Brillouin-Scattering Study of the Elastic Constants of ErVO4

The room-temperature elastic constants of ErVO₄ were considerably smaller than those of isostructural silicate and phosphate analogs. The generally "less-rigid" crystalline lattice and weaker metal-oxygen bond-strength in the RVO₄ (R = rare earth elements) phases indicates that these materials are of interest for potential applications as an interphase component in toughened oxide ceramic composites.     

无汞碱性锌锰电池贮存期漏液原因探讨

介绍了无汞锌粉中的杂质、析气量、锌粉形貌以及电池密封圈对无汞碱性电池高温贮存性能的影响，探讨了电池漏液的原因，提出了防止漏液的措施。     

纸面稻草板阻燃性能的改进研究

本文就纸面稻草板阻燃性能及其环保安全进行探讨。在覆面胶粘剂中加入氮-磷阻燃剂增强耐火性，结果表明：阻燃剂含量25％时，阻燃效果良好，耐火极限明显延长；同时将胶粘剂中游离甲醛含量降低至0．063％，达到国家的环保要求。     

等强条件下橡胶微粒混凝土抗压特性及弹性模量研究

掺加橡胶微粒可以明显改善混凝土的力学特性。采用橡胶微粒等体积取代细骨料的方法,通过不断调整配合比,反复试验配制出橡胶微粒体积掺量分别为0%、10%和15%的等强度(30 MPa)橡胶微粒混凝土,探讨橡胶微粒混凝土的抗压强度变化规律,以及在等强条件下不同橡胶微粒掺量对混凝土弹性模量的影响。结果表明:掺入橡胶后,混凝土的前期强度(3 d和7 d)发展较基准混凝土变缓,7 d以及14 d后强度出现较大幅度的增长,28 d后各个配比混凝土立方体抗压强度增幅不大;掺入一定量的橡胶后,混凝土的抗裂性能得到了一定程度的改善,橡胶微粒体积掺量越大,试件受压破坏后的完整性越好;掺入橡胶后,混凝土的弹性模量呈现出近乎线性的大幅下降趋势。     

Intrinsic Elastic, Dielectric, and Piezoelectric Losses in Lead Zirconate Titanate Ceramics Determined by an Immittance-Fitting Method

The material coefficients of "soft" and "hard" lead zirconate titanate (PZT) ceramics were determined as complex values by the nonlinear least-squares-fitting of immittance data measured for length-extensional bar resonators. The piezoelectric d -constant should be a complex value to obtain a best fitting between observed and calculated results. Because the elastic, dielectric, and piezoelectric losses determined in this process were not "intrinsic" losses, a calculation process to evaluate the "intrinsic" losses was proposed. It was confirmed that the intrinsic losses were smaller than the corresponding extrinsic losses. The intrinsic piezoelectric loss existed in both soft and hard PZTs; ∼50% of the loss of piezoelectric d -constant was derived from the elastic and dielectric losses. The most notable difference between the soft and hard PZTs was observed in their elastic losses.     

Dynamic response of Ti3SiC2 under shock compression up to 112 GPa

Ti₃SiC₂ is of interest due to its unique dual nature reminiscent of both brittle ceramics and ductile metals at ambient conditions. In this work, plate-impact experiments have been performed to study the dynamic behavior of Ti₃SiC₂ under shock compression up to 112 GPa by using laser velocity interferometer and electric pin techniques. Hugoniot elastic limits (HEL), spall strength, and Hugoniot equations of state have been obtained based on measured particle velocity profiles and shock wave velocities. The ratio of spall strength to HEL for Ti₃SiC₂ is larger than brittle ceramics but smaller than metals. This result indicates that the dual nature of Ti₃SiC₂ remains at least up to 10 GPa. On the other hand, the linearity of the Hugoniot equation of state, $D=6.9\text{0}1(22)+1.153(53)u_{\text{p}}$, suggests that the initial structure of Ti₃SiC₂ should be stable up to 112 GPa, in contrast to the result reported by Jordan et al. [J. Appl. Phys., 93 (2003) 9639].     

全球催化剂工业动向

介绍了在全球范围内催化剂工业的现状,包括市场需求及经营形势。由于美国及其他国家环保法规日趋严格迫使炼油工业采用清洁燃料催化剂,导致炼油催化剂需求量上升,聚烯烃催化剂工业获得较大发展,炼油催化剂技术推陈出新。特种化学品产品催化剂和精细化工领域的催化剂工业将面临挑战。     

一种局部强化的多标签传播社区发现算法

在社交网络中,社区和圈子均表现为一组内部连接相对紧密的节点,但后者规模较小。圈子是重要的局部社区信息,利用这一特点有助于进行社区发现。然而,现有的大部分基于标签传播的社区发现算法并没有考虑圈子的信息。为此,提出一种基于局部强化的多标签传播(LSMLP)社区发现算法。给出圈子的定义,提出一种基于圈子信息的迭代多标签传播策略,并从每个节点的多个标签中选择归属系数最大的标签作为其从属的临时社区。采用两步优化方法使模度最大化。在真实网络的数据实验结果表明,与已有的社区发现算法相比,LSMLP算法能更高效地发现社区。     

供应链环境下安全的RFID认证方案

供应链环境下RFID安全认证方案不仅要保证各节点的隐私安全,还应该满足供应链管理需求。针对现有方案存在不能同时兼顾两者的不足,提出一种基于"双重签名"的认证方案。标签的认证信息先后采用访问密钥和认证密钥进行双重签名生成,只有同时具备这两个密钥才能识别标签身份。该方案既可以实现标签在供应链内的安全传递,又能方便供应链的管理。分析表明,该方案较现有方案优势明显。