polyurethanes describes the decomposition reaction and the reverse reaction (formation reaction) – which is dependent on the system of measurement and processing – as a function of the molar mass (end‐group concentration) of the original product, determined from the velocity constants for the decomposition reaction and back reaction. The consideration of the limiting value for t → ∞ is in agreement with the equilibrium constant. Consequently, the development of physical characteristic functions of thermoplastic polyurethane elastomers – independent of the system of measurement – is possible.
Experimental values and calculated curves for the thermal decomposition of PUR‐Et in a melt index analyser. 相似文献
The objective of this work was to demonstrate the utility of lignin-based resins designed for application as an adhesive in the production of particleboard. Bond qualities of lignin-phenol-formaldehyde resins, phenolated-lignin-formaldehyde resins and commercial phenol-formaldehyde (PF-com) resin were assessed by using an automatic bonding evaluation system, prior to production of particleboards. In order to evaluate the quality of lignin-based resins, particleboards were produced and physical and mechanical properties were investigated. These physical properties included internal bond, modules of rupture and modulus of elasticity. Thickness swell and water absorption properties of particleboards bonded with lignin-based resins were also determined. The lignin-based resins have been reported previously in Part I of this study. The results showed that particleboards bonded with phenolated-lignin formaldehyde resins (up to 30% lignin content) exhibited similar physical and mechanical properties when compared to particleboards bonded with PF-com. The work has indicated that phenolated-lignin formaldehyde resins (up to 30% substitution level) can be used successfully as a wood adhesive for constructing particleboard. The performance of these panels is comparable to those of boards made using PF-com resin. 相似文献
Highly densified W2B5/C composites with W2B5 content from 30 to 70 vol% were fabricated by reaction hot pressing of the powder mixture of B4C, WC and carbon black. The reaction products were identified by XRD analysis to consist of only W2B5 and carbon, regardless of carbon content. The reaction formed composites have excellent mechanical properties (the maximum flexural strength and fracture toughness of 786 MPa and 8.9 MPa m1/2 respectively), electrical conductivity (the highest electrical conductivity of 1.64 × 106 Ω−1 m−1), and resistance to both wear and oxidation because of the presence of the plate-like W2B5 grains. In this paper, the preparation, microstructure and properties of this new composite are investigated, and the strengthening, toughening, conduction mechanisms are discussed. 相似文献