Network topology and the theory of rubber elasticity

The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters.     

浅析2020年前美军事战略重点的转变--从装备发展看美国军事战略重点可能的变化

美国21世纪前期的军事战略重点将是争夺外空优势，夺取制天权和制信息权。分析了美国夺取外空优势的原因，及其为夺取外空优势在国家政策、航天发展和技术准备等方面采取的措施。     

宝钢研制的全氢罩式炉控制系统分析

对宝钢研制的全氢罩式炉计算机控制系统的逻辑结构、工作原理及硬件配置进行了分析.该系统与引进的系统相比,在通讯方式、程序结构、操作分析、报警和开放性等方面都有所改进.     

野外大气扩散试验中四面体气球示踪实验的初步评价

1985年11月在瑞士北部进行了一次以探讨“冷池”条件下的扩散和湍流特征为目的的国际野外大气试验,本文介绍其中的四面体气球示踪实验的结果。一共进行了三次由雷达跟踪的四面体示踪实验,释放了10个四面体球。按多轨迹法和单轨迹法分别估算并比较了其中两次示踪实验得到的水平扩散参数σ_y,探讨了风摆效应的贡献。采用“体源模式”并结合单轨迹法估算了微弱风场不定风向条件下的扩散参数,分析了静风,弱风条件下的水平风向标准差和湍流强度。     

PowerPoint2000动画设计应用

PowerPoint2000是Microsoft公司办公自动化软件Office2000的重要构件之一。其自身具有强大的处理功能，尤其是PowerPoint2000所提供的基本动画效果，更是给演示文稿增添了很多色彩。如果能将这些基本动画效果巧妙地组合在一起，就会创作出更富感染力的作品。就创作中的技巧并结合应用举例分析如下。相信人们可以利用这些设计思想，创作出更加精彩的作品。     

军事科研项目中软件项目管理方法研究

列举分析了目前软件开发中存在的问题，提出了在军事科研项目中，对软件项目实施管理的方法，应用先进的软件项目管理理论和方法，有效的提高软件开发效率，确保软件质量。     

The effect of doubly tapered strut morphology on the plastic yield surface of cellular materials

Although the literature on the mechanics of cellular materials is vast, there is no theoretical model to account for the effects of axial yielding of struts aligned to the applied loading direction on the plastic yield surface under multiaxial loading conditions. An anisotropic hexagonal model having tapered strut morphology is developed to show these effects on the plastic yield surface under multiaxial tensile loading condition. This model covers several types of cellular structure such as two-dimensional (2D) hexagonal and square cellular materials, and three-dimensional (3D) hexagonal and rhombic cellular materials of rod-like columnar structure. A tetrahedral element with tapered strut morphology is also used for a foam model to illustrate these effects on the yield surface under axisymmetric loading condition. Plastic collapse due to bending moment in the inclined struts is a dominant mode. However, under multiaxial tensile loading, the collapse due to axial yielding of struts parallel to the loading direction is found to be an important mode. The shape of plastic yield surface was found to depend not only on relative density but also on the strut morphology.     

浅谈综合布线系统接地设计

综合布线系统作为建筑智能化不可缺少的基础设施,其接地系统的好坏将直接影响到综合布线系统的运行质量,故而显得尤为重要。本文介绍了综合布线系统接地的结构及设计要求,并提出在接地设计中应注意的几个问题。     

定向探测引信技术分析

从提高引信与战斗部配合效率出发 ,根据定向战斗部的战术技术性能 ,介绍了一种能够识别弹体周围 4个方向目标的定向探测引信 .分析了定向探测器的工作原理和目标方位识别的关键技术 ,并对探测天线的设计做了详细的分析和计算 .     

对国际岩石力学委员会J_V公式的质疑

通过对国际岩石力学委员会JV 公式的论证 ,指出了该公式不符合数理逻辑。结合工程勘察实践 ,拟建了Ky新公式 ,提高了工程岩体完整程度评价方法的科学性。