Poly(vinyl pyrrolidone)—C70 complexes in aqueous solutions

Aqueous solutions of poly(vinyl pyrrolidone)-fullerene complexes (PVP-C₇₀) have been studied using static and dynamic light scattering methods. Two diffusive processes were detected. The slow diffusion was interpreted as dynamics of large intermolecular PVP-C₇₀ complexes while the fast diffusion was associated with the presence of individual PVP molecules in solution. It was also shown that the molecular weights and dimensions of PVP-C₇₀ complexes are smaller than for PVP-C₆₀ by a factor of 2.5-3. In aqueous solutions of PVP-C₇₀ complex the depolarization and dissymmetry of scattered light were observed in contrast to PVP-C₆₀ solutions. It reveals the existence of anisotropic structures in PVP-C₇₀ solutions. Intermolecular interactions within PVP-C₇₀ complexes are weak and a hydrodynamic field can destroy complexes.     

含氮化合物对NiW体系催化剂芳烃加氢性能的影响

以γ-Al2O3、B改性的γ-Al2O3、F改性的γ-Al2O3、SiO2-Al2O3为载体制备Ni、W含量相同的四种催化剂，通过程序升温还原表征考察活性金属与不同载体的相互作用。利用氮含量不同、四氢萘含量相同的四种原料考察含氮化合物对同种NiW体系催化剂四氢萘加氢的影响以及对活性金属与载体相互作用不同的催化剂四氢萘加氢的影响。结果表明，以γ-Al2O3或SiO2-Al2O3载体制备的催化剂的金属组分与载体相互作用较强，B或F改性的γ-Al2O3能显著削弱活性金属与载体的相互作用；含氮化合物对四氢萘加氢具有强烈的抑制作用，使四氢萘加氢反应的表观活化能增加；在实验研究的四种催化剂中，金属组分与载体相互作用较弱的催化剂受含氮化合物的抑制较强。     

泌阳凹陷复杂断块群油气分布控制因素

泌阳凹陷北部斜坡复杂断块群油田以断鼻、断块及断层+岩性油气藏为主,垂向含油层系多,平面上叠合连片,油气主要富集在鼻状构造主体部位的断鼻断块内。通过对研究区油气控制因素的分析,指出继承性的鼻状构造控制了油气聚集方向和富集程度,油气藏含油范围和油气藏高度则主要受断层封闭性和封闭程度的控制,油气分布规律受伸展构造所伴生的各种断块群构造型式的控制。     

Platinum Binuclear Complexes as Phosphorescent Dopants for Monochromatic and White Organic Light‐Emitting Diodes

Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula C^∧NPt(μ‐pz)₂PtC^∧N (where C^∧N = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C^2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m^–2, a brightness of 3900 Cd m^–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (～ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (～ 5 %) and brightness (～ 600 Cd m^–2 at 10 V).     

阜阳地区石炭-二叠系煤系烃源岩特征

阜阳地区石炭-二叠系煤系地层发育，但由于勘探程度较低，对该区煤系地层烃源岩的生烃潜力认识不清，严重制约了该区的油气勘探。在已有资料的基础上，通过有机地球化学和有机岩石学方法并结合模拟实验，探讨了该区煤系烃源岩的生烃潜力。研究结果表明阜阳地区石炭-二叠系煤系烃源岩有机质丰度达到中等-好烃源岩标准，有机质类型以腐殖型为主，盆地模拟结果显示阜阳地区石炭-二叠系煤系地层油资源量为（30.47~152.33）×10⁶t，气资源量为（266.7～1333.7）×10⁸m³，展示阜阳地区石炭-二叠系煤系地层具有较好的生油气潜力。     

Determination of molecular weight and molecular sizes of polymers by high temperature gel permeation chromatography with a static and dynamic laser light scattering detector

Flow-mode static and dynamic laser light scattering (SLS/DLS) studies of polymers, including polystyrene, polyethylene, polypropylene and poly(dimethylsiloxane) (PDMS), in 1,2,4-trichlorobenzene (TCB) at 150 °C were performed on a high temperature gel permeation chromatography (GPC) coupled with a SLS/DLS detector. Both absolute molecular weight (M) and molecular sizes (radius of gyration, R_g and hydrodynamic radius, R_h) of polymers eluting from the GPC columns were obtained simultaneously. The conformation of different polymers in TCB at 150 °C were discussed according to the scaling relationships between R_g, R_h and M and the ρ-ratio (ρ=R_g/R_h). Flow-mode DLS results of PDMS were verified by batch-mode DLS study of the same sample. The presented technique was proved to be a convenient and quick method to study the shape and conformation of polymers in solution at high temperature. However, the flow-mode DLS was only applicable for high molecular weight polymers with a higher refractive index increment such as PDMS.     

塔里木油田水碳酸盐平衡系数与有机酸的意义

根据统计学规律,对塔里木盆地油田水进行了研究,阐明了该盆地油田水的碳酸盐平衡系数(简称为R_C)与有机酸的基本特征。从油田水的无机组分与有机组分的统计分析中发现了油田水的碳酸盐平衡系数与有机酸存在明显的负相关性,进一步论证了碳酸盐平衡系数和有机酸与油气聚集及油气性质的关系。碳酸盐平衡系数越低及低碳有机酸的含量越高,它们与油藏,尤其是与 轻质油或气藏的关系越密切。从两者的关系中初步了解到有机酸的溶蚀作用对油气藏中储层次生孔隙的形成应有较重要的影响。     

单片LCoS光学引擎中彩色LED照明系统设计

LCoS光学引擎作为整个背投的一个要组成部分，其照明系统显著地影响着LCoS背投的性能。详细分析了影响照明效果的各个因素，并利用ZEMAX软件设计出了单片LCoS光学引擎中基于彩色LED光源的照明系统，该系统能达到较好的亮度和均匀性，满足整个光机系统的成像要求。     

新型微光探测器激光防护材料的研究

系统分析了微光夜视器的结构及其原理，并结合当前器件存在的激光致盲威胁，提出了增强系统安全的新措施。同时，系统地介绍了防激光滤光材料一些重要的性能参数以及滤光材料的组成、制备加工工艺。研究结果表明，新型的防激光材料能够有效地防护800nm，900nm以及10613nm等三个波长的激光，并且可见光透过率大于85％。     

低光照和抗晕CCD的设计和制作

针对帧转移可见光CCD低光照响应、抗电晕能力和动态范围，较详细讨论了CCD光响应灵敏度、动态范围和抗电晕的设计与计算。设计的具有抗晕功能CCD，采用2μm工艺制作，达到了设计技术指标要求，满足了工程应用需求。