This study deals with the development of a laboratory bench for the practical evaluation of catalysts that are useful for the direct conversion of NOx and soot in the exhaust of diesel engines. The employed model exhaust is generated by using a diffusion burner with additionally dosing some gaseous components to the burner gas to obtain a realistic feed composition. The produced soot is extensively characterized by employing thermogravimetry, transmission electron microscopy, N2 physisorption and temperature programmed techniques. The results of the different characterization methods show that the present soot is suitable for the intended catalytic investigations. The simultaneous conversion of NOx and soot is examined like in practice, i.e. the soot is separated from the tail gas by a diesel particulate filter (DPF) that is coated with the catalyst. The deposited soot is then catalytically converted by NOx and O2 to form N2 and CO2. The conversions of NOx and soot are measured by exclusively applying gas analysers, whereby a special experimental procedure is developed to determine the soot removal. Hence, additional soot related analytics are not required. To show the suitability of the constructed bench a Pt/Fe2O3/β-zeolite sample is taken as test catalyst that is reported to be very active in NOx/soot reaction. The measurements performed with and without catalyst clearly show the effect of the used sample in simultaneous NOx/soot conversion. We therefore consider the constructed laboratory bench to be a useful tool for testing and ranking catalytic materials. 相似文献
The nonlinear dynamic behaviour relating the wet front size and liquid saturation under inner cylinder (or rectangular cell) in cylindrical (or rectangular) capillary suction apparatus was investigated. The slow manifold explanation was proposed and the fast- and slow-varying variables were identified. Experiments were conducted to verify theoretical findings. 相似文献
A exhaust system consisting of a close-coupled Pd technology 32 in3 lightoff converter and Pt/Rh technology 170 in3 underfloor converter was vehicle-aged for 56000 miles on a vehicle equipped with a 3.8 l engine. Following this aging, the converters were taken off the vehicle and cut into 1″ thick sections along their axis and characterized for lightoff and warmed-up activity using a laboratory reactor to simulate vehicle exhaust. Each section was also analyzed for the quantity of oil additive poisons (phosphorus and zinc) deposited. Following this initial characterization, the phosphorus and zinc deposits were removed, and the sections were characterized again for lightoff and warmed-up activity. This procedure was used to qualitatively determine the relative contribution of oil additive poisoning and thermal sintering to the total activity deterioration as a function of axial position in the catalyst monoliths.
Analysis of the lightoff converter as taken from the vehicle showed a dramatic axial gradient in the lean and stoichiometric lightoff and warmed-up (600°C) performance for HC, CO and NOx, with most of the deterioration having taken place in the forward-most 1″ section of the converter, which was consistent with the gradient in the deposition of phosphorus (P) and zinc (Zn) in this converter. Comparison of these data sets with those obtained after removal of the P and Zn poisons indicates that most of the total deterioration of lean HC and CO activity can be attributed to P and Zn poisoning of the forwardmost 1″ section. When tested under stoichiometric conditions, most of the deterioration of HC activity is attributable to P and Zn poisoning, while most of the deterioration of CO and NOx activity is attributable to thermal deterioration. A similar activity and poison deposition gradient was detected in the underfloor converter, but to a smaller extent. 相似文献