Fluoroelastomers-dependence of relaxation phenomena on composition

The dynamic-mechanical properties of some fluoroelastomers were determined as a function of composition at low frequency (≈ 1 Hz), by means of a free oscillation torsion pendulum, between −180°C and the softening point. Vinylidenefluoride (VDF)-hexafluoropropene (HFP) copolymers of molar composition 0–39% HFP and terpolymers of VDF and HFP with up to 30mol% tetrafluoroethylene (TFE) and a constant VDF to HFP molar ratio of 3.4 were considered. Two relaxation processes typical of the amorphous phase were found. The first, located at about −87°C, is related to local motions and the transition temperature was found to be independent of composition for copolymers, while it depends on TFE molar content for terpolymers. The second is related to the glass transition and the transition temperature depends on the composition. However, for semicrystalline copolymers the double glass transition phenomenon was observed. When crystallinity goes to zero at about 20 mol% HFP, only one transition is observed. It was also found that ordered structures can take place for terpolymers when TFE molar concentration exceeds 20%. The crystal disorder transition of pure PVDF (75°C) is observed also for low HFP concentrations but the transition temperature is strongly reduced. Analogies between the VDF-HFP and E-P systems are also discussed.     

一次多级离心泵运行故障处理及分析

简要介绍了实际生产中多级离心泵存在的问题,并分析了故障原因和处理措施。     

One‐step synthesis and ring‐opening polymerization of novel macrocyclic(arylene multisulfide) oligomers

A series of macrocyclic(arylene multisulfide) oligomers were synthesized under high dilution conditions by reacting diphenyl ether/diphenyl/diphenyl disulfide/diphenyl methane with dichloro disulfide in the presence of a trace amount of iron powder by a one‐step reaction. From MALDI‐TOF mass spectra, it was established that the repeating units of the cyclization ranged from two to seven and the unit of macrocyclic(arylene multisulfide) oligomers had one to seven sulfur atoms. The macrocyclic oligomers readily underwent ring‐opening polymerization in the melt, resulting in linear, high molecular weight polymultisulfides. DSC thermograms demonstrated that the four polymultisulfides, derived from the macrocyclic(arylene multisulfide) oligomers, are amorphous in nature. The macrocyclic(arylene multisulfide) oligomers and polymers were analyzed by MALDI‐TOF‐MS, IR, HPLC, NMR, DSC, and TGA methods. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 735–741, 2004     

大型渣油气化炉激冷室热质传递过程模拟

对现行８．５３ＭＰａ德士古渣油气化炉激冷室中热质传递过程进行了分析、研究，从数学模型着手，进行模拟计算，模拟结果与工业数据吻合良好。通过模拟揭示了激冷过程本质特征，探讨了现行激冷环损坏的主要原因。     

滑坡面位移特征及其应用

论述了滑坡坡面位移特征，提出了根据坡面位移矢量确定滑坡滑动面、预报滑坡发生时间的原理和方法。     

Triangle strings: Structures for augmentation of vertex-disjoint triangle sets

Vertex-disjoint triangle sets (triangle sets for short) have been studied extensively. Many theoretical and computational results have been obtained. While the maximum triangle set problem can be viewed as the generalization of the maximum matching problem, there seems to be no parallel result to Berge's augmenting path characterization on maximum matching (C. Berge, 1957 [1]). In this paper, we describe a class of structures called triangle string, which turns out to be equivalent to the class of union of two triangle sets in a graph. Based on the concept of triangle string, a sufficient and necessary condition that a triangle set can be augmented is given. Furthermore, we provide an algorithm to determine whether a graph G with maximum degree 4 is a triangle string, and if G is a triangle string, we compute a maximum triangle set of it. Finally, we give a sufficient and necessary condition for a triangle string to have a triangle factor.     

甲醇装置高效分醇技术及双"零"节能工艺

针对甲醇分离系统存在的普遍性问题 ,提出了“少醇无水”工艺技术并进行了工业实际应用。在“少醇无水”工艺的基础上 ,又提出双“零”工艺的构思。分别对该两种工艺进行了经济效益分析。结果表明 :“少醇无水”工艺可使入塔醇含量由0 .987%降至 0 .5 62 % ,装置能力提高 6.0 %～ 11.12 % ;双“零”工艺可使 10万t/a甲醇装置生产能力提高 2 2 .0 0 %。     

Cationic copolymerization behavior of a bicyclic orthoester having hydroxy group with glycidyl phenyl ether and volume change on their copolymerization

This article describes cationic ring‐opening copolymerization of a bicyclic orthoester having hydroxy group (BOE‐OH) and glycidyl phenyl ether (GPE), and the volume shrinkage behavior during the copolymerization. THF soluble polyethers [poly(BOE‐OH‐co‐GPE)] were obtained by the copolymerizations at 80–180°C, while crosslinked poly(BOE‐OH‐co‐GPE) was obtained by the copolymerizations at 220–250°C. This crosslinking reaction may originate from the dehydration of methylol groups in the side chain of poly(BOE‐OH‐co‐GPE). The volume shrinkage during the cationic copolymerization reduced as the increase of the BOE‐OH feed ratio. By contrast, the volume shrinkage on the crosslinking polymerization was almost independent on the BOE‐OH feed ratio. Poly(BOE‐OH‐co‐GPE)s with higher BOE‐OH composition showed lower thermal weight loss temperature owing to the release of H₂O by dehydration of methylol groups. The BOE‐OH component in the THF soluble poly(BOE‐OH‐co‐GPE)s lowered the glass transition temperature (T_g), while that in the crosslinked poly(BOE‐OH‐co‐GPE) increased the T_g probably because of the higher crosslinking density. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1356–1361, 2006     

Online double auction mechanism for perishable goods

One-sided auctions are used for market clearing in the spot markets for perishable goods because production cost in spot markets is already “sunk.” Moreover, the promptness and simplicity of one-sided auctions are beneficial for trading in perishable goods. However, sellers cannot participate in the price-making process in these auctions. A standard double auction market collects bids from traders and matches the higher bids of buyers and lower bids of sellers to find the most efficient allocation, assuming that the value of unsold items remains unchanged. Nevertheless, in the market for perishable goods, sellers suffer a loss when they fail to sell their goods, because their salvage values are lost when the goods perish. To solve this problem, we investigate the suitable design of an online double auction for perishable goods, where bids arrive dynamically with their time limits. Our market mechanism aims at improving the profitability of traders by reducing trade failures in the face of uncertainty of incoming/departing bids. We develop a heuristic market mechanism with an allocation policy that prioritizes bids of traders based on their time-criticality, and evaluate its performance experimentally using multi-agent simulation. We find out that our market mechanism realizes efficient and fair allocations among traders with approximately truthful behavior in different market situations.     

经编二元网在双加压法硝酸装置的应用

通过对双加压法硝酸装置铂网使用情况和铂网脱边事故的统计，分析了氧化炉采用平编三元网存在的问题；论述了经编二元网的特性和优点；计算了铂网的生产强度和接触时间，确定了铂网丝径；总结了硝酸装置使用经编二元网的运行效果和经济效益，结果表明，吨酸氨耗降低了2．48kg，铂耗降低了10mg，经编二元网优于平编三元网。