Adhesion Mechanisms of Polyurethanes to Glass Surfaces I. Structure-Property Relationships in Polyurethanes and Their Effects on Adhesion to Glass

Polyurethanes were prepared from toluene diisocyanate (TDI), 1-4-butane diol (BDO) and polycaprolactone-based triols with varying molecular weights. Among each molecular weight triol-based urethane, hard segment content was varied from 20% to 70%. Differential scanning calorimetry, tensile testing, and Iosipescu shear testing were done on all the various urethanes prepared. Thermal characterization data revealed the dependence of phase separation on hard segment content as well as on the triol molecular weight. Tensile data and Iosipescu shear data further confirmed the observations made from the DSC data. The data further indicated that phase separation can greatly improve the modulus of cross-linked segmented urethanes. Adhesion of these urethanes to glass surface was evaluated using soda-lime float glass plate. Urethane samples were cast on the air side of the glass plates and adhesion was measured in shear mode. Adhesion data indicated that in addition to hard segment content, modulus, cross-link density, and molecular weight of the triols, phase separation seems to be a major factor in controlling adhesion. Surfaces of the failed adhesion samples were also analyzed and the failure mode was found to be cohesive, in varying degree, with the different urethane systems.     

软段含离子基团的阴离子型水性聚氨酯胶粘剂的研究(Ⅱ)——硬段结构的影响

以含有不同离子基团的聚酯多元醇为软段,采用丙酮法合成了一系列水性聚氨酯乳液。研究了不同硬段结构和硬段含量和扩链剂对其干膜物理机械性能和吸水率的影响。     

基于虚拟磁盘的携带型操作系统加密方案

针对移动硬盘的加密系统分区无法被正确辨识而导致误格式化的问题,应用文件系统过滤驱动技术,结合硬盘主引导程序及分区表机理,对现有的基于虚拟磁盘的移动硬盘加解密方案进行了改进,在加密分区包含可运行操作系统的情况下,增加了盘符自动隐藏及恢复的功能。以开源加密软件Truecrypt为例,利用安装了视窗操作系统的固态移动硬盘进行测试。结果表明,在不影响加密操作系统正常运行的同时,盘符自动隐藏及恢复功能避免了用户的误格式化操作,从而提高了移动硬盘加密系统分区的安全性和隐蔽性。     

难粘材料聚烯烃粘合剂

研制了一种不需经任何表面处理即可与聚烯烃类难粘材料粘合的双组份粘合剂，它与铝箔、纸张等极性物粘合效果良好。     

Program Design of Graphic Realism Displaying System Based on DXF Lathe Turning Rotational Parts

For virtually realizing the graphic realism display of DXF machine parts, in AutoCAD2007 graphic drawing environment, an interactive experimental method was taken to realize the display of graphic in DXF, which was taken as the data-exchanged interface and source. Based on depth analysis of DXF data structure, take one drawing of DXF lathe turning rotational part asthe test piece. By VC＋＋6.0 programming, part＇s geometry information could be obtained. Through data processing, 3D data of the test piece could be generated, which is based on 2D data of DXF test piece. Then, OpenGL graphic processing technologies （light, material, texture, map, et al.） were applied on the 3D display of test piece from DXF files or program modules. Finally based on the test report, results of the system functions were shared to prove the realization of system design, and the feasibility of algorithms used. In the developed software, Machine Designers could get a full view of machine parts, and do some proper modifications. The study content and results of our work have some theory and practical significance on the application of program design in the practical projects.     

基于小波分析的储粮害虫图像去噪研究

以储粮害虫为研究对象,阐述了小波去噪的基本原理和高频系数置零、硬阈值法、软阈值等几种方法,并提出了一种改进的小波阈值去噪方法,比较了这几种方法在粮虫图像去噪上的优缺点。实验结果表明,改进的新阈值方法能更好的去除噪声,收到更好的效果。     

A NEW SIMULATION APPROACH TO THE ENTROPY-RELATED PROPERTIES OF FLUIDS——CHEMICAL POTENTIAL AND HELMHOLTZ FREE ENERGY OF HARD SPHERE FLUIDS

A new approach to the computation of entropy-related properties of fluids has been pre-sented.Application of the new technique to hard sphere fluids shows that it is capable of providingreliable estimates of such properties as the chemical potential and Helmholtz free energy,even athigh density where other existing methods are hardly applicable.The chemical potential of an infinitedilute component in hard sphere systems has been estimated,and compared with that calculated fromthe Carnahan-Starling equation.     

淬硬钢硬态切削表面粗糙度研究

使用Ti—C基金属陶瓷刀具对45淬硬钢进行了切削试验,研究了切削用量对表面粗糙度的影响．试验分析表明,进给量对表面粗糙度影响最为显著,切削速度对表面粗糙度有一定影响,切削深度对表面粗糙度的影响很小．运用回归分析法,建立了硬态切削表面粗糙度预测模型,通过试验验证了预测模型的准确性．     

高速镗孔技术在压路机零件加工中的应用研究

针对深长孔加工的同轴度问题,通过分析高速调头镗的效率和加工精度,论述了调头镗孔工艺方法在压路机铰接架零件加工中的应用及高速加工的可行性.     

离子型磁性液体中纳米微粒间相互作用研究

用磁偶板子硬球模型对磁性液体中磁性纳米微粒间相互作用进行了研究。分析表明,微粒间存在着静电排斥、静磁吸引和VanderWaals吸引三种相互作用,无外场时静磁作用非常微弱,可以忽略,静电排斥力作用距离远,起抗团聚作用,Vander Waals作用距离短,是引起团聚主要原因。为确保磁性液体稳定性,制备的离子型磁性液体体积分数应小于5％。