Local Structure of Alkaline-Earth Boroaluminate Crystals and Glasses: II, 11B and 27Al MAS NMR Spectroscopy of Alkaline-Earth Boroaluminate Glasses

¹¹B and ²⁷Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectra of alkaline-earth boroaluminate glasses show that the structure of these glasses are far more complicated than previously thought. The relative concentrations of 3- and 4-coordinated boron vary as found by previous investigators using continuous-wave NMR methods, but the ²⁷Al NMR spectra indicate the presence of Al in 4-, 5-, and 6-fold coordination, in contrast to previous assignments. Analysis of the data based on local charge balance considerations provides a qualitative model that correctly predicts compositional variations of the NMR peak intensities and ²⁷Al chemical shifts for a wide range of boroaluminate glass compositions.     

Application of Wavelet Packet De-noising in Time-Frequency Analysis of the Local Wave Method

The local wave method is a very good time-frequency method for nonstationary vibration signal analysis. But the interfering noise has a big influence on the accuracy of time-frequency analysis. The wavelet packet de-noising method can eliminate the interference of noise and improve the signal-noise-ratio. This paper uses the local wave method to decompose the de-noising signal and perform a time-frequency analysis. We can get better characteristics. Finally, an example of waveletpacket denoising and a local wave time-frequency spectrum application of diesel engine surface vibration signal is put forward.     

N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

城市建设的休克疗法——大连现象解说

在启动大规模的现代化建设的进程中，应对发展中听中型城市实施“休克疗法”，强调性终止城市发展的无序而缓慢的自然进程。选择短暂的“回归”或“中断”历史的调整时，应以能否适当地的历史文化特质从而把握当代的发展机遇为依据。     

Evaluation of influence of external magnetic disturbance on superconducting magnet taking conservation of linkage flux into account

External magnetic disturbance influences the quality of the image obtained with a magnetic resonance imaging (MRI) system because it causes magnetic resonance frequency drift. When a superconducting magnet in persistent current mode operation is exposed to external magnetic disturbance coil current varies to keep linkage flux constant. Conventional analysis is usually formulated with constant current and does not provide correct evaluation of drift of magnetic field in the magnet. This paper proposes a method of numerical analysis of magnetic field considering conservation of linkage flux in a superconducting magnet under a persistent current mode operation. This method is applied to evaluate drift of the magnetic field in a superconducting magnet for magnetic resonance imaging due to external magnetic disturbance. Analysis results show good agreement with the experimental results.     

局域网视频广播接收器的设计

描述了一个局域网视频广播接收器的设计。发送端以计算机按UDP/IP的方式向局域网中发送视频广播，在接收端利用FPGA器件设计的接收器对广播进行接收、缓冲、格式转换，以电视作为显示终端，并介绍了在FPGA器件中所设计的各个模块。     

Nuclear Magnetic Resonance Studies of Silicon Carbide Polytypes

The ²⁹Si MAS NMR spectra of the 2H, 4H, 6H, and 3C polytypes of silicon carbide are presented. An attempt is made to correlate differences in the chemical shifts with local atomic environment. The results of the analysis of the spectra of pure polytypes are used as a basic for the interpretation of the spectra of mixed polytypes and a discussion of the crystallinity and impurity levels of different samples. Carbon-13 chemical shifts obtained from spectra of the same polytypes are also tabulated.     

基于改进PSO算法的结构损伤检测

结构的损伤检测常转化为求解约束优化问题,针对粒子群算法容易出现早熟问题,增大算法后期的粒子位置的改变量,从而增加粒子位置的差异,因而能够增强其在求解约束优化问题时抵抗局部极小的能力。两层刚架单损伤和多损伤识别的数值结果和收敛曲线表明了改进后的粒子群算法优于传统的带惯性因子的粒子群算法。三层框架结构的4种损伤工况的试验研究进一步说明了该算法应用于结构损伤检测领域的有效性。     

Magnetic Resonance Visualisation of Flow and Pore Structure in Packed Beds with Low Aspect Ratio

Different NMR techniques were combined to obtain the structure and velocity information for a systematic investigation of fixed beds with low aspect ratio (tube diameter to particle diamter, d_t/d_p) in the range 1.4 to 32. The structure of the void space was determined for a variety of packed beds of glass beads or regular and irregular porous pellets by magnetic resonance imaging (MRI). Based on the images the radial distribution of the voids within the bed was obtained. Ordering effects were found even for non‐spherical and polydisperse particles, and a maximum of the fluid density near the tube wall was confirmed for all pellet geometries and sizes. By combining MRI with velocity encoding, velocity profiles and distributions of flow velocity components of a single fluid phase through packed beds have been acquired. The radial velocity distribution follows an oscillatory pattern which largely reflects the ordering of the particles, which can be accessed from the density distribution of the interparticle fluid. Maximum velocities of up to four times the average value were found to occur near the tube wall. This wall effect was observed for all but the smallest particles, where the aspect ratio was d_t/d_p = 32. Moreover, a visualisation of flow pattern in the presence of packed particles was achieved by using a tagging technique, and the stationary flow field could be identified for an experimental time of several hours.     

An Electron Spin Resonance Study of Evolution of Organic Free Radicals in Irradiated Pepper During Heat Treatment

ABSTRACT: The thermal evolution behavior of the organic free radicals induced in irradiated black pepper was studied by electron spin resonance spectroscopy. To analyze the time-dependent evolution process, we used the theory of transient phenomena, that is, an ordinal differential equation, as well as the nonlinear least squares numerical method. We found that the radical evolution that occurred in the irradiated pepper obeys a single exponential function and yields a unique time constant. The evolution of the organic free radical undergoes a simple reaction process of a single radical species.