调整工艺条件降低脲醛胶生产的操作成本

根据生成脲醛树脂的反应机理和反应特性,对生产周期的控制步骤——缩聚阶段的工艺条件进行调整,采用在不同反应阶段调整不同工艺条件的方法,使整个反应周期由原来的6．0h缩短到5．0h,从而提高设备利用率、降低生产的操作成本,同时因充分利用反应自身放出的热量,可降低生产能耗。     

有机硅改性丙烯酸酯核-壳结构压敏胶聚合物乳液的研制

采用种子乳液聚合的方法制备了一种新型具有核/壳结构的有机硅改性丙烯酸酯压敏胶聚合物乳液,讨论了多官能团有机硅氧烷功能性单体、核壳单体结构、乳化剂、引发剂以及聚合温度等因素对压敏胶聚合物乳液性能的影响。     

Torque Transmission Capabilities of Bonded Polygonal Lap Joints for Carbon Fiber Epoxy Composites

Although carbon fiber epoxy composite materials have excellent properties for structures, the joint in composite materials often reduces the efficiency of the composite structure because the joint is often the weakest area in the composite structure.

In this paper, the effects of the adhesive thickness and the adherend surface roughness on the static and fatigue strengths of adhesively-bonded tubular polygonal lap joints have been investigated by experimental methods. The dependencies of the static and fatigue strengths on the stacking sequences of the composite adherends were observed.

From the experimental investigations, it was found that the fatigue strength of the circular adhesively-bounded joints was quite dependent on the surface roughness of the adherends and that polygonal adhesively-bonded joints had better fatigue strength characteristics than circular adhesively-bonded joints.     

双组分环氧胶粘剂在我厂的应用

简单介绍了双组分环氧胶粘剂的特点、组成及固化反应机理 ,并且详细叙述了我厂双组分环氧胶粘剂的组分、配制工艺和灌胶工艺以及讨论了双组分环氧胶粘剂在我厂的应用情况 ,为我厂的军品及民用电器产品的灌封胶接提供了广泛的前景     

Application of enzymatically gelled chitosan solutions to water‐resistant adhesives

An investigation was undertaken on the application of dilute chitosan solutions gelled by tyrosinase‐catalyzed reaction with 3,4‐dihydroxyphenethylamine (dopamine). The tyrosinase‐catalyzed reaction with dopamine conferred water‐resistant adhesive properties to the semidilute chitosan solutions. The viscosity of the chitosan solutions increased highly by the tyrosinase‐catalyzed reaction and the subsequent reactions between o‐quinone compounds and chitosan. These highly viscous, gel‐like modified chitosan materials were allowed to spread onto the surfaces of the glass slides, which were tightly lapped together and held them in water. Tensile shear adhesive strength of over 400 kPa was observed for the modified chitosan samples. The increase in the amino group concentration of the chitosan solutions and the molecular mass of the chitosan used effectively led to the increase in adhesive strength of the glass slides. In addition, in the case where the chitosan solution was gelled by the enzymatic reaction with dopamine in the presence of poly(ethylene glycol), adhesive strength sharply increased at shorter reaction times concomitantly with the increase in the viscosity of the chitosan solutions because the tyrosinase activity effectively was retained by poly(ethylene glycol). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1818–1827, 2007     

Binder effect on cycling performance of silicon/carbon composite anodes for lithium ion batteries

The cycling performance of a silicon/carbon composite anode has been significantly enhanced by using acrylic adhesive and modified acrylic adhesive as binder to fabricate the electrodes for lithium ion batteries. The capacity retentions of Si/C composite electrodes bound by acrylic adhesive and modified acrylic adhesive are 79% and 90% after 50 cycles, respectively. These two binders are electrochemically stable in the organic electrolyte in the working window. They also show larger adhesion strength between the coating and the Cu current collector as well as smaller solvent absorption in the electrolyte solvent than polyvinylidene fluoride (PVDF). Furthermore, sodium carboxyl methyl cellulose (CMC) plays an important role on improving the properties of acrylic adhesive, which increases the adhesive strength of acrylic adhesive and improves the activation of the electrodes.     

聚丙烯酸酯压敏胶带制备及其性能研究

本文研究广丙烯酸酯单体的共聚合反应以及交联型压敏胶带的制备过程，从而确定了最佳工艺条件，并测定了压敏胶带的老化，贮存期，可剥离等性能。     

氧化玉米淀粉粘合剂稳定性的探究

探讨了氧化玉米淀粉粘合剂的稳定性的主要影响因素,初步分析其变质机理,以此为依据制备得到高稳定性的产品。     

室温硫化有机硅粘合剂的应用与研究进展

分析了单组份、双组份及三组份室温硫化有机硅粘合剂的性能,介绍了室温硫化有机硅粘合剂在航空工业的应用及进展。     

导静电乳液胶粘剂的研制

用多元乳液共聚法制备了用于粘贴导静电PVC地板胶粘剂,加入乙炔碳黑赋予乳液胶粘剂导静电性能。研究了影响胶接强度和初粘力的主要因素,确定m(VAc)/m(BA+VAc)较合适比为1∶3;研究了乳化剂和交联单体对乳液性能的影响,研究得出,适量加入AA和HMAM可以减少乳化剂的用量,提高乳液的性能;考查了影响导静电性能的因素,研究表明,导静电性能由乙炔碳黑决定,其加入量越大,导静电性能越好。得到的导静电乳液胶粘剂胶接强度达到0.51MPa以上,导静电可达到7.2×103Ω,两项指标均超过国家标准。