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101.
102.
MTBE作为调合生产高标号无铅汽油的重要的高辛烷值组分油,准确测试其辛烷值在汽油调和生产中具有重要的意义。初步探讨了MTBE研究法辛烷值的测试方法,尝试了用甲苯标准燃料做参比燃料直接测定其净辛烷值,同时也测定了MTBE的混配辛烷值,通过MTBE辛烷值的测试,了解了MTBE的调和效应,确认了在石油二厂无铅汽油调和生产中对催化汽油的MTBE的真实辛烷值约为108/RON,指导了车用无铅汽油的调和生产。 相似文献
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介绍了如何提高甲醇触媒的活性及寿命,进一步降低电耗。文中对“精脱硫新工艺”的研发及设备的选取作了详细的论述。 相似文献
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Systems of Pd supported on various La2O3-modified -Al2O3 and CeO2–Al2O3 catalysts were tested for catalytic methanol decomposition and characterized by means of XRD, BET, TPR, H2-chemisorption and CO–FTIR. The addition of lanthanum significantly improved the selectivity of CO and H2 for all the catalysts but showed a different influence on the catalytic activity in two systems. Methanol conversion decreased on La2O3-modified Pd/-Al2O3 catalysts, in line with the reduction of Pd dispersion, while the addition of La2O3 improved the dispersion of Pd and reinforced Pd–CeO2 interaction for La2O3-modified Pd/CeO2–Al2O3 catalysts, which resulted in a high production rate of CO and H2. Thus, a synergistic effect between CeO2 and La2O3 was observed on -Al2O3-supported Pd catalyst for methanol decomposition. 相似文献
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109.
Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles 总被引:3,自引:0,他引:3
Methanol oxidation electrocatalysts were prepared from Ru electrochemical or spontaneous deposition on commercial-grade carbon-supported Pt nanoparticles (Pt-Vulcan XC72, E-TEK). The resulting Ru coverage was estimated by cyclic voltammetry in supporting electrolyte. The maximum electrocatalytic activity for methanol oxidation at room temperature was observed at lower Ru coverage for spontaneous deposition than for electrodeposition;
Ru 10% vs 20%, respectively. On the other hand, higher current densities for methanol oxidation were obtained in the case of electrodeposited Ru. These two results were related to the presence of non-reducible ruthenium oxides in the spontaneous deposit. The present work provides evidence that (i) efficient DMFC electrocatalysts can be achieved by Ru deposition on Pt nanoparticles, and (ii) formation of a PtRu alloy is not a required condition for effective methanol electrooxidation. 相似文献
110.
Abdullahi Nuhu Jorge Soares Monica Gonzalez-Herrera Andrew Watts Ghulam Hussein Michael Bowker 《Topics in Catalysis》2007,44(1-2):293-297
We have investigated the adsorption and reaction of methanol with Au/TiO2 catalysts using a pulsed flow reactor, DRIFTS and TPD. The TiO2 (P25) surface adsorbed a full monolayer of methanol, much of it in a dissociative manner, forming methoxy groups associated
with the cationic sites, and hydroxyl groups at the anions. The methoxy is relatively stable until 250 °C, at which point
decomposition occurs, producing mainly dimethyl ether by a bimolecular surface reaction. As the concentration of methoxy on
the surface diminishes, so the mechanism reverts to a de-oxygenation pathway, producing mainly methane and water (at ~330 °C
in TPD), but also with some coincident CO and hydrogen. Au catalysts were prepared by the deposition-precipitation method
to give Au loadings between 0.5–3 wt %. The effect of low levels of Au on the reactivity is marked. The pathway which gives
methane, which is characteristic of titania, remains, but a new feature of the reaction is the evolution of CO2 and H2 at lower temperature (a peak is seen in TPD at 220 °C), and the elimination of the DME-producing state. Clearly this is associated
with the presence of Au and appears to be due to the production of a formate species on the surface of the Au component. This
formate species is mainly involved in the reaction of methanol with the Au/TiO2 catalysts which results in a combustion pathway being followed, with complete conversion occurring by ~130 °C. 相似文献