耐盐性高吸水树脂的研究进展

综述了近年来国内外提高吸水树脂耐盐性的研究进展，概述了高吸水树脂的结构和吸水机理，归纳了引入亲水单体、降低树脂颗粒微环境的盐浓度等提高吸水树脂耐盐性的方法。     

350m~3高炉煤气净化单文氏管可调喉口理论计算及分析

通过单文氏管可调喉口的理论计算及分析，找出喉口最佳工作状态下的工艺参数及适合这种设备特性的煤气工作参被变化范围，以期能对实际操作过程及运行状态分析提供理论依据，提出单文氏可调喉口在更广泛意义上的设备、工艺参数选择、计算的方法。     

硝酸铵的膨化机理研究

膨化硝酸铵是一种自敏化改性硝酸铵,由硝酸铵溶液在专用表面活性剂作用下,经真空强制析晶工艺制得.文中研究了膨化硝酸铵制备的膨化过程和专用表面活性剂的作用,结果表明:在真空和表面活性剂作用下,硝酸铵溶液由不饱和状态至饱和状态,进而达到过饱和状态,最终导致硝酸铵的快速结晶和体系的膨胀.在真空干燥过程中,形成中心空穴、微细孔道和裂缝,它们使膨化硝酸铵的起爆感度提高;专用表面活性剂具有降低硝酸铵溶液表面张力、发泡剂和加快结晶成核的作用.     

Growth condition of iodine-doped n+-CdTe layers in metal-organic vapor phase epitaxy

Iodine doping of CdTe layers grown on (100) GaAs by metal-organic vapor phase epitaxy (MOVPE) was studied using diethyltelluride (DETe) and diisopropyltelluride (DiPTe) as tellurium precursors and ethyliodine (EI) as a dopant. Electron densities of doped layers increased gradually with decreasing the growth temperature from 425°C to 325°C. Doped layers grown with DETe had higher electron densities than those grown with DiPTe. When the hot-wall temperature was increased from 200°C to 250°C at the growth temperature of 325°C, doped layers grown with DETe showed an increase of the electron density from 3.7×10¹⁶ cm⁻³ to 2.6×10¹⁸ cm⁻³. On the other hand, such an increase of the electron density was not observed for layers grown with DiPTe. The mechanisms for different doping properties for DETe and DiPTe were studied on the basis of the growth characteristics for these precursors. Higher thermal stability of DETe than that of DiPTe was considered to cause the difference of doping properties. With increasing the hot-wall temperature from 200°C to 250°C, the effective ratio of Cd to Te species on the growth surface became larger for layers grown with DETe than those grown with DiPTe. This was considered to decrease the compensation of doped iodine and to increase the electron density of layers grown with DETe. The effective ratio of Cd to Te species on the growth surface also increased with decreasing growth temperature. This was considered to increase the electron density with decreasing growth temperature.     

新型阳离子聚丙烯酰胺微粒的研究--含PEO支链阳离子聚丙烯酰胺微粒的合成、助留性能及作用机理

本文采用反相微乳液聚合的方法合成了丙烯酰胺(AM)/丙烯酰氧基乙基三甲基氯化铵(AD-AMQUAT)/聚氧乙烯大单体(PEO-A)/N,N'-亚甲基双丙烯酰胺(Bis)的四元共聚物微粒.研究了该微粒助留剂的结构与性能.这种微粒和纸纤维能够通过离子键和氢键作用显著地增强助留效果.     

新型可调剪切差平行分束偏光器设计

本文给出了一种新型可调的切差平行分束偏光器设计。它调节方便,可获得较大平行分束剪切差,并可一镜多用     

A NEW APPROACH FOR THE CLASSIFICATION AND ENUMERATION OF UNIQUE REACTION ROUTES AND UNIQUE OVERALL REACTIONS IN MULTIPLE CHEMICAL REACTION SYSTEMS

The methodology of response reactions (RERs) introduced earlier from thermodynamic and kinetic considerations is used in this work to develop a new algorithm for the classification and enumeration of unique/direct reaction routes (RRs) and overall reactions (ORs). According to the RERs approach, a unique set of both RRs and ORs may be generated starting from any conceivable set of linearly independent RRs and ORs. In particular, the direct ORs may be most conveniently enumerated starting from the formula matrix of the terminal species (reactants and products), i.e., without any relation to the elementary reactions comprising the detailed mechanism. Depending on the type of ORs produced by the RRs one can distinguish between two distinct types of direct RRs. Namely, one option is to define a direct RR by specifying the intermediate species that need to be eliminated. This type of RR is referred to as Milner RRs. The other option is to require the direct RRs to produce RERs, thus resulting in RRs referred to as Happel-Sellers RRs.     

罐车内壁元素硫的来源机理

分析了罐车装运喷气燃料中元素硫的来源途径,探讨了罐车内壁元素硫的来源机理。理论分析和实验研究结果表明,罐车内壁元素硫主要来源于硫腐蚀,罐车内存在金属硫化物、水分、氧气等条件时可促进元素硫的生成;沉积于罐壁腐蚀内层的元素硫难以清洗除去,却可慢慢溶解于油品中而致使喷气燃料银片腐蚀不合格。采用汞滴法可快速有效地测定罐车残油中的元素硫含量,检测不合格的罐车不用于装运喷气燃料,可有效地解决喷气燃料银片腐蚀不合格的生产问题。     

胶体五氧化二锑研究现状及发展方向

对胶体五乳化二锑的研究现状进行了回顾，详细概述了胶体五乳化二锑的各种制备方法及其特点和适用范围，讨论了两种成胶理论。针对目前存在的问题，对胶体五乳化二锑的研究方向及研究重点提出了几点建议。     

川东北三叠系飞仙关组鲕滩气藏有利储集层的形成与分布

川东北地区三叠系飞仙关组鲕滩气藏是近年四川盆地碳酸盐岩天然气勘探取得重大突破的领域，目前在中国石油探区内已发现罗家寨、渡口河、铁山坡等大中型气藏。对鲕滩气藏白云岩储集层进行岩心观察、显微薄片分析，并进行微量元素、流体包裹体、X衍射、阴极发光及电子探针等分析，结果表明，白云岩化和多期溶蚀是形成优质白云岩储集层的关键因素，混合云化与埋藏云化的叠加作用是形成孔隙性白云岩储集层的基本条件。飞仙关组鲕滩气藏储集层经历了4期溶蚀作用，即同生期溶蚀作用、浅埋期溶蚀作用、深埋期溶蚀作用和抬升期溶蚀作用，形成优质白云岩储集层的主要溶蚀作用是浅埋期和深埋期的溶蚀作用。优质白云岩储集层主要分布在台缘鲕粒滩相带，纵向与亮晶鲕粒灰岩呈韵律性互层，横向主要分布在鲕粒滩坝靠近漏湖-潮坪一侧。