催化裂化干气回收乙烯用于制备环氧乙烷的研究

叙述了在YS型银催化剂作用下，利用催化裂化干气回收的乙烯制备环氧乙烷的实验研究。结果表明：在银催化剂上催化氧化生成环氧乙烷的过程中，使用回收的乙烯，催化剂的初选择性可达80％；在保持环氧乙烷时空产率不变，经过2000h催化剂稳定性试验后，选择性下降了3—4个百分点，反应温度上升约10℃，与用聚合级乙烯为原料进行比较，催化剂初选择性低2—3个百分点、稳定性略差。该结果为用回收乙烯生产环氧乙烷提供了试验依据。     

中国冷库的现状与发展趋势

本文从的设计建造、制冷工艺和管理维护这三个方面，介绍了近三年来中国冷库的现状，说明中国冷库正朝着灵活、自动化、节能和环保的方向进一步发展。     

Pyrolysis of tertiarybutylphosphine at low pressure

The pyrolysis of tertiarybutylphosphine (TBP) has been studied in the low pressure conditions used for chemical beam epitaxy (CBE). The pyrolysis studies were carried out in low pressure reactors of two different configurations, one of which is a cracker cell designed for use in a CBE system. The reaction products were studied using a quadrupole mass spectrometer. The products observed are accounted for by a reaction mechanism involving homolysis of the parent TBP molecule to produce PH₂ and C₄H₉ radicals. These undergo subsequent reactions to form the stable products C₄H₈, PH₃ and H₂, with smaller amounts of P and P₂ being produced. The production of the sub-hydride PH₂ using this cracker cell design indicates that the use of partially cracked TBP may be a promising technique for reducing the amount of carbon incorporated into the growing epitaxial layer.     

沈阳太平洋广场空调冷热源方案比较

对一幢１１．５万ｍ＾２的四星级综合建筑的空调冷热源不同的蓄冷和取冷比较了四种方案，论证了其中直燃型溴化锂吸收式冷热水机组供冷供暖、小型燃油锅炉供蒸汽的方案最为合理。     

用发展的Sachs法研究模拟轧辊中的残余应力

对不同辊型，尺寸，材料与加工处理方法的模拟冷轧辊进行了内剥层试验研究，求出了原辊和打中心孔或扩孔后辊内残余应力分布曲线，提出了虚拟打孔法和虚拟剥层法，解决了实心辊中心和空心辊内表层的残余应力的精确测量问题，丰富了Ｓａｃｈｓ内剥层法的内容，机械法打中心孔，热处理前打中心孔，空心辊表淬前改变温度场的方法可降低残余应力值，后者降低残余应力的效果尤为显著。     

An investigation of pore cracking in titanium welds

Two welded Ti-6A1-4V pressure vessels leaked prematurely in service. The leaks were caused by cracks emanating from weld porosity. The cracks originated during fabrication, with subsequent growth in service leading to the formation of the leak paths. Pore cracking is thought to be caused by a mechanism that involves both sustained-load and cyclic contributions, with the former being the more prominent. It is shown that the tendency for cracking is influenced by pore position and that pore size is not a deciding factor in that regard. The factors that govern pore cracking are discussed, and the possible role of interstitial embrittlement is assessed.     

The chloride stress-corrosion cracking behavior of stainless steels under different test methods

Chloride-induced stress-corrosion cracking (SCC) is one of the failure modes of stainless steels. Highly alloyed austenitic stainless steels S32654, S31254, and N08028, and duplex grades S32750 and S31803 possess much improved resistance to SCC compared with S30400 and S31600 steels. With the development of a database, SSData, experimental data collected from calcium chloride tests, autoclave tests, and drop evaporation tests were evaluated. Stress-corrosion cracking data generated by autoclave tests agreed well with the practical service conditions and can be used to discriminate alloys for SCC resistance in sodium chloride solution. Drop evaporation test data can be used in situations where evaporation may occur and cyclic loading may be involved. The SCC resistance of alloys under each method increased with increasing molybdenum equivalent Mo + 0.25Cr + 0.1Ni. For a given alloy, the testing result depends on the stress state and environment; different test methods can give different ranking orders concerning SCC resistance. The performance of duplex stainless steels in a chloride-containing environment at higher temperatures was not as good as expected when dynamic loading was involved.     

采用先进技术提高装置运行水平

介绍了中国石油化工股份有限公司高桥分公司 1.4Mt/a同轴式重油催化裂化装置的特点和生产情况。为了满足市场需求 ,提高经济效益 ,几年来在该装置上又采用了一些新技术 ,使装置的运转水平进一步提高。如应用降烯烃催化剂GOR Q ,与使用MLC 5 0 0催化剂相比 ,汽油烯烃体积含量约 30 % ,下降 8～ 10个百分点 ;汽油辛烷值基本不变 ;产品分布改善 ;液体收率增加 ;柴油性质变化不大。又如最大量烷烃异构化 (MIP)新型提升管反应系统的应用 ,与常规催化裂化相比 ,产品分布相当 ,汽油的烯烃体积含量下降至 30 %～ 35 % ,MON增加 0 .5～ 0 .8个单位 ,RON下降幅度不大于 0 .5个单位     

催化裂化装置中旋流快分系统（VQS）的结构设计

阐述了全渣油催化裂化装置反应器中旋流快分系统(VQS)的工作原理,对其受力情况进行了分析。较详细介绍了放流快分系统的支撑结构形式,并就支撑梁(焊接工字钢)的选材、几何尺寸进行了详细的分析与比较。     

KINETICS OF HYDROCARBON GAS GENERATION FROM MARINE KEROGEN AND OIL: IMPLICATIONS FOR THE ORIGIN OF NATURAL GASES IN THE HETIANHE GASFIELD, TARIM BASIN, NW CHINA

In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C_1‐5) and methane (C₁) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C_1‐5 (Ea = 59‐72kcal, A = 1.0×10¹⁴ s^?1) and C₁ (Ea = 61‐78kcal, A = 6.06×10¹⁴ s^?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×10¹⁴ s^?1 for C_1‐5; and Ea = 48‐72kcal, A=3.9×10¹³ s^?1 for C₁, respectively). Using these kinetic parameters, both the yields and timings of C_1‐5 and C₁ hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression.