国内外己内酰胺生产与消费市场研究

分析了国内外己内酰胺生产技术状况和市场消费情况并展望了未来发展前景,由于新建己内酰胺项目耗资巨大,建议国内企业通过消化吸收引进的技术挖潜改造扩大产能,能提高我国自主开发己内酰胺的生产能力。     

高密度增强硬质聚氨酯泡沫塑料的复合泡体结构

通过对高密度玻璃纤维增强硬质聚氨酯泡沫塑料（RRPUF）的断裂面形态观察,发现RRPUF含有多种形态的泡孔,是一种泡孔之间相互连结、贯穿的复合泡体结构。研究结果发现,密度分别为0．11、0．31及0．51g/cm^3RRPUF的泡体结构大致相同,都是复合泡体结构,但随密度增大,泡孔形状更趋于球体,泡孔尺寸分布范围变窄,平均尺寸减小。还计算了RRPUF的气体体积含量与密度及纤维之间的关系,发现其主要与泡体密度有关。此外,还初步探讨了复合泡体结构的形成机理,指出发泡剂和热分布不均是产生复合泡体结构的主要因素。     

预处理短纤维对VMQ/EPDM共混导电橡胶某些性能的影响

研究了预处理短纤维用量对乙炔炭黑填充甲基乙烯基硅橡胶（ＶＭＱ）／ＥＰＤＭ共混硫化胶拉伸、撕裂、耐屈挠疲劳和导电性能的影响。实验结果表明，加入适量短纤维对ＶＭＱ／ＥＰＤＭ体系有一定的补强作用；纤维用量较大时，导电性能下降。加入４．０份左右的预处理短纤维，可使ＶＭＱ／ＥＰＤＭ共混导电橡胶获得良好的物理机械性能和导电性能     

切边V带的研制

采用恒张力整体成型、胶套式硫化罐硫化、硫化后切割的新工艺研制了切边Ｖ带。强力层材料选用进口硬质聚酯线绳，底胶选用ＣＲ并掺入２０～３０份棉短纤维，产品性能均超过化工部ＨＧ４－４０１—７４标准并达到了日本ＪＡＳＯＥ１０７—８２标准要求，可以满足用户要求，新生产工艺具有产品质量稳定、生产效率高和更换产品规格灵活方便等特点。     

短纤维-橡胶复合材料在输送带中的应用

介绍了以不连续的聚酯短纤维群为骨架材料，ＮＲ／ＳＢＲ为基质胶的定向短纤维橡胶复合材料（ＯＳＦＲＣ）在输送带中的应用。结果表明，ＯＳＦＲＣ输送带与棉帆布芯输送带相比，使用寿命提高１倍，带体综合物理性能好，在应力作用下不脱层，无受潮霉烂现象，输送平稳且不打滑，适宜在苛刻条件下使用。     

我国人工皮革发展机遇的探讨

介绍了国外超细纤维人工皮革的产销与应用情况．追溯了国际上这一领域最新技术的进展．通过对国内未来几年市场需求的分析与预测，提出了应在高起点上发展我国人工皮革的思路。     

剑麻纤维／酚醛树脂复合材料研究

本文采用碱处理、硅烷偶联剂处理、化学接枝和热处理等物理化学方法，对剑麻纤维进行改性。研究了改性后短剑麻纤维／酚醛树脂复合材料的弯曲性能、无缺口冲击强度和布氏硬度，借助扫描电子显微镜观察了复合材料的弯曲断口形貌，并研究了剑麻纤维的不同处理方法对复合材料耐水浸泡性的影响。结果表明：剑麻纤维经硅烷偶联剂处理后，能有效改善刚性的剑麻纤维与脆性的酚醛树脂基体之间的粘结，从而提高了复合材料的综合力学性能，剑麻     

碳纤维自行车车架的研制与开发

开发生产碳纤维自行车是当今自行车工艺领域致力研究的课题，本文介绍国内外碳纤维自行车研制的过程和现状取得成果的基础上，着重对整体车架从形态设计，有限元受力分析，成型工艺三个方面进行的研究和开发进行了分析。     

Graphene oxide membranes supported on the ceramic hollow fibre for efficient H2 recovery

The special channels and intrinsic defects within GO laminates make it a very potential candidate for gas separation in recent years. Herein, the gas separation performance of GO membranes prepared on the surface of ceramicα-Al_2O_3 hollow fibre was investigated systematically. The microstructures of ceramic hollow fibre supported GO membranes were optimized by adjusting operation conditions. And, the GO membrane fabricated at 30 min exhibited great promising H_2 recovery ability from H_2/CO_2 mixture. At room temperature, the H_2 permeance was over 1.00 × 10~(-7)mol·m~(-2)·s~(-1)·Pa~(-1)for both single gas and binary mixture. The corresponding ideal selectivity and mixture separation factor reached around 15 and 10, respectively. In addition, humility, operation temperature, H_2 concentration in the feed and the reproducibility were also studied in this work.     

In situ fibre‐reinforced composite films of poly(lactic acid)/low‐density polyethylene blends: effects of composition on morphology,transport and mechanical properties

This study aimed to investigate the effects of blend composition on packaging‐related properties of poly(lactic acid) (PLA) and low density polyethylene (LDPE) blown films. Blend films with PLA contents of 5–20 wt% were produced and compared. Scanning electron micrographs of cross‐sectional cryofractured surfaces of the blend films revealed that in situ fibre‐reinforced composites were obtained. Viscosity ratio of the polymer components of ca 1 confirmed that fibre formation was favourable for this blend system. PLA microdomains were dispersed throughout the film in forms of long fibres (length‐to‐diameter ratio > 100) and ribbons. The number of fibres and ribbons increased with an increase of PLA content. Critical content of PLA was found to be 20 wt% for effective improvement of both moduli and gas barrier properties. Incorporation of poly[ethylene‐co‐(methyl acrylate)] compatibilizer showed minimal effect on PLA structure. However, it did improve moduli and O₂ barrier properties when sufficient amount (1.5 pph) was used in 10 wt% PLA/LDPE. In short, flow behaviour, ratio of polymer components and degree of compatibility together played intricate roles in the morphology and hence mechanical and transport properties of PLA/LDPE immiscible blends. © 2017 Society of Chemical Industry