首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   19192篇
  免费   3406篇
  国内免费   1756篇
电工技术   332篇
技术理论   1篇
综合类   1424篇
化学工业   4733篇
金属工艺   371篇
机械仪表   2242篇
建筑科学   2537篇
矿业工程   853篇
能源动力   923篇
轻工业   4890篇
水利工程   706篇
石油天然气   648篇
武器工业   129篇
无线电   523篇
一般工业技术   1770篇
冶金工业   806篇
原子能技术   457篇
自动化技术   1009篇
  2025年   62篇
  2024年   511篇
  2023年   404篇
  2022年   833篇
  2021年   1154篇
  2020年   1064篇
  2019年   1045篇
  2018年   935篇
  2017年   872篇
  2016年   935篇
  2015年   827篇
  2014年   1166篇
  2013年   1472篇
  2012年   1176篇
  2011年   1300篇
  2010年   957篇
  2009年   888篇
  2008年   858篇
  2007年   1108篇
  2006年   963篇
  2005年   919篇
  2004年   742篇
  2003年   679篇
  2002年   519篇
  2001年   425篇
  2000年   338篇
  1999年   314篇
  1998年   300篇
  1997年   280篇
  1996年   209篇
  1995年   186篇
  1994年   158篇
  1993年   138篇
  1992年   105篇
  1991年   79篇
  1990年   61篇
  1989年   51篇
  1988年   43篇
  1987年   36篇
  1986年   36篇
  1985年   24篇
  1984年   33篇
  1983年   20篇
  1982年   14篇
  1981年   51篇
  1980年   21篇
  1979年   7篇
  1957年   2篇
  1955年   3篇
  1951年   17篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
41.
土体含水量是影响高边坡稳定的重要因素。本文对宝鸡峡灌区总干98km高边坡变形破坏原因进行了探讨,并提出高边坡治理设计坡型。  相似文献   
42.
The kinetics and extent of glucose uptake, ethanol and acetate production, glucose-induced medium acidification and endogenous respiration were studied in baker's yeast starved aerobically for 0, 28, 54 and 96 h in saline (9 g litre?1 NaCI) at 35°C. Except for the last interval, prolonged starvation brought about an overall increase in most parameters; the transient increase in endogenous respiration observed after glucose addition was lowered with proceeding starvation. A 96 h starvation brought about a change in the kinetics of ethanol production, sharp increase in acetate production and a strong reduction of both the extent and the rate of glucose-induced acidification and of endogenous metabolism.  相似文献   
43.
44.
Consumption of diets rich in phenolic compounds has been associated with reduced risk of chronic diseases. The effect of cooking and simulated gastrointestinal digestion on phenolic compounds and antioxidant properties of two cowpea (Vigna unguiculata) types was determined. Phenolic acids, flavan‐3‐ols and flavonols were the main groups of phenolic compounds identified. Cooking and simulated enzyme digestion of the cooked cowpea samples rendered some phenolics less extractable (possibly by promoting binding with other food components) or more extractable (possibly by release of bound forms). Total phenolic contents and radical scavenging properties of the cowpeas were reduced upon cooking, but increased upon simulated enzyme digestion. Cowpea extracts inhibited human LDL oxidation at a concentration of 2 mg mL?1 possibly due to their phenolic content. Phenolic compounds in cowpea can potentially protect against cardiovascular diseases for which LDL oxidation is a risk factor.  相似文献   
45.
This paper describes the first map, albeit partial, of toxigenic fungi re-isolated from grape berries collected in three out of the six most important Slovakia winemaking areas in two different periods of the harvest year 2008. Low temperatures and high relative humidity during July 2008 favoured the development of grape fungal diseases that cause rots such as Plasmopara, Uncinula, Botrytis, Metasphaeria, Elsinoë, and Saccharomycetes. In the analysed samples, the following genera of toxigenic fungi were identified in the range of 1–4%: Aspergillus, Alternaria, Cladosporium, Epicoccum, Fusarium, Penicillium, Rhizopus, Ulocladium, and Trichoderma Trichothecium, while the genera Aspergillus, Alternaria, Fusarium, and Penicillium were in the range 11–29%. A. niger, A. carbonarius, some strains of A. carbonarius–with ‘crystals’ and strains of A. uvarum–uniseriate were identified; these species are considered ochratoxigenic (able to produce variable amounts of toxins). In addition, a non-ochratoxigenic strain of A. ibericus and a Fusarium strain able to biosynthesize small amount of fumonisins, beauvericin, and enniatins were identified. P. expansum, able to produce citrinin, represents 29.7%, of the Penicillium genus together with P. verrucosum, P. glabrum, P. citrinum, and P. crustosum. An analysis for the identification and quantification of the main toxins: ochratoxin A, fumonisins, beauvericin, enniatins, and fusaproliferin was performed on grape samples; it was consistent with the results of the mycological analysis. Toxigenic fungi should be checked throughout the years and their occurrence compared with all environmental factors to avoid health risks.  相似文献   
46.
顶空气相色谱质谱联用法分析芝麻油的挥发性气味成分   总被引:6,自引:0,他引:6  
刘平年 《中国油脂》2005,30(10):47-49
应用顶空气相色谱质谱法分析了芝麻油的挥发性气味成分,讨论了顶空和气相色谱质谱联用仪的操作参数.经质谱数据检索可知,芝麻油的挥发性气味成分主要分为含氧、含氮和含硫3类化合物.  相似文献   
47.
Updated knowledge about the presence of phenolic compounds in wine   总被引:1,自引:0,他引:1  
Phenolic compounds are partly responsible for the color, astringency, and bitterness of wine, as well as for numerous physiological properties associated with wine consumption. Mass spectrometry has allowed for great progress in the identification and characterization of wine polyphenols. The aim of the present article is to summarize the numerous advances recently achieved in this field. The main type of phenolic compounds found in wine, including hydroxybenzoic and hydroxycinnamic acids, stilbenes, flavones, flavonols, flavanonols, flavanols, and anthocyanins, are firstly described. Chemical reactions and mechanisms involving phenolic compounds during winemaking are also extensively discussed, including enzymatic and chemical oxidation reactions, direct and acetaldehyde-mediated anthocyanin-tannin condensation reactions, acetaldehydemediated and glyoxylic acid-mediated tannin-tannin condensation reactions and, C-4/C-5 anthocyanin cycloaddition reactions with 4-vinylphenols, vinylflavanols and pyruvic acid, among others, leading to the formation of pyranoanthocyanins. Useful mass spectral data of well-known and novel phenolic compounds recently identified in wine, and details related to their fragmentation pathway according to different ionization techniques, are given.  相似文献   
48.
朱海欧  陈进  卢志刚  李翔  张桂珍  李建军 《印染》2012,38(11):38-41
采用环境测试舱(ETC)、自动热脱附仪(ATD)和气相色谱/质谱(GC/MS)联用技术,建立了地毯中13种挥发性有机物(VOCs)的分析方法。该方法对VOCs单体的最小检出限(LODs)范围为0.008~0.4μg/m~3,方法的加标回收率为90%~106%,相对标准偏差(RSD)小于11%。将该方法用于多种市售地毯的VOCs测试,发现地毯释放VOCs的种类,与地毯底层材料有较大关联,沥青底胶层的方块地毯释放出较多的2-乙基-1-己醇,黄麻背衬地毯和聚酯背衬地毯释放出较多的苯乙烯和4-苯基环己烯,而薄层聚丙烯背衬地毯则释放出较多的直链或支链烷烃。  相似文献   
49.
The formation of 3-monochloropropane-1,2-diol (3-MCPD) esters in refined palm oil during deodorisation is attributed to the intrinsic composition of crude palm oil. Utilising D-optimal design, the effects of the degumming and bleaching processes on the reduction in 3-MCPD ester formation in refined palm oil from poor-quality crude palm oil were studied relative to the palm oil minor components that are likely to be their precursors. Water degumming remarkably reduced 3-MCPD ester formation by up to 84%, from 9.79 mg/kg to 1.55 mg/kg. Bleaching with synthetic magnesium silicate caused a further 10% reduction, to 0.487 mg/kg. The reduction in 3-MCPD ester formation could be due to the removal of related precursors prior to the deodorisation step. The phosphorus content of bleached palm oil showed a significant correlation with 3-MCPD ester formation.  相似文献   
50.
用海藻酸钠-PVA混合载体包埋制备固定化酵母细胞颗粒,比较了阶段性硬化和混合凝固剂同时硬化两种方法的固定化细胞颗粒的通透性及传质效果.电镜扫描和正交实验结果表明,阶段性硬化可提高固定化细胞颗粒的通透性及传质效果;最佳固定化条件为细胞颗粒在2%(w/w)CaCl2溶液成型后,立即在3%(w/w)的硼酸溶液中硬化24 h;固定化酵母细胞发酵过程产酒和机械性能的稳定.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号