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141.
Design of fluidized bed photoreactors: Optical properties of photocatalytic composites of titania CVD-coated onto quartz sand 总被引:1,自引:0,他引:1
Volumetric optical properties (spectral absorption, scattering and extinction coefficients) of differently expanded narrow-path fluidized beds (FB) of a photocatalyst obtained by plasma-CVD deposition of titania onto quartz sand, relevant for photoreactor design purposes, are determined by using an unidirectional and unidimensional (1DD) model for the solution of the radiative transfer equation (RTE). Two simplified approaches are used: a Kubelka-Munk (KM) type of solution, by which the RTE is transformed into a pair of ordinary differential equations, and a discrete ordinate method (DOM) by which the complete RTE is transformed into an algebraic system that can be solved computationally. The second approach was validated by introducing the obtained optical parameters into a more elaborated bi-directional and two-dimensional (2DD) DOM model. Despite its simplicity, the KM method was able to yield fair order-of-magnitude estimates of the spectral optical properties of these FB. 相似文献
142.
143.
概述了广义线性模型(含半参数广义线性模型)与非线性模型研究的新进展,着重讨论了它们参数估计的统计推断。近年来,广义线性模型与非线性模型的研究发展迅速,有着广泛的应用前景。 相似文献
144.
气辅注射工艺参数对气体穿透能力的影响 总被引:2,自引:0,他引:2
以某轿车后车门杂物箱盖为例,利用Moldflow软件和正交实验法,评价气体辅助注射成型的主要工艺参数对气体穿透能力和气辅零件质量的影响,并给出一组优化后的工艺参数。 相似文献
145.
非饱和土壤水分和溶质运移参数(扩散率、导水率和水动力弥散系数)取值范围较大,往往跨越几个数量级。采用传统离散化蚁群算法求解此类问题,所需节点较多,这会造成算法收敛时间较长。该文在传统蚁群算法基础上,对蚂蚁搜索路径进行改进,改进后的蚁群算法寻优路径由参数精度位数(整数位和小数位)、参数个数以及0–9十个数字构成,并将路径解码公式修改为具有判别参数正负功能的解码公式。采用改进的连续蚁群算法对非饱和溶质运移参数识别优化模型进行求解。数值模拟表明相同迭代次数下改进的蚁群算法比传统蚁群算法耗时少,算法计算时间与迭代次数满足线性关系,含水率和溶质浓度实测值与计算值吻合较好、相关性较高。 相似文献
146.
147.
Y. Castrillejo M. R. Bermejo A. M. Martínez C. Abejón S. Sánchez G. S. Picard 《Journal of Applied Electrochemistry》1999,29(1):65-73
The stability of indium chloride and oxide as well as the electrochemical behaviour of indium ions have been studied in the equimolar CaCl2–NaCl melt at 550 C by X-ray diffraction (XRD) and different electrochemical techniques, using molybdenum and tungsten wires as working electrodes. Voltammetric and chronopotentiometric studies showed signals attributed to the presence of three oxidation states of indium, i.e. 0, i and iii. The standard potential of the redox couples, as well as the solubility products of indium oxides have been determined, showing that In(iii) ions are completely reduced to monovalent indium by the indium metal according to the reaction: In () + 2 In 3 In () and that In2O is a strong oxide donor according to the reaction: In2O(s) 2 In() + O2- These results have allowed the construction of E-pO2– equilibrium diagrams summarising the properties of In–O compounds. The electrodeposition of indium was uncomplicated at Mo and W electrodes. Very good adherence of liquid indium to the electrode materials was observed, with the formation of Na–In alloys at highly reducing potentials, and there was no evidence of indium dissolution into the melt. Moreover, the voltammograms corresponding to the electrochemical In(iii)/In(i) exchange were well defined. The two electrochemical steps were found to be quasi-reversible, and the values of the kinetic parameters, ko and , for both reactions, as well as the diffusion coefficients, DIn(III) and DIn(I) were calculated. 相似文献
148.
149.
Abstract. In this paper we consider the time series dependence, stationarity, and higher moments issues of a family of first-order conditionally heteroskedastic in mean models with a possibly time-varying mean parameter. The interest in these models lies in the fact that economic theory and physics often require the connection between the first and second conditional moments of time series. Our results reveal important properties of these models, which are consistent with stylized facts in financial and turbulence data sets. They can also be employed for model identification, estimation, and testing. 相似文献
150.