Synthesis of AlPO4 Molecular Sieves with AFI and AEL Structures by Dry-Gel Conversion Method and Catalytic Application of Their SAPO Counterparts on Isopropylation of Biphenyl

AlPO₄-5 and AlPO₄-11 were synthesized by dry-gel conversion (DGC) method. Steam-assisted conversion (SAC) and vapor-phase transport (VPT) techniques were applied for this purpose. The synthesis was successful in presence of a certain minimum amount of external bulk water, without which the crystallization failed. Crystallization by VPT method was slower than corresponding SAC and HTS method. SAPO analogs of the samples, SAPO-5 and SAPO-11 were also synthesized by DGC method. Samples made by DGC methods had higher yield than the conventional hydrothermal synthesis (HTS); otherwise the samples showed similar characteristics as that made by HTS. XRD, SEM and N₂-adsorption results showed high crystallinity and purity of the samples made by DGC, and ²⁷Al MAS NMR spectra indicated the tetrahedral framework nature of Al. SAPO-5 and SAPO-11 were tested for their catalytic activity in isopropylation of biphenyl, and in terms of conversion and selectivity, SAPO-5 was found to be suitable for this application.     

The study on the conductivity of styrene-maleic anhydride copolymer electrolytes based on poly(ethylene glycol)400 and LiClO4

Polyelectrolytes, in this study were synthesized from styrene-maleic anhydride (SMA) copolymer, poly(ethylene glycol)400 (PEG400), and lithium perchlorate (LiClO₄). Fourier transform infrared spectroscopy (FTIR), and magic angle spinning (MAS) solid-state NMR were used to monitor the interaction between Li⁺ ions and polymer. The results of FTIR and MAS solid-state NMR indicate the Li⁺ ions are preferentially coordinated to the ether oxygen of PEG. The T_g of the PEG segments in polyelectrolyte increases with LiClO₄ concentration, as determined by differential scanning calorimetry (DSC), indicating that solubility of the Li⁺ ions in the host polymer increases with the PEG content. Impedance spectroscopy (IS) shows that the bulk conductivity of polyelectrolytes and the conductivity behavior obeys the Vogel-Tamman-Fulcher (VTF) equation.     

类人机器人通信子系统的设计与实现

针对类人机器人足球比赛通信环境的高效性和实时性要求,提出了一套无线通信系统设计方案。该通信方案主要解决三个问题:通信平台、通信模块硬件设计和通信协议。其中,通信平台是实现信息交互的物理硬件,通信模块的硬件设计是无线传输模块的控制电路设计,通信协议是类人机器人系统中协作信息内容和格式的约定。本文建立了类人足球机器人通信子系统的通信平台,给出了基于该系统的硬件设计,并为多机器人系统提出了一套可行的对话协议。实验和比赛结果证明了该通信系统的可行性。     

PHA-767491联合IL-24基因对肝癌细胞的杀伤研究

利用最新发现的抗癌新药PHA-767491联合肿瘤基因治疗中最常用的杀伤基因IL-24共同处理肝癌细胞Bel-7404,采用20MOI携带IL-24基因的非复制型病毒Ad-IL-24联合不同浓度的PHA-767491对肝癌细胞Bel-7404进行治疗研究。western blot实验结果表明:PHA-767491对IL-24的表达无明显抑制作用;MTT和Ho-ceast33342染色实验表明二者联合对Bel-7404细胞表现出了较高协同杀伤作用。     

混合H2／H∞控制问题的降阶控制器

考虑混合H2／H∞控制问题的降阶控制器的设计问题．基于线性矩阵不等式（LMI）,分别‘给出了连续和离散情形下混合H2／H∞问题的降阶控制器的设计．     

湿度对CR-39固体核径迹探测器测量^220Rn／^222Rn水平的影响研究

在可调控温度、湿度及氡浓度的南华大学氡实验室对不同的湿度条件下CR-39固体核径迹探测器测量^220Rn、^222Rn的探测效率进行了测定,分析了湿度对CR-39固体核径迹探测器测量^220Rn、^222Rn探测效率的影响．实验结果表明：相对湿度在35％-95％范围内,当湿度为50％左右时,CR-39固体核径迹探测器测^222Rn,探测效率最高,标准偏差为2．0％;相对湿度在30％-100％范围内,当湿度为75％时,CR-39固体核径迹探测器测^220Rn的探测效率最低,标准偏差达到78．4％．     

人白细胞介素-24基因的克隆、表达和纯化

目的对人白细胞介素-24(hIL-24)进行克隆、表达和纯化。方法分离人外周血单个核细胞,ConA刺激培养,提取细胞总RNA,应用RT-PCR技术从外周血单个核细胞中扩增hIL-24成熟肽编码区,定向克隆至融合表达载体pGEX-4T-1,重组载体pGEX-4T-1/hIL-24经DNA测序鉴定后,转化E.coliBL21(DE3),IPTG诱导表达,阴离子交换层析纯化融合蛋白,SDS-PAGE和Westernblot鉴定。结果所得hIL-24基因经序列分析,与GenBank公布一致。所构建融合表达载体pGEX-4T-1/hIL-24测序正确,转化BL21(DE3)后,37℃诱导表达相对分子质量约为44000的融合蛋白,主要以包涵体形式存在,占菌体总蛋白的30.63%。经纯化后,纯度达85%以上。Westernblot检测能与兔抗人IL-24的多克隆抗血清发生结合反应。结论已成功构建了hIL-24的融合表达载体pGEX-4T-1/hIL-24,并在大肠杆菌中高效表达,纯化后获得了高纯度的融合蛋白,为hIL-24的功能及活性研究奠定基础。     

基于无线传感网络技术在高压开关柜测温中的应用研究

无线传感网络是目前国内外研究的热点课题,并且在结构健康监测中具有广阔应用前景。为了简化传感器铺设的及布线的繁琐,采用Nordic2.4G无线通信技术,高压开关柜中高压侧采用多点组网的方式,即高压侧多路测温系统,对应低压侧一路接收系统。本文方案利用无线收发nRF24L01芯片设计传感节点电路,介绍了系统硬件组成与工作原理,较好实现了温度的实时远程监测。     

二十四节气与现代文明传承的现实意义研究

二十四节气作为我国传统农耕文明重要的科学总结,对现代农业、生活同样有着借鉴意义。同时,二十四节气中包含了众多中国所固有的传统文化,人们在对其传承和发扬的过程中,应体现出二十四节气中诗词、曲赋、农业、中医等内容的传承。而为了将传统文明与现代社会相结合,以促进其进一步发展,人们就需要保护和创新历史文明的艺术,以实际行动将其发扬光大。本文就以二十四节气为研究对象,简要阐述了传统文明与现代文明传承的现实意义。     

某城区排涝泵站设计流量计算方法初探

采用平均排除法、最大24 h雨型洪水流量时程分配法和产流汇流法3种方法分别计算了某城区电排站的设计流量,并将3种方法的计算结果进行对比分析,选用合适电排站的设计流量,可为类似工程设计流量的确定提供参考。