Synthesis and characterisation of carboxylic acid and diphenylphosphine derivatives in the 1,3-diyne series: Spectral properties of polydiacetylene carboxylates

Symmetrically substituted 1,3-diynes containing hydroxyalkyl ( 1a-d ), bromoalkyl ( 1e-h ) (diphenylphosphinyl) ( 1i-k ) and carboxyalkyl ( 2a-d ) substituents have been prepared and characterised; the phosphine derivative ( 1k ) has been converted with alkyl iodides ( RI ; R = Me, Et) into bis(phosphonium) salts ( 1l and m ). During preparation of the diynedioic acid. ( 2a ), the non-centrosymmetrical diyne, HO₂CCH₂C?C—C?C(CH₂)₂OH ( 3 ), was also isolated. ⁶⁰Co γ-Irradiation of diacetylene monomers ( 2a – d ) and 10,12-tricosadiyn-1-oic acid gave the corresponding polydiacetylene derivatives ( 4a – d and 5 ), respectively. Rubidium salts of ( 4c ) and ( 4d ), a barium salt of ( 4c ), and a potassium salt of ( 5 ) were prepared and isolated; soluble potassium salts of the carboxylic acid polymers ( 4 ) were generated in aqueous solution. The effects of changes in pH on the UV/visible absorption spectra of aqueous solutions of selected carboxylic acid polydiacetylenes have been recorded, and are discussed.     

自升式平台深水化改造的新模式及其可行性分析

针对我国现有自升式平台存在的不能满足深水域勘探开发的要求以及造价过高等问题,提出一种自升式平台深水化改造新模式——分体坐底自升式平台,在基本不改变原有平台结构的基础上,通过增加可沉浮平台下体,使作业水深增加50m以上,而造价比同工作水深的常规自升式平台低得多。文章介绍了该分体坐底自升式平台的结构方案、作业工况及操作程序,分析了该平台的技术可行性和经济可行性,并提出了深入研究和具体实施需要解决的问题。     

非标准工况下空分设备增产氩的研究与实践

文章对非标准工况下的空分设备增产氩措施进行了研究。以宝钢6#60000m3/h空分设备为例,通过设计型算法和校核型算法,建立了空分设备精馏的数学模型,通过改变数学模型的参数,分析了在非标准工况下精馏塔内的组分浓度分布,并提出了优化后的操作方案和操作参数,实施后提高了空分设备的氩提取率,取得了显著的经济效益。     

电子商务中SET协议的安全缺陷研究

目前SET协议在电子商务交易中应用越来越广泛,因此,对SET协议的安全性的要求就越来越高。论文在SET协议的交易流程基础上,分析了其安全机制采用的技术和优点,指出了SET协议安全性存在的一些问题。     

Development of a Magnetic Suspension Densimeter and Measurement of the Density of Toluene

The development of a magnetic suspension densimeter that has been built for measurement of the density of compressed liquid at pressures up to 30 MPa in the temperature range 20 to 150°C is described. The densimeter was first built by the author and his coworkers at NIST. We describe here further improvements made on a second system built at NMIJ based on the same principle. The densimeter uses a small coil suspended from an electronic balance. Within the coil is placed a sample cell in which the pressurized sample and a buoy, which is a permanent magnet, are enclosed. For measurement of density, balance readings are recorded (1) with the buoy at rest and (2) with the buoy in magnetic suspension. The measurement procedure is basically a hydrostatic weighing, which is simpler than those of conventional magnetic densimetry. As an example, measurements of toluene density performed as part of an inter-laboratory comparison are presented. The data agreed with reliable literature values to within a few hundredths of a per cent.     

40000m~3/h空分设备主换热器的设计及制造

通过对进口 4 0 0 0 0m3 /h空分设备主换热器进行结构分析及对比模拟计算 ,用国产传热翅片进行设计、采用真空钎焊工艺制造的主换热器 ,经并网运行 ,设计指标优于原空分设备 ,为今后成套大型空分设备板翅式换热器国产化设计、制造创造了条件。     

海洋石油平台水下夹桩器本体结构分析

水下夹桩器是一种广泛应用于海洋石油平台建设的液压夹具。水下夹桩器本体焊接在导管架上，支撑夹桩器液压缸。在水下夹桩器本体设计中，采用有限元法完成了对本体强度和刚度的结构分析；建立了有限元分析模型，用ANSYS软件进行结构分析，得到了分析结果，并将该结果与理论计算结果进行了比较，验证了有限元分析技术的有效性。设计结果满足工程要求，为改进和优化结构提供了理论依据，节省了分析计算时间。     

Interweaving genetic programming and genetic algorithm for structural and parametric optimization in adaptive platform product customization

An adaptive product platform offers high customizability for generating feasible product variants for customer requirements. Customization takes place not only to product platform structure but also to its relevant parameters. Structural and parametric optimization processes are interwoven with each other to achieve the total optimality. This paper presents an evolutionary method dealing with interwoven structural and parametric optimization of adaptive platform product customization. The method combines genetic programming and genetic algorithm for handling structural and parametric optimization, respectively. Efficient genetic representation and operation schemes are carefully adapted. While designing these schemes, features specific to structural and parameter customization are considered for the simplification of platform product management. The experimental results show that the performance of the proposed algorithm outperforms that of the tandem evolutionary algorithm in which a genetic algorithm for parametric optimization is totally nested in a genetic programming for structural optimization.     

我国海洋石油钻井平台现状与技术发展分析

海洋油气开发装备产业是直接关系到海洋油气资源开发、影响国家能源稳定和经济安全的战略产业。海洋石油钻井平台是海洋油气开发的关键装备,我国海洋石油装备产业在海洋油气产业持续快速发展的带动下,正处于高速发展的新时期。对我国海洋石油钻井装备产业发展现状及市场需求进行了深入研究,并对海洋石油钻井平台技术特点做了介绍,重点分析了该项技术的发展状况,从钻井平台类型和技术含量等方面指出我国与世界先进海洋石油钻井平台的主要差距,并提出了若干发展建议。     

An ideal topology type convergent theorem on scale effect algebras

The famous Antosik-Mikusinski convergent theorem on the Abel topological groups has very extensive applications in measure theory, summation theory and other analysis fields. In this paper, we establish the theorem on a class of effect algebras equipped with the ideal topology. This paper shows also that the ideal topology of effect algebras is a useful topology in studying the quantum logic the- ory.