Diamino telechelic polybutadienes for solventless styrene-butadiene-styrene (SBS) triblock copolymer formation

High molecular weight, high functionality diamino telechelic polybutadienes (TPBs) were synthesized by ring-opening metathesis polymerization (ROMP) of 1,5-cyclooctadiene (COD) in the presence of a chain transfer agent, 1,8-dicyano-4-octene, followed by lithium aluminum hydride reduction. Melt coupling of diamino TPB with anhydride-terminated polystyrene (PS-anh) resulted in the formation of styrene-butadiene-styrene (SBS) triblock copolymers; ca. 80% maximum conversion of PS-anh was achieved within 30 s. The results from SAXS, TEM, and rheological measurements of the coupling products confirmed the formation of SBS triblock copolymers having lamellar morphology. A fluorescent-labeled PS-anh was used to study the coupling kinetics by diluting the reactants by the addition of non-functional PS.     

基于ANSYS的铸嘴流体耦合场三维有限元仿真分析

作者用大型有限元分析软件ANSYS对铸嘴内稳态层流铝熔体进行仿真分析。实现了三维建模。解决了三维热一流耦合求解的问题，得到铝流体的速度、压力及温度的分布图。分析了铸嘴出口速度和温度的分布规律及其对连续铸轧的影响。     

饲料级磷酸氢钙中氟的几种分析方法比较

本文采用茜素络合酮比色法和氟离子选择电极法对饲料磷酸氢钙进行氟的测定实验对比,得出常用的氟离子选择电极法完全可以代替经典的蒸馏比色法的结论。     

Equilibrium distribution of water in the two-phase system supercritical carbon dioxide–textile

When natural fibres are dyed in supercritical carbon dioxide, the addition of a small amount of water increases coloration. For a process design it is important to know how much water has to be added to obtain a desired humidity of both textile and carbon dioxide. In this work a thermodynamic model is proposed to calculate the distribution of water over the textile phase and the supercritical phase as a function of pressure and temperature. The phase equilibrium is described with Raoult's law for non-ideal fluids. The absorbed water in the textile is a condensed phase and is modelled here as a non-ideal liquid, using the NRTL-equation. The non-ideality of the supercritical phase is described by a solubility enhancement factor, a new equation derived from statistical thermodynamics. Although the model is applied to cotton, viscose, silk and wool, it can be used for all water absorbing textiles.     

莺歌海盆地底辟构造的成因及石油地质意义

在总结莺歌海盆地底辟构造特征及其伴生的温度和压力异常资料的基础上,提出了流体底辟模式,并进一步讨论了流体底辟在石油地质中的意义.     

凝固过程中的颗粒推斥

颗粒推斥是材料在固液相变过程中的基础问题之一，界面自由能的传统理论难以解释在金属基复合材料制备过程中的颗粒推斥现象，作者提出了固液界面前沿的流体流动是颗粒推斥的主要原因之一，并给出颗粒滚动及颗粒速度两种作用机制，推导出颗粒推斥条件判据，并以实验验证流体流动的作用机制及颗粒推斥理论判据。     

粉煤灰填充尼龙6浇铸制品的研究

将粉煤灰用硅烷偶联剂处理后填充到尼龙6浇铸制品(MC尼龙)中,可以改善制品的吸水性、收缩率及热稳定性等,还可以降低成本。该项研究结果有很大的实用价值。     

Oxidative coupling of methane over CaO-MgO mixed oxide

Mixed oxide catalyst prepared by co-precipitating magnesium oxide and calcium oxide showed an excellent activity for the oxidative coupling of methane. The high performances were presumed to arise from the high basicity of the mixed oxide.