Austenite stability in Fe–Mn–Si-based shape memory alloys

The stability of austenite in a number of Fe–Mn–Si-based shape memory alloys has been investigated. It was found that a grain boundary precipitate of BCC structure is formed over a wide range of alloy compositions and heat treatment temperatures. This grain boundary phase has been identified as the chi (χ) phase. Although up to 3 vol.% of the grain boundary precipitate was generated by isothermal aging in the range 500–800 °C, it was found not to markedly affect the mechanical properties or the shape memory effect. Nano-indentation indicated that the hardness and strength of the parent and precipitate phase are very similar, as are their compositions.     

Analysis of the thermal expansion characteristics of Ni53.6Mn27.1Ga19.3 alloy

Dilatation characteristics of Ni_53.6Mn_27.1Ga_19.3 alloy were measured in the temperature range of 20–360 °C. The coefficient of thermal expansion (CTE) decreased with increasing temperature in the temperature range of the existence of martensite. Three variants of martensite transformed gradually into austenite. Analysis of the dilatation characteristics showed that compression deformation of the alloy at room temperature produces two kinds of strain.     

平面超冗余机器人形状控制的几何样条方法

本文提出了平面超自由度机器人形状控制的样条曲线方法。此方法无需求解复杂非线性优化问题和雅可比伪逆。机器人宏观构形与参考样条曲线之间的匹配非常简单，算法适用于实时控制。     

Analyses of (AD)-sorption for the estimation of pore-network dimensions and structure

The interpretation of pore dimensions based on physical ad-desorption analyses is central to the characterization of pore network structure. Several approaches have been proposed and are commonly employed in the analysis of physical adsorption and/or desorption to deduce the dimensions of the porous network. These approaches assume either theoretical (e.g., BET, the Halsey equation as interpreted by Pierce et al., or the more recent analyses of microporosity) or standard isotherms as model(s) for the sequential calculations required in estimating the pore network dimensions. Subsequent representation of the pore dimensions and the relationship between these distributions in dimension and other experimental parameters (such as catalytic activity, adsorptivity or transport); thus, depend explicitly on the model employed in the analyses. Each instrument currently available for the measurement of porous solid structure by sorption employs the same specific models for the relationship between the volume ad-desorbed and the dimensions of the porous network that is being characterized.This paper analyzes the interpretation of porous dimensions based on the sequential calculations required in the analyses. A new approach is proposed which is based on a modification to current practices reflecting Halsey's original theory for the thickness of the adsorbed layer (as a function of P/P ₀). Further, the calculations of the incremental changes in the exposed surface area are discussed as they relate to pore network structure. A method is proposed to infer the differences in pore shape. Sorption data are analyzed by these new approaches, and these analyses will be compared with those approaches currently employed. Analyses based on these modified approaches provide a dramatically more consistent interpretation of the sorption data and the corresponding pore network structures.     

Precision Compensators Using Giant Superelasticity Effect

Elastic compensators for overconstrained precision devices can be separate components or integrated, e.g. as in HSK toolholders. The latter require precision complex surfaces and are expensive, the former require small springs allowing large deformations. The paper describes a recently discovered Giant Superelasticity Effect (GSE), wherein wires or tubes made from a NiTi superelastic material demonstrate 15-20% recoverable deformation when compressed radially. They are mildly nonlinear and exhibit significant damping. An effective method of attaching elastic tubes is developed. Application of GSE to toolholder-spindle interfaces, with significant reduction of runout, increased stiffness and damping is described.     

现有合成氨厂建设8万吨/年硫酸钾及4万吨/年纯碱装置的可行性

本文试图论述现有合成氨厂改变产品结构,采取以生产化肥为主,联产化工产品。通过对钾芒硝法工艺及联碱工艺技术路线的选择,技术经济分析,以期提高化肥厂的经济效益。     

不同金属硫化物从钨酸盐溶液中除钼的效果

针对钨冶炼过程中钨钼分离这一关键问题,研究了利用CuS,CoS,NiS,PbS,FeS,ZnS和HgS等金属硫化物从钨酸盐溶液中除钼的效果.对含钼的Na2WO4或(NH4)2WO4溶液用Na2S或(NH4)2S 进行硫化处理,使其中的MoO2-4转化为MoS2-4,然后加入上述金属硫化物进行除钼.结果表明,CuS,CoS和NiS在Na2WO4或(NH4)2WO4溶液中均具有良好的除钼效果,综合考虑经济、环保等因素,认为CuS是最经济合理的钨钼分离新试剂.考察了试剂用量、反应温度和溶液pH值对除钼效果的影响,并获得了最佳除钼工艺条件,即在CuS试剂用量为理论量的3～4倍、室温下搅拌反应1h的条件下,可使溶液中的Mo从0.6～0.77g/L降至0.007～0.02g/L,除钼率达96.0%～98.5%,整个除钼过程中钨的回收率达99.75%以上.     

中国传统园林小中见大空间手法解析

小中见大是中国传统园林尤其是江南私家园林的重要特征,如何在有限面积营造无限之空间体验,创造出小中见大的空间效果,一直是传统园林研究的重要课题之一。文章重拾传统,以留园等江南私家园林为主要研究对象,从新的视角解读传统园林中小中见大空间手法,提出概念,并试图总结新手法,以期为中国传统园林的传承和发展提供基础。     

时效对Au－39．8Cu－21．0Zn－3．2Al形状记忆合金的影响

用电阻法研究了不同时效条件对标题合金的马氏体转变温度和形状记忆效应的影响。结果表明：经分级淬火处理的合金，有较高的热稳定性和良好的形状记忆效应。但在高于１２０℃的温度时效一定时间后，将严重影响合金的马氏体相变，从而使合金丧失形状记忆效应。     

Characterization of copper bioreduction and biosorption by a highly copper resistant bacterium isolated from copper-contaminated vineyard soil

Copper is an essential but toxic heavy metal that negatively impacts living systems at high concentration. This study presents factors affecting copper bioremoval (bioreduction and biosorption) by a highly copper resistant monoculture of Pseudomonas sp. NA and copper bioremoval from soil. Seven bacteria resistant to high concentration of Cu(II) were isolated from enrichment cultures of vineyard soils and mining wastes. Culture parameters influencing copper bioreduction and biosorption by one monoculture isolate were studied. The isolate was identified by 16S rRNA gene sequence analysis as a Pseudomonas sp. NA (98% similarity to Pseudomonas putida, Pseudomonas plecoglossicida and other Pseudomonas sp.). The optimal temperature for growth was 30 °C and bioremoval of Cu(II) was maximal at 35 °C. Considerable growth of the isolate was observed between pH 5.0 and 8.0 with the highest growth and biosorption recorded at pH 6.0. Maximal bioreduction was observed at pH 5.0. Cu(II) bioremoval was directly proportional to Cu(II) concentration in media. Pseudomonas sp. NA removed more than 110 mg L^− 1 Cu(II) in water within 24 h through bioreduction and biosorption at initial concentration of 300 mg L^− 1. In cultures amended with 100 mg L^− 1, 20.7 mg L^− 1 of Cu(II) was biologically reduced and more than 23 mg L^− 1 of Cu(II) was biologically removed in 12 h. The isolate strongly promoted copper bioleaching in soil. Results indicate that Pseudomonas sp. NA has good potential as an agent for removing copper from water and soil.