Unique clay orientation in the injection-molded bar of isotactic polypropylene/clay nanocomposite

In this article, the injection-molded bars of isotactic polypropylene/organoclay nanocomposite with different clay contents have been obtained via dynamic packing injection molding (DPIM). The oriented microstructure including layered nanoparticles and PP lamellae has been inspected through 2D-WAXS analyses along the sample thickness of the molded bars. Depending on the clay content and sample thickness, various oriented clay structures with nanoparticles uniplanar-axially oriented parallel to the surface of molded bar, or partially tumbled around the flow axis of the molded bar, or even a random orientation, could be observed. The observed orientation behavior of nanoparticles could be temporarily elucidated as the results of the sensitive response of layered nanoparticles to shear deformation and the structural recovery of clay network assisted by the electrostatic attraction existing between adjacent nanoplatelets.     

注射成型模具排气槽的设计

塑料注射成型模具的排气方式和排气槽结构直接影响塑料制品质量。介绍了塑料注射成型模具的排气方式、排气槽设计经验以及切实可行的排气方案和排气槽结构。     

The effect of cooling rate on the impact performance and dynamic mechanical properties of rotationally molded metallocene catalyzed linear low density polyethylene

This article examines changes to the morphology of rotationally molded metallocene catalyzed linear low density polyethylene brought about by varying the cooling rate during processing. These changes in morphology lead to variations in the impact performance, which is reflected in the dynamic mechanical characteristics of the materials. Various analytical techniques are used in an attempt to explain the differences in impact behavior. Slow cooling is shown to result in high crystallinity, and in the formation of large spherulites, which in turn is detrimental to the impact performance of the material, particularly at low temperatures. The high crystallinity corresponds with a shift in the β transition of the material to a higher temperature, and is shown to result in a higher brittle–ductile transition. A case study was also carried out on samples from a finished part provided by an industrial molder, one section of which failed in a brittle manner when impact tested while the other failed in a ductile manner. Microscopy results showed that the brittle material had large spherulites at the inside surface, while the ductile material showed incipient degradation at this surface, which has previously been shown to be of benefit to impact strength in rotationally molded parts. Dynamic mechanical studies again showed a β transition at a higher temperature in the brittle samples. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1963–1971, 2006     

彩色显像管锁紧螺母注射模设计制造

分析彩色显像管锁紧螺母塑料件的工艺结构特点和改性聚苯醚的成型特性,介绍该塑料件注射模的结构、工作过程及制造特点;重点阐述自动旋转脱螺纹机构的设计要点。该模具结构巧妙、合理,生产效率高,对同类产品的生产具有一定的借鉴作用。     

气体控制参数对气体辅助成型产品翘曲的影响

从气体辅助注射成型工艺的角度探讨了气体的延迟时间和第一段压力这两个关键的参数对槽的影响进而对产品翘曲变形的影响，结果表明：虽然通过使用气体辅助注射成型技术能改善产品变形，但并不能完全消除变形；造成产品变形的原因和机理十分复杂，只有进行从设计到工艺的全方位考察才能有效的控制变形，气体手指效应也是造成产品变形的一个重要因素，工艺上可以通过调整延迟时间和气体压力来减小产品的变形量。     

碰撞式混合器的设计和使用

从反应注射成型过程对混合器的结构设计、操作条件等的要求出发，对碰撞式混合器的设计和使用应注意的问题进行了分析探讨，并提出了相应的解决办法和处理措施。     

Effect of crystallization and interface formation mechanism on mechanical properties of film‐insert injection‐molded poly(propylene) (PP) film/PP substrate

A previous study has shown that the adhesion between the film and substrate of film‐insert injection‐molded poly(propylene) (PP) film/PP substrate was evident with the increases in barrel temperature and injection holding pressure. In this second part of the research work, the crystallinity at the interfacial region (i.e., region between the film and the injected substrate) was extensively studied using FTIR imaging, polarized light microscopy, and DSC in an attempt to determine the level of influence that crystallinity has on the interface and bulk mechanical properties. Consequently, a more thorough and clearer picture of the influence of the inserted film on the interfacial crystallinity and subsequently the substrate mechanical properties, such as peel strength and impact strength, has been revealed. The initial proposition that crystallinity could enhance film–substrate interfacial bonding has been confirmed, judging from the higher peel strength with increasing crystallinity at the interfacial region. Nevertheless, the change in crystallinity was not only confined to the interfacial region. With the film acting as heat‐transfer inhibitor between the injected resin and the mold wall, the total crystal structure of the substrate was substantially altered, which subsequently affected the bulk mechanical properties. The lower impact strength of film‐insert injection‐molded samples compared to that of samples without film inserts provided evidence of how the film could impart inferior properties to the substrate. The difference in cooling rate between the substrate and film might also cause other defects such as warpage and/or residual stress build‐up within the product. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 294–301, 2005     

孤东油田二区聚合物驱工程可行性研究

孤东油田二区开发单元,目前已进入特高含水开发阶段,由于油层非均质性及驱替水与油层内流体流度比制约着注入水的驱油效果,水驱采收率不高。针对二区油藏特点及水驱开发现状,决定开展聚合物驱可行性研究。     

鼠标的组合型腔浇注系统优化设计

本文将注塑系统平衡的理论和数值模拟技术紧密结合起采，研究鼠标组合型腔的浇注系统。如果熔体不能同时到达各浇口并充满各个型腔，将导致压力分布不均匀，使制品的质量下降，以至于出现充不满等问题，本研究对浇注系统优化，得出了一组最佳的浇注系统方案，从而保证熔体能够基本上在同一时间充满型腔，实现熔体的平衡流动。从分析结果可知，要平衡熔体在组合型腔内的流动，分流道的截面形状和尺寸起到非常大的作用。     

Cure monitoring via different techniques: Isothermal cure of an epoxy-novolac molding compound

The isothermal cure of an epoxy-novolac molding compound was studied by means of Fourier-transform infrared spectroscopy (FTIR) and dielectrometry (DE). Results obtained were compared with previous differential scanning calorimetric (DSC) observations. The behavior of epoxide conversion (_FTIR) measured via FTIR was found similar to (but not exactly coinciding with) the extent of cure (_DSC) determined previously by means of DSC. As for the DE analysis, directly measurable properties such as permittivity () and loss factor () varied in a complicated manner during the course of cure, showing strong dependence on both temperature and frequency. Other dielectric parameters (such as ionic conductivity, relaxed permittivity, and characteristic relaxation time) previously suggested in the literature as suitable for cure monitoring purposes were found difficult to determine within the limited frequency range (10⁰ to 10⁴ Hz) here. With some arbitrariness, the relative drop in log (at 100 Hz) was taken as an index (_DE) for the extent of cure. It was observed that _DE behaves in a manner similar to _FTIR and _DSC Comments on the application of these three techniques in the characterization of thermosetting systems were given.