用面向对象编程实现问题求解自动化

本文从面向对象方法基本原理和面向对象编程的技术特征出发，阐明所建应用软件系统中的对象，类及相应类层次结构和类组合结构，使系统具有很强的表现真空世界复杂系统结构的能力，系统通过消息传递在程序执行中实现对操作的调用机制，使之在面向用户问题选择和执行求解策略方面有很强的适应性，这一点对于强调人－机交互和解题协作的智能决策支持系统设计至关重要，文章给出了用Ｃ＋＋实现的模型对象系统及消息传递机制。     

The volume integral method of eddy-current modeling: Verification

The volume integral method of eddy-current modeling represents a flaw in metal as a set of electric dipoles located within volume elements or cells defining the flaw volume. Given this dipole distribution, impedance changes may be computed. The electric field of the dipole distribution is determined by an integral equation relating, by means of the electric field Green's tensor, the electric field due to the source to the total electric field in the flaw. The integral equation is solved by assuming that the total electric field is constant in each volume element, resulting in a matrix equation. The method has been programmed for use on a microcomputer. The method and computer program are verified using the analytical solution for a small spherical flaw and three sets of measured impedance data, measured by air-core coils along profiles overlying both surface-breaking and buried simulated flaws of known dimensions. Operating frequencies ranged between 900 and 4000 Hz. Generally agreement is good at lower frequencies ( 1000 Hz). At higher frequencies ( 4000 Hz), the agreement is not as good. This is thought to be due to the inability of the constant electric field approximation to model the steep electric field gradients present in the host metal at high frequency. The results are also sensitive to the method of computation of the electric field due to the source. Some improvements can and should be made to the method.     

FMS的模型参考自适应调度

用运筹学研究生产线调度问题已有几十年的历史,但由此得出的调度策略的实时性很差.1986年自动控制工作者提出了“PMS动态自适应计算机调”一词.令人感到十分新奇.可惜.从未见到任何有关的论文.本文研究FMS的模型参考自适应调度.本文采用我们提出的考虑了有限缓冲器容量的极大代数模型.环境的影响反映于对象参数的摄动,本文采用我们提出的摄动计算方法.调度器的设计采用次梯度法,以求解连续变量和离散变量混合的优化问题,附有数字实例,计算和仿真表明:FMS的模型参考自适应调度是可行的,是值得继续深入研究的。     

Degree of crosslinking and mechanical properties of crosslinked poly(vinyl alcohol) beads for use in solid-phase organic synthesis

The limited swellability in polar media of the commonly used polystyrene/divinylbenzene (PS-DVB) support materials for solid-phase organic synthesis has led to the development of novel, highly swellable hydrophilic gels designed for use in aqueous or polar media. Poly(vinyl alcohol) beads crosslinked with epichlorohydrin (PVA-EP) were prepared by a two-step inverse-suspension polymerization method. While it is known that the morphology of the resulting beads can be controlled by the ratio of EP versus PVA as well as by the pre-crosslinking time, the actual degree of crosslinking of the beads and their mechanical properties remain unknown. It is therefore the purpose of this study to evaluate the actual degree of crosslinking of beads prepared with different quantities of crosslinker in the feed by spectroscopic (Raman, nuclear magnetic resonance) and chemical (functional group loading) methods. The mechanical properties of these swollen PVA-EP beads will be evaluated by single-bead unconfined compression in solvents such as water, N,N-dimethylformamide (DMF), and tetrahydrofuran (THF) and compared to model PS-DVB beads commonly used for solid phase synthesis.     

Transitions of saturated monoacid triglycerides: Modeling conformational change at glycerol during α→β′→β transformation

The glycerol region geometry of modeled saturated monoacid triglycerides was altered by bond rotations and minor angle distortions to convert theoretical α-forms into bent β′- and β-forms. Direct α to β conversion involves lateral disruption of fatty chain packing to generate side-chain character typical of the β-form. Such disruption, which could contribute to fat bloom, allows additional molecular movement and shifts in molecular mechanics energy (MME) that may approximate thermal changes observed by differential scanning calorimetry during α to β transformations. Energy calculations at 100 points throughout each transformation identified plausible conversion routes. A two-stage conversion, α to either of two stereospecific β′-forms bent at glycerol followed by subsequent conversion to β, showed less chain movement and more favorable MME than direct α to β conversion. The preferred path, based on energy profiles of each conversion, involves a β′-D form and rotation of carbonyl to α-carbon bonds in chain #2 and a side chain (chain #3).     

Transformation of β-Ni(OH)2 to NiO nano-sheets via surface nanocrystalline zirconia coating: Shape and size retention

Shape and size of the synthesized NiO nano-sheets were retained during transformation of sheet-like β-Ni(OH)₂ to NiO at elevated temperatures via nano-sized zirconia coating on the surface of β-Ni(OH)₂. The average grain size was 6.42 nm after 600 °C treatment and slightly increased to 10 nm after 1000 °C treatment, showing effective sintering retardation between NiO nano-sheets. The excellent thermal stability revealed potential application at elevated temperatures, especially for high temperature catalysts and solid-state electrochemical devices.     

High resolution solid state 13C n.m.r. of butadiene grafted polypropylene

¹H dipolar decoupled ¹³C n.m.r. experiments with the aid of the magic angle spinning technique have been used to determine the graft content and the isomer content of the polybutadiene grafts in a graft copolymer with isotactic polypropylene.     

Human interaction with policy flight simulators

Policy flight simulators are designed for the purpose of exploring alternative management policies at levels ranging from individual organizations to national strategy. This article focuses on how such simulators are developed and on the nature of how people interact with these simulators. These interactions almost always involve groups of people rather than individuals, often with different stakeholders in conflict about priorities and courses of action. The ways in which these interactions are framed and conducted are discussed, as well as the nature of typical results.     

Predicting N mineralized in a Georgia Coastal Plain field

The N mineralized from soil organic matter provides an important portion of N available for crop production. The objective of this study was to determine the amount of spatial variability in N mineralization potential in a field and to evaluate three different methods that might be used to estimate this variability. The three methods tested included predicting the N mineralized from surface soil properties as well as from a biological and a chemical procedure. Three soils varying in N mineralization potential were selected for the study from a field in the Georgia Coastal Plain. The N mineralized from these soils was determined by an N balance of unfertilized and cropped plots. The amount of N mineralized could not be reliably predicted from surface soil organic C, although surface soil clay concentration was positively correlated with the N mineralized. The N mineralized that was predicted using mineralization parameters determined by aerobic incubation, adjusted daily for soil water content and temperature, was approximately 50% of the field measurements of N mineralized. The values of NH₄-N extracted with hot 2 M KCl were related significantly to N mineralized in the field (r²= 0.60) and also to the zero order rate constant of mineralization, k₀ (r²= 0.77), determined from the N mineralized in the aerobic laboratory incubation.     

Assessing the predictive capability of two‐phase models for the mechanical behavior of alumina/epoxy nanocomposites

A review of analytical modeling of particulate reinforcement is made as a prelude to the problem of microstructural inhomogeneity in nanocomposite materials. Noting the inevitability of dispersion nonuniformity, and variations in agglomerate morphology and filler‐matrix interaction, the need to question the application of such models to novel materials arises. Employing the mechanical properties of alumina/epoxy nanocomposites, with known dispersion characteristics, an evaluation of the predictive capability of various models for Young's modulus, strength, and failure strain is made. Comparison between models is accompanied by a discussion of the parameters used in the fitting of macroscopic behavior to microstructural features. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 869–879, 2005