Dipole moments of copolymers in relation to the distribution of polar monomer unit sequences

A method for evaluating the dipole moments of copolymers in relation to the distribution of polar unit sequences is proposed. Experimental data on the synthesis and dipole moments of styrene-p-chlorostyrene and styrene-p-methoxystyrene copolymers were used to calculate the effective dipole moment of a polar unit in a copolymer. For this purpose, we assumed the following effective moment values for the corresponding polar unit sequences along the copolymer chains: when both of the nearest neighbours are polar, μ_PP, when one of the nearest neighbours is polar and the other is non-polar, μ_PS, and when both of the nearest neighbours are non-polar, μ_SS. The relative magnitudes of μ_SS, μ_PS and μ_PP calculated for both copolymers reflect the influence of dipole-dipole interactions on the effective dipole moment of a polar unit in a copolymer molecule.     

Influence of polymer molecular weight on selected thermodynamic properties of polymer/solvent systems and the application of the UNIFAC theory

The intrinsic viscosities of eleven narrow molecular weight distribution polystyrene samples ranging from number-average molecular weight 1820 to 1 292 000 have been determined in pure solvents of tetrahydrofuran and chloroform with a Ubbelohde No. 1 viscometer at 25°C. By combining the original and modified Fox-Flory viscosity treatments, respectively, with the Flory-Huggins Lattice theory, the interaction parameters were calculated. With the aid of original and modified UNIFAC methods the solvent activity, clustering function of the solvent, and the interaction parameter were computed and compared with the experimental data. It was established that the influence imposed by the polymer molecular weight on the activity of the solvent, the clustering function of solvent, and interaction parameter is insignificant. The modified UNIFAC method satisfactorily predicted the solvent activity as illustrated by previous investigators. However, both UNIFAC methods failed to predict the interaction parameter.     

面向综合集成研讨环境的主动信息获取方法*

针对在综合集成研讨环境中,由于存在时间压力,传统的网络信息获取方法难以直接使用,提出了一种面向综合集成研讨环境的主动信息获取方法。该方法将领域词条与通用词条相结合,从发言文本流中实时提取话题,并在话题发生变化时自动生成检索词送入搜索引擎进行检索,再通过多个用户之间的协作推荐实现对重要检索结果的筛选。实验结果表明,这种方法可为综合集成研讨系统的用户提供及时、准确、上下文相关的信息服务。     

基于虚拟机的轻量级医疗诊断系统的应用研究*

医疗诊断系统存在设计难度大、投入成本高、数据安全难以保障等问题。提出一种基于虚拟机和轻量级开发的解决方案,采用ASP.NET+Access+Ajax模式设计医疗诊断系统,并运行在VMWare虚拟机环境中。根据该方案设计了急腹症医疗诊断系统。实践表明,基于虚拟机的轻量级医疗诊断系统,具有开发难度适中、成本低、安全可靠、管理维护方便等优点。     

PSO-SVM模型的构建与应用

为了使支持向量机(SVM)获得更好的分类效果,针对人为选择参数的随机性,提出了利用粒子群算法(PSO)进行参数自动选取的优化方法,构建了PSO-SVM模型.在个人信用评估中,通过对粒子适应度函数的设置来控制造成较大损失的第二类误判,应用结果表明:模型在训练和测试样本中的分类精度可以达到95%,第二类误判率分别仅为0.78%和2.02%.利用PSO对SVM中的参数进行优化,可以避免人为选择的随机性,并且在解决分类问题中表现出较好的稳健性.     

基于多特征融合的运动物体识别方法研究

为了实现运动目标的实时检测,本文基于多特征融合,提出了一种运动物体分级识别方法.首先通过对运动目标的分割,分析得到各个物体的形状矩特征、面积大小及运动速度.对上述特征,采用支持向量机方法对其矩特征进行快速的一级分类,然后对一级分类结果及各物体的面积、速度等信源根据其对分类的重要程度,采用模糊积分技术进行多特征融合分类.实验表明,本方法具有较强的学习能力及较高的识别精度,可有效地应用于道路监控等系统.     

Simulation and optimization of SOFC-BCHP system

As the prime motor of dispersed energy system, the high-temperature solid oxide fuel cells (SOFC) are high efficient with large heat recovery. This study presents a simulation of SOFC building-based cooling, heat and power (BCHP) system, which can meet basic requirements in power and heating (cooling) of the designated customers. The peak power load can be met by power grid, while the peak heating (cooling) load requirement can be met by backup equipments. In order to solve the economic dispatch problem of the energy system, a restricted nonlinear optimization model has been developed. The production costs can be minimized via both the equality constraints of customer’s heat and power demands, and other inequality constrains of equipments’ capacities. The sequential quadratic programming method has been used to search the solution. The study indicates that the model can be used to optimize the system’s capacities and run strategy. An office building case has been computed, and it is indicated that the model can be served in design and optimization of SOFC-BCHP system.     

基于邻域风险最小化概率密度估计的自适应盲分离算法*

为实现由不同统计特性和概率分布平滑特性信号得到混合信号的盲分离,对基于支持向量机的邻域风险最小化概率密度估计算法进行研究,提出一种邻域函数的构造方法,将其与自然梯度批处理算法相结合,形成一种新的自适应盲分离算法;利用广义高斯模型分析了分离算法的精确度。通过仿真实验,验证了该算法能分离统计特性不同的混合信号,相比于基于经验风险最小化的方法,该方法在收敛速度和精度方面的性能有很大提高。     

基于支持向量机的主动红外式结冰冰型分类方法研究*

针对飞机机翼等部位的结冰探测,提出了一种主动式红外结冰冰型分类的方法。该方法基于支持向量机,通过测量不同冰型结冰表面的红外激光反射系数,达到对结冰冰型分类的目的。初步试验结果表明,该方法能够以一定的准确性对物体结冰的冰型进行实时动态分类,为飞机结冰探测提供了一种新的技术思路。     

海洋平台灰预测和支持向量机的逆控制

导管架式海洋平台在随机波浪等外载荷作用下极易产生有害振动,且其动力响应具有极强的非线性和时变性,采用被动控制方法和基于精确数学模型的主动控制方法控制海洋平台的有害振动很难达到理想的控制效果.结合灰预测和支持向量机的优点,提出了基于灰预测和支持向量机的自适应逆控制方法,并将其与动态刚度阵法相结合应用于导管架式海洋平台的振动主动控制中.数值算例分析表明,该控制方法可有效地控制波浪和风载荷作用下引起导管架式平台的有害振动,并能解决由于控制信号传输等原因引起的时滞问题.