全文获取类型
收费全文 | 90663篇 |
免费 | 5937篇 |
国内免费 | 2983篇 |
专业分类
电工技术 | 4418篇 |
技术理论 | 14篇 |
综合类 | 8854篇 |
化学工业 | 10014篇 |
金属工艺 | 6968篇 |
机械仪表 | 2174篇 |
建筑科学 | 36600篇 |
矿业工程 | 3090篇 |
能源动力 | 1858篇 |
轻工业 | 2771篇 |
水利工程 | 5771篇 |
石油天然气 | 2064篇 |
武器工业 | 329篇 |
无线电 | 3100篇 |
一般工业技术 | 5436篇 |
冶金工业 | 2932篇 |
原子能技术 | 327篇 |
自动化技术 | 2863篇 |
出版年
2024年 | 255篇 |
2023年 | 941篇 |
2022年 | 2009篇 |
2021年 | 2458篇 |
2020年 | 2176篇 |
2019年 | 1563篇 |
2018年 | 1525篇 |
2017年 | 2061篇 |
2016年 | 2358篇 |
2015年 | 2677篇 |
2014年 | 8355篇 |
2013年 | 5064篇 |
2012年 | 6849篇 |
2011年 | 7470篇 |
2010年 | 6208篇 |
2009年 | 6777篇 |
2008年 | 5837篇 |
2007年 | 6452篇 |
2006年 | 5338篇 |
2005年 | 4162篇 |
2004年 | 3593篇 |
2003年 | 3172篇 |
2002年 | 2533篇 |
2001年 | 1977篇 |
2000年 | 1660篇 |
1999年 | 1288篇 |
1998年 | 935篇 |
1997年 | 793篇 |
1996年 | 620篇 |
1995年 | 577篇 |
1994年 | 454篇 |
1993年 | 316篇 |
1992年 | 256篇 |
1991年 | 185篇 |
1990年 | 143篇 |
1989年 | 133篇 |
1988年 | 75篇 |
1987年 | 61篇 |
1986年 | 48篇 |
1985年 | 35篇 |
1984年 | 39篇 |
1983年 | 29篇 |
1982年 | 25篇 |
1981年 | 7篇 |
1980年 | 19篇 |
1979年 | 9篇 |
1965年 | 5篇 |
1960年 | 6篇 |
1959年 | 6篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Jennie O'Loughlin Silvia Napolitano Fahad Alkhathami Cillian O'Beirne Daniel Marhöfer Megan O'Shaughnessy Prof. Orla Howe Prof. Matthias Tacke Dr. Marina Rubini 《Chembiochem : a European journal of chemical biology》2021,22(6):1093-1098
Antibiotic resistance is a growing problem for public health and associated with increasing economic costs and mortality rates. Silver and silver-related compounds have been used for centuries due to their antimicrobial properties. In this work, we show that 1,3-dibenzyl-4,5-diphenyl-imidazol-2-ylidene silver(I) acetate/NHC*-Ag-OAc (SBC3) is a reversible, high affinity inhibitor of E. coli thioredoxin reductase (TrxR; Ki=10.8±1.2 nM). Minimal inhibition concentration (MIC) tests with different E. coli and P. aeruginosa strains demonstrated that SBC3 can efficiently inhibit bacterial cell growth, especially in combination with established antibiotics like gentamicin. Our results show that SBC3 is a promising antibiotic drug candidate targeting bacterial TrxR. 相似文献
22.
Iqbal Ahmad Syed Mujtaba Shah Muhammad Nadeem Zafar Muhammad Naeem Ashiq Wei Tang Uzma Jabeen 《Ceramics International》2021,47(3):3760-3771
Ferrites are materials of interest due to their broad applications in high technological devices and a lot of research has been focused to synthesize new ferrites. In this regard, an effort has been devoted to synthesize spinel Pr–Ni co-substituted strontium ferrites with a nominal formula of Sr1-xPrxFe2-yNiyO4 (0.0 ≤ x ≤ 0.1, 0.0 ≤ y ≤ 1.0). The cubic structure of pure and Pr–Ni co-substituted strontium ferrite samples calcinated at 1073 K for 3 h has been confirmed through X-ray diffraction (XRD). Average sizes of crystallites (18–25 nm) have been estimated from XRD analysis and nanometer particle sizes of synthesized ferrites have been further verified by scanning electron microscopy (SEM). SEM results have also shown that particles are mostly agglomerated and all the samples possess porosity. It has been observed that at 298 K, the values of resistivity (ρ) increase, while that of AC conductivity, dielectric loss, and dielectric constants decrease with increasing amounts of Pr3+ and Ni2+ ions. The values of dielectric parameters initially decrease with frequency and later become constant and can be explained on the basis of dielectric polarization. Electrochemical impedance spectroscopy (EIS) studies show that the charge transport phenomenon in ferrite materials is mainly controlled via grain boundaries. Overall, synthesized ferrite materials own enhanced resistivity values in the range of 1.38 × 109–1.94 × 109 Ω cm and minimum dielectric losses, which makes them suitable candidates for high frequency devices applications. 相似文献
23.
Karina Polak Beata Bergler-Czop Micha Szczepanek Kamila Wojciechowska Aleksandra Frtczak Norbert Kiss 《International journal of molecular sciences》2021,22(9)
Psoriasis is a chronic, immune-mediated inflammatory disease that affects around 125 million people worldwide. Several studies concerning the gut microbiota composition and its role in disease pathogenesis recently demonstrated significant alterations among psoriatic patients. Certain parameters such as Firmicutes/Bacteroidetes ratio or Psoriasis Microbiome Index were developed in order to distinguish between psoriatic and healthy individuals. The “leaky gut syndrome” and bacterial translocation is considered by some authors as a triggering factor for the onset of the disease, as it promotes chronic systemic inflammation. The alterations were also found to resemble those in inflammatory bowel diseases, obesity and certain cardiovascular diseases. Microbiota dysbiosis, depletion in SCFAs production, increased amount of produced TMAO, dysregulation of the pathways affecting the balance between lymphocytes populations seem to be the most significant findings concerning gut physiology in psoriatic patients. The gut microbiota may serve as a potential response-to-treatment biomarker in certain cases of biological treatment. Oral probiotics administration as well as fecal microbial transplantation were most reported in bringing health benefits to psoriatic patients. However, the issue of psoriatic bacterial gut composition, its role and healing potential needs further investigation. Here we reviewed the literature on the current state of the relationship between psoriasis and gut microbiome. 相似文献
24.
25.
针对传统低压回路电阻测试仪只能在被测设备停电时使用的一大限制,本文提出并设计了一种新型低压回路电阻测试仪。该仪器可在低压设备运行状态下对其回路电阻进行测量,在保证测量精度的前提下减少了设备停电率,大大提高了工作效率。 相似文献
26.
Wenshu Chen Jiajun Gu Yongping Du Fang Song Fanxing Bu Jinghan Li Yang Yuan Ruichun Luo Qinglei Liu Di Zhang 《Advanced functional materials》2020,30(25)
Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS2 nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active / heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich / sites, the fabricated 1T–MoS2 QS/Ni(OH)2 hybrid (quantum sized 1T–MoS2 sheets decorated with Ni(OH)2 via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm?2, respectively, and has a low Tafel slope of 30 mV dec?1 in 1 m KOH. So far, this is the best performance for MoS2‐based electrocatalysts and the 1T–MoS2 QS/Ni(OH)2 hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions. 相似文献
27.
《Journal of the European Ceramic Society》2020,40(8):2896-2906
The brittleness of MoSi2 ceramic and the thermal mismatch between MoSi2 coating and C / C composite lead to brittle cracking of the coating at 900−1200 °C. This problem has been overcome in this studyby introducing submicron-SiB6 into the coating. The pre-fabricated cracks and a kinetics model of hot-pressed SiB6-MoSi2 ceramic could quantitatively predict the glass growth and crack healing. As expected, enhancing temperature and SiB6 content increased the growth rate of the borosilicate glass and the crack healing ability of MoSi2 ceramic, which was ascribed to the lower oxidation activation energy and larger specific surface area of submicron-SiB6. For the plasma sprayed coating, SiB6 with submicron structure was benefit for cracking inhibition and formation of borosilicate glass during oxidation, reducing the oxygen permeability and the consumption of inner coating. Hence, the 15 % SiB6-MoSi2 coatings raised the protection times to 84 and 120 h at 900 and 1200 °C respectively, presenting favorable oxidation protective performance. 相似文献
28.
29.
Sawao Honda Shinobu Hashimoto Benoît Nait-Ali David S. Smith Yusuke Daiko Yuji Iwamoto 《Journal of the American Ceramic Society》2022,105(10):6335-6344
Porous alumina with a highly textured microstructure was fabricated by pulse electric current sintering (PECS) using alumina platelets. Highly oriented porous alumina with a porosity of 3%–50% was obtained by a pressure-controlled method of PECS. The properties of the highly textured porous alumina were measured in two directions. The nitrogen gas permeance and thermal conductivity at room temperature were higher in the direction along the platelet length due to the higher continuity of pores and the connectivity of alumina platelets, respectively. The anisotropy of the thermal conductivity at room temperature was investigated and explained by the effect of grain size of platelets as well as morphology and orientation of pores. The bending strength was higher with the loading direction along the platelet thickness. The thermal shock strength was clearly different in the two directions. The difference in the thermal shock strength was investigated by the measurement of properties and thermal stress analysis. 相似文献
30.
土木工程施工课程作为土木工程及工程管理专业的学科基础课和核心专业课程,在疫情防控期间"停课不停教""停课不停学"的要求下,通过线上平台进行授课。由于土木工程施工课程内容庞杂、综合性强、实践性强,且章节之间关联性较弱,探究既能使学生快速适应,又能保证教学质量的在线教学方法至关重要。以华南某高校土木工程施工课程为例,基于中国大学MOOC、建筑云课、腾讯课堂、QQ群等线上平台讲授教学内容,并运用问卷调查对课程线上教学效果进行评价。结果表明,线上教学为学生提供了丰富灵活的学习方式,显著提高了学生的自主学习能力,扩大了学生的知识面,达到了较好的学习效果。 相似文献