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101.
102.
M.A.R. Alves 《Microelectronics Journal》2005,36(1):51-54
We developed a process to obtain sharper silicon tips by employing anisotropic etching in a KOH solution followed by SF6 plasma etch. The tips were further sharpened using the established thermal oxidation technique to decrease the cone angle and, therefore, obtain smaller curvature radii. We have analyzed the impact of such changes in geometry on a figure of merit associated with the field emission characteristics. An increase in the figure of merit by a factor of three was found in relation to the tips before sharpening. 相似文献
103.
本文在理论和试验两个方面探讨了离子注入中的热效应和温升现象。注入样品的温升对离子注入层的性能有直接影响。分析了理论计算注入样品温升的一些情况。给出了实际测量注入样品温升的几种试验方法。阐明了控制注入样品温升的若干可能途径。 相似文献
104.
105.
Stanislav I. StoliarovPhillip R. Westmoreland Marc R. Nyden Glenn P. Forney 《Polymer》2003,44(3):883-894
The theory and implementation of reactive molecular dynamics (RMD) are presented. The capabilities of RMD and its potential use as a tool for investigating the mechanisms of thermal transformations in materials are demonstrated by presenting results from simulations of the thermal degradation of poly(methyl methacrylate) (PMMA). While it is known that depolymerization must be the major decomposition channel for PMMA, there are unanswered questions about the nature of the initiation reaction and the relative reactivities of the tertiary and primary radicals formed in the degradation process. The results of our RMD simulations, performed directly in the condensed phase, are consistent with available experimental information. They also provide new insights into the mechanism of the thermally induced conversion of this polymer into its constituent monomers. 相似文献
106.
Alumina coatings have been deposited by combustion flame pyrolysis on amorphous silica and stainless steel substrates with the objective to study the effect of solvent composition, Fe3+ addition and determine the thermal fatigue lifetime. The effect of solvent composition on crystallinity, transformation temperature and hardness are studied, three different solvent compositions are chosen for preparing the aluminium nitrate solution. Using 100% water, as-deposited films are amorphous and transform to α-alumina only upon annealing, while this equilibrium phase is directly obtained but with a porous microstructure by using 100% methanol. The hardness of the coatings varies with the flammability of the solvents. The effect of Fe3+ addition on the crystallization of alumina is studied by combustion pyrolysis of aqueous solutions of Al3+ and Fe3+ nitrates. Small amount of ferric nitrate reduced the transformation temperature by 100 °C. Thermal cycling of as-deposited amorphous alumina on stainless steel substrate is carried out at different temperatures to determine the thermal fatigue lifetime. 相似文献
107.
Hydrogen is considered to be the most important future energy carrier in many applications reducing significantly greenhouse gas emissions, but the safety issues associated with hydrogen applications need to be investigated and fully understood to be applicable as the carrier. Generally, the locations of hydrogen production and consumption are different. Hydrogen must be transported from the point of production to the point of use. Pipeline delivery is cheaper than all other methods for large quantities of hydrogen. The rupture of a hydrogen pipeline can lead to outcomes that can pose a significant threat to people and property in the immediate vicinity of the failure point. In this work, a simplified equation of hazard analysis is proposed for the pipeline transporting hydrogen, which relates the diameter, the operating pressure and the length of the pipeline to the size of the affected area in the event of a failure of the pipeline. The dominant hazards are thermal radiation from sustained fire and shock pressure from gas cloud explosion. For a transmission pipeline of hydrogen gas, the hazard area from the fire is slightly larger than by the other event. The hazard area is directly proportional to the operating pressure raised to the power one-half, and to the pipeline diameter. This simplified equation to estimate the hazard area will be a useful tool for safety management of hydrogen gas transmission pipelines. 相似文献
108.
T. Brard F. H. Cornet 《International Journal of Rock Mechanics and Mining Sciences》2003,40(7-8):1121-1140
When they occur, borehole breakouts are considered strong markers of principal stress directions at depth. An innovative processing method for automatically identifying breakouts from ultrasonic borehole wall images has been developed. It has been applied to data sets from two deep, sub-vertical wells (GPK1 and GPK2) at the Soultz geothermal site in eastern France. In well GPK1, below 3 km depth, compression breakouts, with a 95°±7° azimuth, increasingly occur with depth. They result from time dependent compression failure at sub-critical stress levels and are indicators of the minimum horizontal principal stress orientation. However, in the uppermost logged section of well GPK2 (1.6–2.9 km depth), continuous borehole elongations share roughly the same azimuth with so called drilling-induced fractures (164°±18° and 175°±17° azimuth, respectively). Both features concomitantly vanish with depth, together with the amplitude of the thermal perturbation induced by drilling. It is proposed that these latter borehole elongations result from a pervasive, cooling-induced, tensile micro-cracking process prior to macroscopic failure localization. They are termed thermal elongations and are indicators of the maximum horizontal principal stress orientation. Had a simple logging caliper tool been used for this work, these thermal elongations might have been confused with classical compression breakouts. A simple criterion for differentiating compression breakouts from thermal elongation is proposed. 相似文献
109.
110.
Hot electrons emitted from thin oxide film-coated heavily doped silicon electrodes by cathodic pulse polarization can induce electrochemiluminescence from luminophores. The intensity of electrochemiluminescence produced at the electrode surface is dependent on the features of thin oxide films formed by thermal oxidation. As a preliminary study, we investigated the effect of thermal oxide growth conditions on the intensity of electrochemiluminescence produced at these electrodes, such as oxidation atmospheres, oxidation temperature, oxidation time and pre-treatment of wafers, using ruthenium(II) tris-(2,2′-bipyridine) chelate as a model luminophore. Optimal oxidation conditions of heavily doped silicon electrodes were obtained for the generation of intense electrochemiluminescence at this kind of silicon electrodes. 相似文献