X 射线法对刨片机刀片工作温度的测定

本文论述了用 X 射线衍射法间接测定双■轮刨片机 GCr15钢制刀片的工作温度.用该钢种制成并经不同热处理的八个标样和服役后的刀片,进行衍射线形的测量和半高宽值的测算.通过微机进行的回归分析,得出半高宽值与温度的关系曲线的相关系数为0.995,刀片工作温度为271±10℃.理论分析和实验数据表明:这一间接测定刀片工作温度的方法、简便易行,有一定的准确、可靠性.对某些不能用常规方法测定工作温度的金属零件具有特殊的意义.     

电解锰粉的物理测试

用X射线衍射(XRD)法研究了电解锰粉中MnO_2的晶型。对确定为γ—MnO_2的锰粉做了化学成份、差热曲线、比表面积和比重测定,探讨了γ—MnO_2的鉴定问题。     

光栅衍射谱线产生缺级的条件

本文对光栅衍射谱线产生缺级的条件进行了讨论，澄清了某些教科书中不确切的叙述。     

Acoustic scattering at a gap between two orthogonal,semi-infinite barriers: coordinate and spectral equations

The 2-D problem of diffraction by a gap between two orthogonal semi-infinite barriers is considered. The method of reflections is applied and the diffraction problem is reformulated as a propagation problem on a multi-sheet surface. An auxiliary problem, with a single incident wave, is formulated. By applying an embedding formula the auxiliary problem is reduced to that of finding a set of edge Green’s functions for the surface. The edge Green’s functions are proven to satisfy two sets of differential equations: the coordinate equations and the spectral equation. Although too complicated to be solved analytically, these ordinary differential equations offer some advantages over partial differential equations or integral equations.     

基于ATmega128的球管电压控制系统设计与实现

本设计利用ATMEL公司AVR系列ATmega128单片机的控制调频电路来调制系统的工作频率,实现对口腔CBCT系统X射线球管电压的精确控制和调节,同时还实现了系统的人机交互、数据存储和传输、数/模转换、串口通信等功能。该控制电路硬件设计简单可靠,易于实现;软件开发方便灵活,实现了预期的功能。     

Solid state phase equilibria in the Fe–Ga–Sb ternary system at 600 °C

Solid state phase equilibria in the ternary Fe–Ga–Sb diagram were determined at 600 °C using experimental techniques such as X-ray diffraction, electron probe microanalysis and scanning electron microscopy. Very limited solid solutions were measured in the binary constituent Fe–Ga and Fe–Sb compounds except for the -phase (Fe_≈2.55Sb₂) which extends from 42 to 48 at.% Sb. In the Fe-rich part of the diagram, a ternary phase Fe_tGa_2−xSb_x (2.15≤t≤2.80) was evidenced which corresponds in fact to a solid solution into which Ga and Sb substitute one another on the same hexagonal sublattice. This phase, which can be truly considered as a pseudo-binary one since its origin results from the -phase, shows an extended homogeneity range with a Ga-rich limit corresponding to the formula Fe_tGa_0.8Sb_1.2. Moreover, it crystallizes in hexagonal symmetry with a disordered structure derivative from the NiAs-type (B8₁). This pseudo-binary phase is in thermodynamic equilibrium with all the binaries of the system except FeGa₃. The main result of the ternary Fe–Ga–Sb diagram remains the existence of a diphasic region between the Fe_tGa_2−xSb_x phase (1.2≤x≤1.6; 2.15≤t≤2.80) and the semiconductor GaSb. Nevertheless, at 600 °C, this pseudo-binary phase does not extend up to the Fe₃GaSb composition which is stoichiometric in Ga and Sb. Finally, a comparative study has been made with the three other ternary systems Fe–Ga–As, Ni–Ga–As and Ni–Ga–Sb previously reported, and the consequences for the solid state interdiffusions in Metal/III–V semiconductor heterostructures are discussed.     

On the synthesis and characterization of a new manganite type CMR material: La0.7Hg0.3MnO3

A new manganite type CMR material, La_0.7Hg_0.3MnO₃ has been successfully synthesized and has been found to exhibit magnetoresistance (≈9%) at low fields (≈1.5 kG). The synthesis has been carried out through a solid state reaction route consisting of the formation of La_0.7MnO₃ followed by diffusion of Hg leading to La_0.7Hg_0.3MnO₃. The as grown samples are polycrystalline and correspond to an orthorhombic unit cell with the lattice parameters; a=5.5183 Å, b=5.6383 Å and c=7.5368 Å. The typical grain size as revealed by scanning electron microscopy is in the range of 0.5–2 μm. The ρ–T behaviour shows a peak at T_IM=227 K. The ρ–T behaviour above this temperature corresponds to that of an insulator and below this to that of a metal. The ρ–T behaviour remains unaltered when a magnetic field (H_dc=1.5 kG) is applied. However, with this magnetic field a drop in the resistivity is observed up to 77 K. At room temperature the magnetoresistance ratio (MRR) is too small but it steadily increases as the temperature is decreased. Thus, MRRs at 227.13 and 77 K are 3.41 and 9.05%, respectively, in an applied field of H_dc=1.5 kG. At a given temperature the variation in MRR with field H_dc is rapid at lower field values (H_dc<1.2 kG) and scales linearly for higher field values (H_dc>1.2 kG). It may be mentioned that the present work on the synthesis and magnetoresistance behaviour of La_0.7Hg_0.3MnO₃, is the first of its type.     

Thermal behavior and structural study of ZrO2/poly(ε-caprolactone) hybrids synthesized via sol-gel route

The thermal behavior of pure ZrO₂ and four ZrO₂-based organic-inorganic hybrids (OIHs) containing increasing amount (6, 12, 24 and 50?wt%) of poly(ε-caprolactone) (PCL) (named Z, ZP6, ZP12, ZP24 and ZP50 respectively) has been studied by simultaneous thermogravimetry (TG) and differential scanning calorimetry (DSC). The FTIR analysis of the gas mixture evolved at defined temperatures from the samples submitted to the TG experiments identified the mechanism of each thermally activated process. The obtained results suggest that the inorganic matrix of the OIHs prepared by this method exerts a stabilizing effect on the polymer, in particular for poor-PCL hybrid materials. In fact, the different thermal behavior of the ZP50 sample suggests that the polymer is not entirely bonded to the -OH groups of the zirconia matrix due to their saturation. For this reason a part of PCL is not affected by the stabilizing effect of the matrix and is subjected to thermal degradation. Finally, by observing their thermal behavior it was possible to select the most suitable temperatures for thermal pretreatment: 400, 600 and 1000?°C. The structural analysis by X-ray diffraction (XRD) revealed that at 400?°C the materials are amorphous, while at 600?°C they are mostly tetragonal, and the content of the tetragonal phase decreases with increasing the amount of PCL in the OIHs. All the materials treated at 1000?°C are monoclinic, but their crystallinity decreases with increasing the PCL content.     

Strontium and zinc co-substituted nanophase hydroxyapatite

It is well documented that biological hydroxyapatite (HA) differs from pure and synthetically produced HA, and contains of a mixture of calcium phosphate (CaP) phases in addition to a range of impurity ions, such as strontium (Sr²⁺), zinc (Zn²⁺), magnesium (Mg²⁺), fluoride (F^-) and carbonate(CO₃^2-), but to name a few. Further to this, biological apatite is generally in the form of rod (or needle-like) crystals in the nanometre (nm) size range, typically 60 nm in length by 5–20 nm wide. In this study, a range of nano-hydroxyapatite (nHA), substituted nHA materials and co-substituted nHA (based on Sr²⁺ and Zn²⁺) were manufactured using an aqueous precipitation method. Sr²⁺ and Zn²⁺ were chosen due to the significant performance enhancements that these substitutions can deliver. The materials were then characterised using Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), X-Ray Photoelectron Spectroscopy (XPS) and Transmission Electron Microscopy (TEM) techniques. The TEM results show that all of the samples produced were nano-sized, with Zn-substituted nHA being the smallest crystals around 27 nm long and 8 nm wide. The FTIR, XRD and XPS results all confirm that the materials had undergone substitution with either Sr²⁺ and Zn²⁺, for Ca²⁺ within the HA lattice (or both in the case of the co-substituted materials). The FTIR results confirmed that all of the samples were carbonated, with a significant loss of hydroxylation as a consequence of the incorporation of Sr²⁺ and Zn²⁺ into the HA lattice. None of the materials synthesised here in this study contained any other impurity CaP phases. Therefore this study has shown that substituted and co-substituted nanoscale apatites can be prepared, and that the degree of substitution (and the substituting ion) can have a profound effect of the attendant materials’ properties.