Nanofluidics: A New Arena for Materials Science

A significant growth of research in nanofluidics is achieved over the past decade, but the field is still facing considerable challenges toward the transition from the current physics‐centered stage to the next application‐oriented stage. Many of these challenges are associated with materials science, so the field of nanofluidics offers great opportunities for materials scientists to exploit. In addition, the use of unusual effects and ultrasmall confined spaces of well‐defined nanofluidic environments would offer new mechanisms and technologies to manipulate nanoscale objects as well as to synthesize novel nanomaterials in the liquid phase. Therefore, nanofluidics will be a new arena for materials science. In the past few years, burgeoning progress has been made toward this trend, as overviewed in this article, including materials and methods for fabricating nanofluidic devices, nanofluidics with functionalized surfaces and functional material components, as well as nanofluidics for manipulating nanoscale materials and fabricating new nanomaterials. Many critical challenges as well as fantastic opportunities in this arena lie ahead. Some of those, which are of particular interest, are also discussed.     

3D‐Printed Biomimetic Super‐Hydrophobic Structure for Microdroplet Manipulation and Oil/Water Separation

Biomimetic functional surfaces are attracting increasing attention for various technological applications, especially the superhydrophobic surfaces inspired by plant leaves. However, the replication of the complex hierarchical microstructures is limited by the traditional fabrication techniques. In this paper, superhydrophobic micro‐scale artificial hairs with eggbeater heads inspired by Salvinia molesta leaf was fabricated by the Immersed surface accumulation three dimensional (3D) printing process. Multi‐walled carbon nanotubes were added to the photocurable resins to enhance the surface roughness and mechanical strength of the microstructures. The 3D printed eggbeater surface reveals interesting properties in terms of superhydrophobilicity and petal effect. The results show that a hydrophilic material can macroscopically behave as hydrophobic if a surface has proper microstructured features. The controllable adhesive force (from 23 μN to 55 μN) can be easily tuned with different number of eggbeater arms for potential applications such as micro hand for droplet manipulation. Furthermore, a new energy‐efficient oil/water separation solution based on our biomimetic structures was demonstrated. The results show that the 3D‐printed eggbeater structure could have numerous applications, including water droplet manipulation, 3D cell culture, micro reactor, oil spill clean‐up, and oil/water separation.     

Light Confinement Effect Induced Highly Sensitive,Self‐Driven Near‐Infrared Photodetector and Image Sensor Based on Multilayer PdSe2/Pyramid Si Heterojunction

In this study, a highly sensitive and self‐driven near‐infrared (NIR) light photodetector based on PdSe₂/pyramid Si heterojunction arrays, which are fabricated through simple selenization of predeposited Pd nanofilm on black Si, is demonstrated. The as‐fabricated hybrid device exhibits excellent photoresponse performance in terms of a large on/off ratio of 1.6 × 10⁵, a responsivity of 456 mA W^?1, and a high specific detectivity of up to 9.97 × 10¹³ Jones under 980 nm illumination at zero bias. Such a relatively high sensitivity can be ascribed to the light trapping effect of the pyramid microstructure, which is confirmed by numerical modeling based on finite‐difference time domain. On the other hand, thanks to the broad optical absorption properties of PdSe₂, the as‐fabricated device also exhibits obvious sensitivity to other NIR illuminations with wavelengths of 1300, 1550, and 1650 nm, which is beyond the photoresponse range of Si‐based devices. It is also found that the PdSe₂/pyramid Si heterojunction device can also function as an NIR light sensor, which can readily record both “tree” and “house” images produced by 980 and 1300 nm illumination, respectively.     

Quantitative Magnetic Separation of Particles and Cells Using Gradient Magnetic Ratcheting

Extraction of rare target cells from biosamples is enabling for life science research. Traditional rare cell separation techniques, such as magnetic activated cell sorting, are robust but perform coarse, qualitative separations based on surface antigen expression. A quantitative magnetic separation technology is reported using high‐force magnetic ratcheting over arrays of magnetically soft micropillars with gradient spacing, and the system is used to separate and concentrate magnetic beads based on iron oxide content (IOC) and cells based on surface expression. The system consists of a microchip of permalloy micropillar arrays with increasing lateral pitch and a mechatronic device to generate a cycling magnetic field. Particles with higher IOC separate and equilibrate along the miropillar array at larger pitches. A semi‐analytical model is developed that predicts behavior for particles and cells. Using the system, LNCaP cells are separated based on the bound quantity of 1 μm anti‐epithelial cell adhesion molecule (EpCAM) particles as a metric for expression. The ratcheting cytometry system is able to resolve a ±13 bound particle differential, successfully distinguishing LNCaP from PC3 populations based on EpCAM expression, correlating with flow cytometry analysis. As a proof‐of‐concept, EpCAM‐labeled cells from patient blood are isolated with 74% purity, demonstrating potential toward a quantitative magnetic separation instrument.     

Path Planning and Control of a Cooperative Three-Robot System Manipulating Large Objects

After a brief review of the current research on multi-robot systems, the paper presents a path planning and control scheme for a cooperative three-robot system transferring/manipulating a large object from an initial to a desired final position/orientation. The robots are assumed to be capable of holding the object at three points that define an isosceles triangle. The mode of operation adopted is that of a master-and-two-slave robots. The control scheme employs the differential displacement of the object which is transformed into that of the end-effector of each robotic arm, and then used to compute the differential displacements of the joints of the robots. The scheme was applied to several 3-robot systems by simulation and proved to be adequately effective, subject to certain conditions regarding the magnitude of the differential displacements. Here, an example is included which concerns the case of three Stäubli RX-90L robots.     

Electrically Sensitive Plasmonic Photonic Crystals for Dynamic Upconversion Manipulation

Local optical field modulation using plasmonic materials or photonic crystals provides a powerful strategy for enhancing upconversion emission of lanthanide-doped upconversion nanocrystals (UCNPs). However, it is restricted to static UC enhancement and the corresponding dynamic modulation of UC is yet to be reported, limiting its practical applications in information devices. Here, a dynamic UC modulation system is reported through electric stimulation by integrating UCNPs with electrically sensitive WO_3−x plasmonic photonic crystals (PPCs). The tunable emission enhancement of UCNPs varying from five to 26 folds is achieved in WO_3−x PPCs/UCNPs hybrids through external electric stimulation within +1.6 and −1.6 V. It stems from the reversible control of the photonic bandgaps and localized surface plasmon resonance of WO_3−x PPCs, ascribed to the variation of refractive index and oxygen vacancy of WO_3−x, induced by the reversible change of atomic ratio of W⁵⁺ to W⁶⁺ under different applied voltages. Moreover, the electrically triggered information encryption devices are developed, employing a programmable logic gate array based on WO_3−x PPCs/UCNPs with the ability to convert information-encrypted electrical signals into visible patterns. These observations offer a new attempt to manipulate the UC and will simulate the new applications in the display and optical storage devices.     

A self-adjusting and modular supervisory control algorithm for planar dexterous manipulation

Many applications require precise handling and manipulation of delicate objects. In some cases, the object must be transported to a new location following a strict travel path including time-related constraints. This paper presents a self-adjusting modular control algorithm for dexterous manipulation of planar objects using multiple manipulators with precise path and timing deliveries. The popular caging approach is simple, and usually effective when manipulating objects with multiple devices but can fail following complex paths with orientation adjustments under time-critical tracking requirements. The proposed approach exploits the dynamics of the object in real-time using tracking control and allocates the force that needs to be applied by each manipulator based on their current position around the object to maximize their capability to push in the direction of the contact angle. The new algorithm is self-adjusting and modular; It can adjust its force allocation according to configuration changes during operation, and manipulators execute the same algorithm regardless of their number. The advantages of the new approach are successfully demonstrated both with simulations and testbed experiments, including orientation tracking, which is not typically featured with the caging approach. Conditions to check when the new algorithm is most effective are also analyzed. The closed-loop stability and performance of the new algorithm are also studied and necessary conditions are identified.     

Field-Free Manipulation of Skyrmion Creation and Annihilation by Tunable Strain Engineering

Creation and annihilation of skyrmions are two crucial issues for constructing skyrmion-based memory and logic devices. To date, these operations were mainly achieved by means of external magnetic, electrical, and optical modulations. In this work, we demonstrated an effective strain-induced skyrmion nucleation/annihilation phenomenon in [Pt/Co/Ta]_n multilayers utilizing the shape memory effect of a TiNiNb substrate. A tunable tensile strain up to 1.0% can be realized in the films by thermally driving phase transition of the substrate, which significantly decreases the nucleation field of skyrmions by as many as 400 Oe and facilitates the field-free manipulation of skyrmions with the strain. Such a strain effect can be attributed to the synergetic interplay of the planar magnetic moment twirling and decrement of interfacial Dzyaloshinskii–Moriya interaction. In addition, the strain tunability is found to be strongly related to the strain direction due to magnetoelastic interaction. These findings provide a novel strategy for developing strain-assisted skyrmion-based memory and logic devices.     

Stretchable and Ultrasensitive Intelligent Sensors for Wireless Human–Machine Manipulation

Metallic two-dimensional conductive nanomaterials are extensively explored in stretchable strain sensors, which have promising applications ranging from health monitoring to human–machine manipulation. However, there are limited materials available in this category, and their sensing abilities need to be strengthened. Herein, a controllable deoxidation–nitridation strategy via the pyrolysis of an amine nitrogen source to synthesize oxygen-doped vanadium nitride (VNO) nanosheets with high conductivity is reported. Its metallic characteristics and low dimensionality, together with layer-to-layer slippage make VNO particularly suitable for stretchable strain sensors with remarkable performance, including extraordinary sensitivity (a maximum gauge factor of 2667), wide detection range (0–100%), high durability (over 6000 cycles), and rapid response (44 ms). Furthermore, the strain sensors can capture various physiological signals; in particular, a state-of-the-art wireless vehicle control system designed for differently abled people is fabricated based on the sensors. Moreover, by engineering the thickness of the VNO layer, it can behave as an elastic conductor, demonstrating its feasibility for stretchable wiring.