用T621A石墨炭源合成出高强度金刚石

介绍了合成高强度(22．5kg～25．8kg)粗颗粒(40／50～25／30)单晶金刚石所需的炭源材料，触媒合金种类、装填方式、合成参数与合成效果。讨论了原料、合成工艺条件对生长高强度粗颗粒的优质金刚石的影响及合成机理。     

New synthesised pyridazine derivatives as effective inhibitors for the corrosion of pure iron in HCl medium

The inhibition of pure iron in 1 M HCl by new synthesised pyridazine compounds has been studied by weight loss, electrochemical polarisation and electrochemical impedance spectroscopy (EIS) measurements. The results obtained reveal that these compounds are efficient inhibitors. The inhibition efficiency increases with the increase of inhibitor concentration and reached 98% at 10⁻⁴ M for 5-benzyl-6-methyl pyridazine-3-thione. Potentiodynamic polarisation studies clearly reveal that the presence of pyridazines does not change the mechanism of hydrogen evolution and that they act essentially as cathodic inhibitors. The temperature effect on the corrosion behaviour of pure iron in 1 M HCl without and with the pyridazines at 10⁻⁴ M was studied in the temperature range from 298 to 353 K. EIS measurements show that the increase of the transfer resistance with the inhibitor concentration.     

Φ10007/00有压三产品重介旋流器结构参数优选与分选效果

辛置选煤厂针对原煤煤质变化后的特点 ,采用有压给料三产品重介旋流器为核心的高效选煤工艺系统分选 5 0～ 0mm原煤 ;对旋流器一段及二段中心管的直径和插入深度、二段底流口的直径等进行了优化调整 ,同时调整了介质泵的工作频率及悬浮液密度等参数 ,取得了分选效率高、产品质量稳定等显著效果     

氨纶干法纺丝介质循环系统的设备和工艺介绍

介绍氨纶干法纺丝技术中纺丝介质 (SM )循环系统的主要设备 ,对循环风压力、风温度和风量控制进行了探讨。严格控制SM循环工艺参数 ,可减少并丝现象。     

中压汽包法兰断裂失效原因分析及改进措施

本文针对中压汽包法兰断裂失效原因进行分析，指出汽包上两个法兰同时断裂的原因在于安全阀排汽管路设计上的失误，并提出对安全阀排汽系统的改进措施。     

盐水介质铝合金复合缓蚀剂的研究

以葡萄糖酸盐、醇胺磷酸酯、苯并三氮唑(BTA)、表面活性剂、添加剂等合成了盐水介质铝缓蚀剂并用腐蚀失重法进行了评价。在22.5％盐水介质中,葡萄糖酸钙:苯并三氮唑:硫酸锌:醇胺磷酸酯:十二烷基苯磺酸钠=1.0:1.0:0.6:0.2:0.05,50℃时,铝缓蚀率可达95％以上。     

Numerical study of the transfer of shock-wave loading to a screened flat wall through a layer of a powdered medium and a subsequent air gap

The two-velocity, two-temperature model with two stresses in a mixture of a gas and solid particles contacting each other is used to numerically study the dynamic effect of an air shock wave incoming onto a solid wall with a screening layer of a porous powdered medium at some distance from the wall. The process is described for the case of one-dimensional planar motion of the gaseous and disperse phases under the assumption of a viscoelastic behavior of the powder skeleton. The effect of stepwise shock waves onto the porous powdered screen is considered. The influence of parameters of the screening layer and the air gap on the dynamics of loading of the screened solid wall is analyzed. __________ Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 1, pp. 132–142, January–February, 2007.     

高效防腐中温磷化液LC-1的制备及性能

制备了一种含Zn2+、Mn2+、N i2+三系离子的LC-1磷化液,通过硫酸铜点滴、氯化钠浸蚀、SEM等手段对磷化膜进行了测试,测定了磷化温度、磷化时间对膜层耐蚀性的影响。结果表明,在磷化温度大于65℃,磷化时间大于10 m in的条件下,所形成的磷化膜结晶均匀、致密、黑褐色,耐蚀性良好。LC-1三系磷化液可适用于大批量钢铁工件的磷化生产。     

STUDIES ON COUNTERACTING CHROMATOGRAPHIC ELECTROPHORESIS AND ITS UTILIZATION FOR PROTEIN PURIFICATION

A counteracting chromatographic electrophoresis(CACE)separation device has been success-fully built and tested.Experiments are performed with protein mixtures of BSA,Hg,Mg and Cyto-cto study the separation performances,concentration profiles,start-up methodology as well as influ-ences of pH and ionic strength on the separation process.Mathematical models based on the fluiddynamics of the porous medium are proposed.Experiments indicate that the CACE process has agood commercial potential in protein engineering and fine chemicals purification.     

悬浮法合成固体粒状丙烯酸树脂

研究了悬浮法合成固体丙烯酸树脂颗粒。讨论了不同软硬单体配比对丙烯酸树脂颗粒的玻璃化转变温度、相对分子质量及其分布的影响以及不同的引发剂及悬浮剂对其聚合过程、最终产物形态及上述性能的影响。制得的丙烯酸树脂的数均相对分子质量用凝胶渗透色谱(GPC)测定为3.9×104～6.2×104,相对分子质量分布为2.04～2.32;用红外光谱图表征了制得的丙烯酸树脂结构。差示扫描量热法(DSC)测定了聚合物的玻璃化转变温度(Tg)。